Negative active material for lithium secondary battery, method for preparing the same, negative electrode comprising the same, and lithium secondary battery comprising same
The present invention relates to a negative active material for a rechargeable lithium battery, a method of manufacturing the negative active material, and a rechargeable lithium battery including the negative active material. The negative active material includes a first graphite particle including graphite pieces; and at least one second particle selected from the group consisting of an element particle, an element compound particle, a composite particle, and a carbon composite particle, and a combination particle thereof, wherein the element particle, the element compound particle, the composite particle, and the carbon composite particle are selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof; wherein each of the graphite pieces has a thickness ranging from 0.01 μm to 0.1 μm and the graphite pieces are linked to one another forming a curved side; and wherein the at least one second particle is dispersed between the graphite pieces.
1. A negative active material for a rechargeable lithium battery comprising:
a first graphite particle including graphite pieces; and
at least one second particle selected from the group consisting of an element particle, an element compound particle, a composite particle, and a carbon composite particle, and a combination particle thereof,
wherein the element particle is selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof;
the element compound particle is selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof;
the composite particle including at least one element selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof; and
the carbon composite particle including at least one element selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof;
wherein each of the graphite pieces has a thickness ranging from 0.01 μm to 0.1 μm and the graphite pieces are linked to one another forming a curved side; and
wherein the at least one second particle is dispersed between the graphite pieces.
2. The negative active material of claim 1 , wherein the first graphite particle has a cabbage shape formed by the graphite pieces being linked to one another.
3. The negative active material of claim 1 , wherein the element compound particle selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof comprises a Si particle and a transition element.
4. The negative active material of claim 3 , wherein the transition element includes at least one selected from the group consisting of Sc, Ti, Mn, Fe, Co, Ni, Cu, Y, Zr, Nb, Mo, Ru, La, Hf, Ta, W, Re, Os, and combinations thereof.
5. The negative active material of claim 1 , wherein the composite particle comprising at least one element selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof is formed by mixing the element particle selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof and the element compound particle selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof.
6. The negative active material of claim 1 , wherein the carbon composite particle comprising at least one element selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof comprises at least one selected from the group consisting of a composite of at least one element particle selected from the Si, Sn, Al, Ge, Pb, and combinations thereof and carbon; a composite of at least one element compound particle selected from the group consisting of the Si, Sn, Al, Ge, Pb, and combinations thereof and carbon; a composite of at least one element particle selected from the group consisting of the Si, Sn, Al, Ge, Pb, and combinations thereof, at least one element compound particle selected from the group consisting of the Si, Sn, Al, Ge, Pb, and combinations thereof, and carbon; and a combination composite thereof.
7. The negative active material of claim 1 , wherein the element particle selected from the group consisting of the Si, Sn, Al, Ge, Pb, and combinations thereof; the element compound particle selected from the group consisting of the Si, Sn, Al, Ge, Pb, and combinations thereof; and the composite particle including at least one element selected from the group consisting of the Si, Sn, Al, Ge, Pb, and combinations thereof have a size ranging from 5 nm to 5 μm.
8. The negative active material of claim 1 , further comprising amorphous carbon or soft carbon dispersed between the graphite pieces.
9. The negative active material of claim 8 , wherein the amorphous carbon or soft carbon dispersed between the graphite pieces has a micro porous channel.
10. The negative active material of claim 8 , wherein the first graphite particle is coated on its surface with amorphous carbon or soft carbon.
11. The negative active material of claim 10 , wherein the amorphous carbon or soft carbon coated on the surface of the first graphite particle has a thickness ranging from 0.01 μm to 1 μm.
12. The negative active material of claim 8 , wherein the amorphous carbon or soft carbon dispersed between the graphite pieces is included in an amount ranging from 1 to 50 wt % based on the entire weight of the negative active material.
13. The negative active material of claim 8 , wherein the amorphous carbon or soft carbon dispersed between the graphite pieces includes therein at least one element selected from the group consisting of AI, Cu, Cr, Co, Fe, Mg, Mn, Mo, Ni, Pt, Ru, Si, Ta, Ti, W, U, V, Zr, and combinations thereof.
14. The negative active material of claim 1 , wherein the first graphite particle is coated on its surface with amorphous carbon or soft carbon.
15. The negative active material of claim 14 , wherein the amorphous carbon or soft carbon coated on the surface of the first graphite particle has a thickness ranging from 0.01 μm to 1 μm.
16. The negative active material of claim 1 , wherein the at least one second particle is included in an amount ranging from 1 to 70 wt % based on the entire weight of the first graphite particle.
17. The negative active material of claim 1 , wherein the graphite pieces have a curved side continuously arranged along and within the inner circumference of the first graphite particle.
18. The negative active material of claim 1 , wherein the at least one second particle is uniformly dispersed between the graphite pieces inside the first graphite particle.
19. A negative electrode for a rechargeable lithium battery comprising a negative active material of claim 1 .
20. The negative electrode of claim 19 , which comprises a conductive agent.
21. The negative electrode of claim 20 , wherein the conductive agent comprises amorphous carbon or soft carbon.
22. The negative electrode of claim 20 , wherein the negative active material for a rechargeable lithium battery and the conductive agent are comprised in a weight ratio ranging from 98:2 to 20:80.
23. A rechargeable lithium battery comprising a positive electrode comprising a positive active material capable of intercalating and deintercalating lithium ions; a negative electrode comprising a negative active material of claim 1 ; and an electrolyte.
24. A method of manufacturing a negative active material for a rechargeable lithium battery, the method comprising:
exfoliating graphite into graphite pieces having a thickness ranging from 0.01 μm to 0.1 μm,
preparing a mixture by mixing the graphite pieces and at least one second particle selected from the group consisting of an element particle selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof; an element compound particle selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof; a composite particle comprising at least an element selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof; a carbon composite particle comprising at least one element selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof; and a combination particle thereof, and
assembling the mixture to obtain a first graphite particle in which the graphite pieces are linked to one another forming a curved side and the at least one second particle is dispersed between the graphite pieces.
25. The method of claim 24 , wherein the graphite is flake-shaped graphite.
26. The method of claim 24 , further comprising isostatically pressuring the first graphite particle, after assembling the mixture.
27. The method of claim 24 , further comprising:
mixing the first graphite particle and an amorphous carbon precursor or a soft carbon precursor to obtain a second mixture, and
heating the second mixture to carbonize the amorphous carbon precursor or the carbon precursor, thereby obtaining the first graphite particle coated with amorphous carbon or soft carbon.
28. A method of manufacturing a negative active material for a rechargeable lithium battery, the method comprising:
exfoliating graphite into graphite pieces having a thickness ranging from 0.01 μm to 0.1 μm,
preparing a mixture by mixing the graphite pieces, at least one second particle selected from the group consisting of an element particle selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof; an element compound particle selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof; a composite particle comprising at least an element selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof; a carbon composite particle comprising at least one element selected from the group consisting of Si, Sn, Al, Ge, Pb, and combinations thereof; a combination particle thereof, and an amorphous carbon precursor or a soft carbon precursor,
assembling the mixture to prepare an assembly in which the graphite pieces are linked to one another forming a curved side to form a first graphite particle and the at least second particle and the amorphous carbon precursor or soft carbon precursor are dispersed between the graphite pieces, and
heat-treating the assembly to carbonize the amorphous carbon precursor or the carbon precursor.
29. The method of claim 28 , wherein the graphite is flake-shaped graphite.
30. The method of claim 28 , further comprising isostatically pressuring the assembly, after preparing the assembly.
31. The method of claim 28 , further comprising mixing the assembly with an additional amorphous carbon precursor or soft carbon precursor, after preparing the assembly.