Polymeric blends and related optoelectronic devices

1. An optoelectronic device comprising a first electrode, a second electrode, and a photoactive layer disposed between the first and second electrodes, the photoactive layer comprising a polymer-polymer blend semiconductor material, the polymer-polymer blend semiconductor material comprising an electron-donor polymer and an electron-acceptor polymer, wherein:

the electron-acceptor polymer is represented by Formula 1 or 2:

wherein:

π−1 and π−1′ are identical or different and independently are selected from the group consisting of:

R 1 and R 1′ are identical or different and independently are selected from the group consisting of a C 1-30 alkyl group, a C 2-30 alkenyl group, a C 1-30 haloalkyl group, a C 6-20 aryl group and a 5-14 membered heteroaryl group, wherein the C 6-20 aryl group and the 5-14 membered heteroaryl group optionally are substituted with a C 1-30 alkyl group, a C 2-30 alkenyl group, or a C 1-30 haloalkyl group;

M a and M a′ are identical or different and independently are a repeat unit comprising one or more conjugated moieties that does not include a rylene diimide;

p and q independently are a real number, wherein 0.1≦p≦0.9, 0.1≦q≦0.9, and the sum of p and q is about 1; and

n is an integer in the range of 2 to 5,000;

provided that at least one of the following is true: (a) π−1′ is different from π−1, (b) R 1′ is different from R 1 , or (c) M a′ is different from M a ; and

the electron-donor polymer is an alternating copolymer selected from the group consisting of:

wherein R b , at each occurrence, is a linear or branched C 3-40 alkyl group; R c , at each occurrence, is H or a C 6-20 alkyl group; and n is an integer in the range of 5 to 5,000.

2. The device of claim 1 , wherein the electron-acceptor polymer is represented by Formula 3 or 4:

wherein:

R′ and R″ are identical or different and independently are selected from the group consisting of H, F, Cl, —CN, and —L—R, wherein L, at each occurrence, independently is selected from the group consisting of —O—, —S—, —C(O), —C(O)O—, and a covalent bond;

and R, at each occurrence, independently is selected from the group consisting of a C 6-20 alkyl group, a C 6-20 alkenyl group, and a C 6-20 haloalkyl group;

m and m′ independently are 1, 2, 3, 4, 5 or 6.

3. The device of claim 1 , wherein the electron-acceptor polymer is represented by Formula 5, 6, or 7:

4. The device of claim 1 , wherein R 1 and R 1′ are selected from the group consisting of a branched C 3-20 alkyl group, a branched C 4-20 alkenyl group, and a branched C 3-20 haloalkyl group.

5. The device of claim 4 , wherein R 1 and R 1′ are selected from the group consisting of:

6. The device of claim 1 , wherein the acceptor subunit (A) is represented by the formula:

wherein δ represents the electron-poor conjugated moiety, and R c , at each occurrence, is H or R, wherein R, at each occurrence, independently is selected from the group consisting of a C 6-20 alkyl group, a C 6-20 alkenyl group, and a C 6-20 haloalkyl group.

7. The device of claim 6 , wherein the electron-poor conjugated moiety (δ) is an 8-14 membered polycyclic heteroaryl moiety comprising either at least one ring that has two or more heteroatoms selected from N and S, and/or at least one ring that is substituted with one or more electron-withdrawing groups selected from the group consisting of F, Cl, an oxo group, a carbonyl group, a carboxylic ester group, and a sulfonyl group.

8. The device of claim 6 , wherein the electron-poor conjugated moiety (δ) is selected from the group consisting of:

wherein R d , at each occurrence, independently is selected from a C 3-40 alkyl group, a C 3-40 alkenyl group, and a C 3-40 haloalkyl group; and R f , at each occurrence, independently is selected from the group consisting of H, F, Cl, —CN, —S(O) 2 —C 1-20 alkyl, —C(O)—OC 1-20 alkyl, —C(O)—C 1-20 alkyl, a C 1-20 alkyl group, a C 2-20 alkenyl group, a C 1-20 alkoxy group, a C 1-20 alkylthio group, and a C 1-20 haloalkyl group.

9. The device of claim 8 , wherein R d , at each occurrence, independently is a linear or branched C 6-20 alkyl group; and R f , at each occurrence, independently is selected from H, F, Cl, C(O)R e , C(O)OR e , and S(O) 2 R e ; where R e , at each occurrence, independently is a linear or branched C 6-20 alkyl group.

10. The device of claim 1 , wherein the electron donor polymer is a random copolymer selected from the group consisting of:

wherein R b , at each occurrence, is a linear or branched C 3-40 alkyl group; R, at each occurrence, is a C 6-20 alkyl group; x and y independently are a real number, wherein 0.1≦x≦0.9, 0.1≦y≦0.9 (0.2≦x≦0.8, 0.2≦y≦0.8), and the sum of x and y is about 1;

and n is an integer in the range of 5 to 5,000.

11. The device of claim 1 , wherein the electron donor polymer is an alternating copolymer selected from the group consisting of:

wherein R b , R d , R e , at each occurrence, independently is a linear or branched C 3-40 alkyl group; R c , at each occurrence, is H or a C 6-20 alkyl group; R f , at each occurrence, independently is selected from H, F, Cl, C(O)R e , C(O)OR e , and S(O) 2 R e ; where R e , at each occurrence, independently is a linear or branched C 6-20 alkyl group; r is 0 or 1; and

n is an integer in the range of 5 to 5,000.

12. The device of claim 1 configured as an organic photovoltaic device comprising an anode, a cathode, optionally one or more anode interlayers, optionally one or more cathode interlayers, and in between the anode and the cathode the photoactive layer.

13. The device of claim 1 , wherein the donor subunit (D) comprises a benzodithiophene moiety selected from the group consisting of:

is selected from the group consisting of:

each of which optionally is substituted with 1-2 R b groups, and R b , at each occurrence, independently is a C 3-40 alkyl group or branched alkyl group.