Ultraviolet semiconductor light-emitting device and fabrication method
An ultraviolet semiconductor light emitting device includes: a light-emitting epitaxial layer including an n-type semiconductor layer, a light-emitting layer, and a p-type semiconductor layer; a tunnel junction at a non-light-emitting surface of the light-emitting epitaxial layer and having a patterned structure with openings to expose the light-emitting epitaxial layer; an optical phase matching layer over a surface layer of the light-emitting epitaxial layer and transmissive of UV light; and a reflecting layer covering the entire tunneling junction and the optical phase matching layer. A patterned structure is provided over the tunnel junction for full-angle light reflection. Part of the tunneling junction forms ohmic contact with the low work function reflecting metal. The patterned distribution design can effectively reduce the ohmic contact resistance.
1. A UV semiconductor light-emitting device, comprising:
a light-emitting epitaxial layer having one side as a light-emitting surface and another side as a non-light-emitting surface and comprising an n-type semiconductor layer, a light-emitting layer, and a p-type semiconductor layer;
a tunneling junction at the non-light-emitting side and comprising a patterned structure having openings to expose the light-emitting epitaxial layer;
an optical phase matching layer over a surface layer of the light-emitting epitaxial layer and transmissive of UV light; and
a reflecting layer covering the tunneling junction and the optical phase matching layer.
2. The semiconductor light-emitting device of claim 1 , wherein the reflecting layer comprises a material having a work function of about 4.0-5.0 eV, and forms ohmic contact with the tunneling junction.
3. The semiconductor light-emitting device of claim 2 , wherein the reflecting layer has a work function value of about 4.0-5.0 eV, and a reflectivity of not less than 70% for light with wavelengths less than 380 nm.
4. The semiconductor light-emitting device of claim 1 , wherein the tunneling junction has a patterned structure and a side with a solid slope with a gradient between 10°-85°.
5. The semiconductor light-emitting device of claim 4 , wherein the patterned structure comprises at least one of a band shape, an island shape, a round platform, a trapezoid platform, a cone shape, or a hemispheric shape.
6. The semiconductor light-emitting device of claim 1 , wherein the light-emitting epitaxial layer comprises a III-V group material that is a binary compound or ternary compound comprising at least one of Al, Ga, N, P, or In.
7. The semiconductor light-emitting device of claim 6 , wherein the III-V group material is AlGaN having an Al concentration of not less than 40%.
8. The semiconductor light-emitting device of claim 1 , wherein: the optical phase matching layer is composed of an insulation material.
9. A method of fabricating a UV light-emitting device with wavelengths of about 100-380 nm, the method comprising:
(1) fabricating an n-type conductive layer, a light-emitting layer, a p-type conductive layer over a growth substrate and forming a light-emitting epitaxial layer having one side as a light-emitting surface and another side as a non-light-emitting surface;
(2) fabricating a tunneling junction over the non-light-emitting surface;
(3) patterning the tunneling junction including etching an area of the tunneling junction and the light-emitting epitaxial layer to expose a portion of the light-emitting epitaxial layer surface;
(4) fabricating an optical phase matching layer over the exposed light-emitting epitaxial layer surface; and
(5) fabricating a reflecting layer over the tunneling junction and the optical phase matching layer.
10. The fabrication method of claim 9 , wherein the growth substrate is substantially transparent and UV-permeable with a band gap not less than 3.4 eV.
11. The fabrication method of claim 9 , wherein the step (3) comprises fabricating a three-dimensional pattern at the tunneling junction by yellow light photoetching and dry etching with an etching depth not less than 0.5 nm.
12. The fabrication method of claim 9 , wherein the reflecting layer comprises a material with a work function of 4.0-5.0 eV and forming ohmic contact with the tunneling junction.
13. The fabrication method of claim 9 , further comprising:
fabricating a p-electrode and an n-electrode over the p-type semiconductor layer and the n-type semiconductor layer, respectively;
providing a supporting substrate having a patterned metal layer thereon, which bonds the supporting substrate with the p-electrode and the n-electrode; and
thinning the growth substrate to form a flip-chip light-emitting device.
14. The fabrication method of claim 9 , further comprising:
forming an electrode bonding layer over the reflecting layer;
providing a supporting substrate and bonding the supporting substrate with the electrode bonding layer; and
removing the growth substrate to expose the light-emitting epitaxial layer, over which fabricating an electrode, to thereby form a vertical light-emitting device.
15. A system comprising a plurality of UV semiconductor light-emitting devices, each device comprising:
a light-emitting epitaxial layer having one side as a light-emitting surface and another side as a non-light-emitting surface and comprising an n-type semiconductor layer, a light-emitting layer, and a p-type semiconductor layer;
a tunneling junction at the non-light-emitting side and comprising a patterned structure having openings to expose the light-emitting epitaxial layer;
an optical phase matching layer over a surface layer of the light-emitting epitaxial layer and transmissive of UV light; and
a reflecting layer covering the tunneling junction and the optical phase matching layer.
16. The system of claim 15 , wherein the reflecting layer comprises a material having a work function of about 4.0-5.0 eV, and forms ohmic contact with the tunneling junction.
17. The system of claim 16 , wherein the reflecting layer has a work function value of about 4.0-5.0 eV, and a reflectivity of not less than 70% for light with wavelengths less than 380 nm.
18. The system of claim 15 , wherein the tunneling junction has a patterned structure and a side with a solid slope with a gradient between 10°-85°.
19. The system of claim 18 , wherein the patterned structure comprises at least one of a band shape, an island shape, a round platform, a trapezoid platform, a cone shape, or a hemispheric shape.
20. The system of claim 15 , wherein the light-emitting epitaxial layer comprises a III-V group material that is a binary compound or ternary compound comprising at least one of Al, Ga, N, P, or In.