Glass with enhanced strength and antimicrobial properties, and method of making same
A method of making an antimicrobial glass article that includes the steps: submersing the article in a strengthening bath to exchange a portion of ion-exchangeable metal ions in the glass article with a portion of ion-exchanging metal ions in the strengthening bath to form a compressive stress layer extending from the first surface to a diffusion depth in the article; removing a portion of the compressive stress layer from the first surface of the article to a first depth above the diffusion depth in the article to define a new first surface and a remaining compressive stress layer; and submersing the article in an antimicrobial bath to exchange a portion of the ion-exchangeable and the ion-exchanging metal ions in the compressive stress layer with a portion of the silver metal ions in the antimicrobial bath to impart an antimicrobial property in the article.
1. An antimicrobial glass article, comprising:
a glass article having a first surface, wherein a surface region between the first surface and about 0.5 μm in depth from the first surface is substantially free of hydrogen penetration;
a compressive stress layer extending from the first surface of the glass article to a first selected depth in the glass article; and
an antimicrobial region comprising a plurality of silver ions extending from the first surface to an antimicrobial depth of approximately 3 μm or less in the glass article,
wherein the first surface of the glass article has a concentration of silver ions that ranges from about 5% to about 70% by weight of Ag 2 O.
2. The antimicrobial glass article according to claim 1 , wherein the first surface is characterized by a morphology consistent with about 0.1 μm to 2 μm of material removal from a polishing treatment or an etching treatment.
3. The antimicrobial glass article according to claim 1 , wherein the compressive layer contains a plurality of exchanged alkali metal ions.
4. The antimicrobial glass article according to claim 1 , wherein the first surface has a concentration of silver ions that ranges from about 20% to about 40% by weight.
5. The antimicrobial glass article according to claim 1 , wherein the first surface has a concentration of silver ions that ranges from about 30% to about 40% by weight.
6. The antimicrobial glass article according to claim 1 , wherein the surface region has a hydrogen penetration as measured by Secondary Ion Mass Spectrometry (SIMS) of about 1000 counts/second or less.
7. The antimicrobial glass article according to claim 1 , further comprising:
a residual antimicrobial region comprising one or more silver ions and extending from the antimicrobial depth to a residual antimicrobial depth.
8. The antimicrobial glass article according to claim 1 , wherein silver ions are not appreciable at a depth of 1500 nm or greater from the first surface of the glass article.
9. An antimicrobial glass article, comprising:
a glass article having a first surface wherein a surface region between about 0.1 μm and about 0.5 μm in depth from the first surface is substantially free of hydrogen penetration;
a compressive stress layer extending from the first surface of the glass article to a first selected depth in the glass article; and
an antimicrobial region comprising a plurality of silver ions extending from the first surface to an antimicrobial depth of approximately 3 μm or less in the glass article,
wherein the first surface of the glass article has a concentration of silver ions that ranges from about 5% to about 70% by weight of Ag 2 O.
10. The antimicrobial glass article according to claim 9 , wherein the first surface is characterized by a morphology consistent with about 0.1 μm to 2 μm of material removal from a polishing treatment or an etching treatment.
11. The antimicrobial glass article according to claim 9 , wherein the compressive layer contains a plurality of exchanged alkali metal ions.
12. The antimicrobial glass article according to claim 9 , wherein the first surface has a concentration of silver ions that ranges from about 20% to about 40% by weight.
13. The antimicrobial glass article according to claim 9 , wherein the first surface has a concentration of silver ions that ranges from about 30% to about 40% by weight.
14. The antimicrobial glass article according to claim 9 , wherein the surface region has a hydrogen penetration as measured by Secondary Ion Mass Spectrometry (SIMS) of about 1000 counts/second or less.
15. The antimicrobial glass article according to claim 9 , further comprising:
a residual antimicrobial region comprising one or more silver ions and extending from the antimicrobial depth to a residual antimicrobial depth.
16. The antimicrobial glass article according to claim 9 , wherein silver ions are not appreciable at a depth of 1500 nm or greater from the first surface of the glass article.