High performance lithium battery electrodes by self-assembly processing
View Patent ↗Disclosed are methods and processes for producing electrochemical devices having well-organized nanostructures or microstructures. In one aspect, the present invention discloses a simple, cheap, and fast nanotechnology-based manufacturing process for fabricating high performance electrodes. The present processing technique is highly versatile and can be applied to diverse materials systems for anode and cathode electrodes.
1. A method for producing an electrochemical device, the method comprising:
(a) placing a slurry comprising first active material particles comprising a first active material and second active material particles comprising a second active material on a metallic surface to form a slurry layer;
(b) applying an electric field to the slurry layer on the metallic surface wherein a dipole moment of the first active material particles and a dipole moment of the second active material particles are induced such that the first active material particles and the second active material particles are oriented to form a structure along with a direction of the electric field; and
(c) removing the electric field such that the structure remains stable to form the electrochemical device,
wherein the first active material and the second active material are selected from the group consisting of lithium cobalt oxide, lithium iron phosphate, lithium manganese oxide, lithium nickel manganese cobalt oxide, lithium nickel cobalt aluminum oxide, lithium titanate, lithium vanadium oxide, lithium iron fluorophosphates, and lithium-containing layered compounds having hexagonal symmetry based on α-NaFeO 2 structure with a space group of R3 −m, and
wherein the second active material is different from the first active material,
wherein step (b) comprises forming a plurality of binary structures of the first active material particles and the second active material particles along the direction of the electric field, at least some of the plurality of binary structures including a core of one of the first active material particles and the second active material particles and a shell of the other of the first active material particles and the second active material particles,
wherein the slurry comprises a solvent, and
wherein the first active material particles are more polarizable than the solvent, and
wherein the second active material particles are more polarizable than the solvent.
2. A method for producing an electrochemical device, the method comprising:
(a) placing a slurry comprising first active material particles comprising a first active material and second active material particles comprising a second active material on a metallic surface to form a slurry layer;
(b) applying an electric field to the slurry layer on the metallic surface wherein a dipole moment of the first active material particles and a dipole moment of the second active material particles are induced such that the first active material particles and the second active material particles are oriented to form a structure along with a direction of the electric field; and
(c) removing the electric field such that the structure remains stable to form the electrochemical device,
wherein the first active material and the second active material are selected from the group consisting of lithium cobalt oxide, lithium iron phosphate, lithium manganese oxide, lithium nickel manganese cobalt oxide, lithium nickel cobalt aluminum oxide, lithium titanate, lithium vanadium oxide, lithium iron fluorophosphates, and lithium-containing layered compounds having hexagonal symmetry based on α-NaFeO 2 structure with a space group of R3 − m, and
wherein the second active material is different from the first active material,
wherein step (b) comprises forming a plurality of binary structures of the first active material particles and the second active material particles along the direction of the electric field, at least some of the plurality of binary structures including alternating first active material particles and second active material particles,
wherein the slurry comprises a solvent, and
wherein one of the first active material particles and the second active material particles are more polarizable than the solvent, and
wherein the other of the first active material particles and the second active material particles are less polarizable than the solvent.
3. The method of claim 1 wherein:
the first active material comprises nanoparticles or microparticles, and
the second active material comprises nanoparticles or microparticles.
4. The method of claim 3 wherein:
the slurry further comprises a binder selected from the group consisting of polytetrafluoroethylene, polyvinylidene fluoride, cellulose, polyvinyl alcohol, carboxymethylcellulose, starch, hydroxypropylcellulose, regenerated cellulose, polyvinyl pyrollidone, tetrafluoroethylene, polyethylene, polypropylene, ethylene-propylene-diene terpolymers, sulfonated ethylene-propylene-diene terpolymers, styrene butadiene rubbers, fluoro-rubbers, copolymers, polymer-saponified polyvinyl alcohol, and mixtures thereof.
5. The method of claim 2 wherein:
the slurry further comprises a binder selected from the group consisting of polytetrafluoroethylene, polyvinylidene fluoride, cellulose, polyvinyl alcohol, carboxymethylcellulose, starch, hydroxypropylcellulose, regenerated cellulose, polyvinyl pyrollidone, tetrafluoroethylene, polyethylene, polypropylene, ethylene-propylene-diene terpolymers, sulfonated ethylene-propylene-diene terpolymers, styrene butadiene rubbers, fluoro-rubbers, copolymers, polymer-saponified polyvinyl alcohol, and mixtures thereof.
6. The method of claim 2 wherein:
step (b) comprises forming a network of alternating first active material particles and second active material particles in a plane perpendicular to the direction of the electric field.
7. The method of claim 2 wherein:
the first active material comprises nanoparticles or microparticles, and
the second active material comprises nanoparticles or microparticles.