Nanoporous graphene nanowires and producing methods and applications of same
The invention relates to a material of porous graphene nanowires with a pore-rich structure, production methods and applications of the material of porous graphene nanowires. The method includes: synthesis of catalyst nanowires for porous graphene nanowires, chemical vapor deposition of a carbon source on the catalysts to grow graphene, removal of residual catalyst, and formation of the porous graphene nanowires. The porous graphene nanowires can be used as an electrochemical energy storage material, carriers of catalysts, a conductive material, an adsorption material, a desorption material, or the like.
1. A method for producing nanoporous graphene nanowires, comprising the steps of:
dissolving a magnesium compound into water to form a solution having a concentration of magnesium ions in a range of about 0.005-10.0 mol/L, and treating the solution under hydrothermal synthesis to obtain catalyst, wherein the step of treating the solution under the hydrothermal synthesis comprises heating the solution at a temperature in a range of about 100-300° C. for a period of time in a range of about 1-20 hours;
calcining the catalysts at a temperature in a range of about 100-800° C. to form porous catalyst nanowires;
introducing a carbon source to a reactor containing the porous catalyst nanowires at a temperature in a range of about 400-1500° C. to grow graphene on the porous catalyst nanowires, thereby forming a composite thereof; and
obtaining porous graphene nanowires from the formed composite.
2. The method according to the claim 1 , wherein the porous graphene nanowires have fiber morphology, with lengths in a range of about 0.5 μm to about 2 mm, and diameters in a range of about 10 nm to about 15 μm.
3. The method according to the claim 1 , wherein the porous graphene nanowires have a pore-rich structure, with a specific surface area in a range of about 1000-3000 m 2 /g.
4. The method according to the claim 1 , wherein the catalysts have nanowire morphology, with lengths in a range of about 0.5 μm to about 2 mm and diameters in a range of about 10 nm to about 15 μm.
5. The method according to the claim 1 , wherein the magnesium compound comprises magnesium oxide, magnesium hydroxide, magnesium chloride, magnesium nitrate, magnesium sulfate, magnesium acetate, magnesium carbonate, or any combination thereof.
6. The method according to the claim 1 , wherein the carbon source comprises hydrocarbon, or a heteroatom-containing organic compound.
7. The method according to the claim 6 , wherein the hydrocarbon comprises aromatic hydrocarbon, or non-aromatic hydrocarbon.
8. The method according to the claim 7 , wherein the aromatic hydrocarbon comprises benzene, toluene, xylene, or any combination thereof.
9. The method according to the claim 7 , wherein the non-aromatic hydrocarbon comprises methane, ethane, propane, ethylene, propylene, acetylene, or any combination thereof.
10. The method according to the claim 6 , wherein the heteroatom-containing organic compound comprises sucrose, glucose, polyimide, polyaniline, phenolic resin, thiophene, or any combination thereof.
11. The method according to the claim 1 , wherein the step of introducing the carbon source is performed with chemical vapor deposition.
12. The method according to the claim 11 , wherein a reaction time for the chemical vapor deposition is in a range of about 30 seconds to about 15 hours.
13. The method according to the claim 1 , wherein the step of obtaining the porous graphene nanowires comprises the steps of
dissolving the formed composite into an acid reagent; and
removing the porous catalyst nanowires from the dissolved composite to obtain the porous graphene nanowires.
14. The method according to the claim 13 , wherein the acid reagent comprises hydrochloric acid, acetic acid, nitric acid, or sulfuric acid.