Process for the treatment of a silicate mineral
A process for the treatment of a silicate mineral, includes: preparing a first composition including an alkali metal magnesium orthosilicate and optionally either (i) magnesium oxide or (ii) an alkali metal silicate, by reaction, at a temperature from 500 to 1200° C., of an alkali metal carbonate compound, which compound is an alkali metal carbonate, an alkali metal bicarbonate or a mixture thereof, with a magnesium silicate, the molar ratio of alkali metal carbonate compound, expressed as alkali metal oxide of the formula R 2 O, in which R represents an alkali metal, to magnesium silicate, expressed as silicon dioxide, of the formula SiO 2 , being from 4:1 to 1:4, and contacting the first composition with water to produce a second composition comprising an amorphous magnesium silicate hydrate (M-S—H).
1. A process for the treatment of a silicate mineral, said process comprising:
preparing a first composition comprising an alkali metal magnesium orthosilicate and optionally either (i) magnesium oxide or (ii) an alkali metal silicate, by reaction, at a temperature from 600° C. to 1000° C., of an alkali metal carbonate compound, which compound is an alkali metal carbonate, an alkali metal bicarbonate or a mixture thereof, with a magnesium silicate, the molar ratio of alkali metal carbonate compound, expressed as alkali metal oxide of the formula R 2 O, in which R represents an alkali metal, to magnesium silicate, expressed as silicon dioxide, of the formula SiO 2 , being from 4:1 to 1:4, wherein the reaction is obtained by contacting the alkali metal carbonate compound and the magnesium silicate to each other in a solid state, and
contacting the first composition with water to produce a second composition comprising an amorphous magnesium silicate hydrate (M-S—H).
2. A process according to claim 1 , wherein M-S—H is represented by an oxide formula in the form pMgO.SiO 2 .qH 2 O where p is from 0.5 to 2.0 and q is from 1 to 4.
3. A process according to claim 1 , wherein the magnesium silicate is a magnesium silicate in which the molar ratio of magnesium oxide to silica is from 0.5 to 3.
4. A process according to claim 1 , wherein the magnesium silicate comprises a magnesium silicate rock comprising a magnesium silicate of general composition:
m (MgO). t (QO).SiO 2 x H 2 O
wherein m is from 0.5 to 3, t is less than or equal to 1, x is from zero to 2, and Q represents a metal or metals other than magnesium.
5. A process according to claim 4 , wherein Q represents iron, nickel and/or chromium which process further comprises isolating an iron, nickel and/or chromium compound.
6. A process according to claim 1 , further comprising isolating or producing magnesium oxide, magnesium hydroxide or an alkali metal silicate from the second composition.
7. A process according to claim 1 , further comprising a step in which the second composition is carbonated to produce a third composition comprising a magnesium carbonate compound.
8. A process according to the claim 7 , further comprising a step in which the magnesium carbonate from the third composition is calcined to produce a fourth composition comprising magnesium oxide.
9. A process according to claim 7 , wherein the carbonation of the second composition is conducted in a second substep, after a first substep during which the second composition is formed by molding or pressing to form a shaped article, such that a carbonated shaped article is obtained.
10. A process according to claim 1 , wherein the temperature is from 800 to 1000° C.