MOLECULARLY IMPRINTED POLYMER SENSORS
Systems and methods for the detection of one or more target molecules, such as benzene, are described. The systems and methods may include a molecularly imprinted polymer film; a sensing material, wherein the molecularly imprinted polymer film comprises a polymer host with one or more binding sites for one or more target molecules. The molecularly imprinted polymer film may be coated upon the sensing material.
1 . A system for the detection of one or more target molecules, the system comprising:
a molecularly imprinted polymer film wherein the molecularly imprinted polymer film comprises a polymer host with one or more binding sites for one or more target molecules, wherein the one or more target materials are non-polar;
a sensing material, and
wherein the molecularly imprinted polymer film is coated upon the sensing material.
2 . The system of claim 1 , further comprising a housing at least partially surrounding the molecularly imprinted polymer film and an air inlet into the housing.
3 . The system of claim 1 , wherein the one or more target molecules are selected from the group consisting of: benzene, benzene derivatives, and combinations thereof.
4 . The system of claim 1 , wherein the one or more target molecules are benzene.
5 . The system of claim 1 , wherein the sensing material indicates changes in resistance or capacitance upon detection of the one or more target molecules.
6 . The system of claim 1 , wherein the molecularly imprinted polymer film is a phase inversion film.
7 . The system of claim 1 , wherein the molecularly imprinted polymer film is synthesized using monomers and crosslinking agents.
8 . A method for detecting one or more target molecules, the method comprising:
providing a molecularly imprinted polymer film with one or more binding sites for detection of one or more target molecules, wherein the one or more target molecules are non-polar;
exposing said molecularly imprinted polymer film to a gas, air sample, or vapor; and
measuring a change of said molecularly imprinted polymer film, wherein said change is used to detect said one or more target molecules in said gas, air sample, or vapor.
9 . The method of claim 8 , wherein the one or more target molecules are benzene.
10 . The method of claim 8 , wherein the change is a change is resistance or capacitance upon detection of the one or more target molecules.
11 . A method for producing a strain sensitive molecularly imprinted polymer film for detection of one or more target molecules, the method comprising:
dissolving a polymer host comprising a structural component and a reporting component in a first solvent to form a first solution;
mixing a target molecule into said first solution to form a molecularly imprinted polymer solution;
coating said molecularly imprinted polymer solution onto a sensing material; and
removing the target molecule to form a molecularly imprinted polymer film.
12 . The method of claim 11 , wherein the coating comprises spin coating.
13 . The method of claim 11 , wherein the removing the target molecule comprises:
extracting the target molecule from the molecularly imprinted polymer film using a second solvent,
wherein the polymer host is insoluble in the second solvent, and
wherein the target molecule is soluble in said second solvent.
14 . The method of claim 11 , wherein the first solvent has a boiling point lower than the boiling point of the target molecule, and wherein the removing the target molecule comprises evaporating the target molecule from the molecularly imprinted polymer film.
15 . The method of claim 11 , wherein the target molecule is selected from the group consisting of: benzene, benzene derivatives, and combinations thereof.
16 . The method of claim 11 , wherein the target molecule is benzene.
17 . The method of claim 11 , wherein the molecularly imprinted polymer film is a phase inversion film.
18 . The method of claim 17 , wherein the coating is spin coating.
19 . The method of claim 11 , wherein the molecularly imprinted polymer film is synthesized using monomers and crosslinking agents.
20 . The method of claim 19 , wherein the polymer host comprises monomer for the molecularly imprinted polymer film, and further adding a crosslinking agent.