Water-repellent, thermoplastic resin sheet, and molded article
Provided is a water-repellent, thermoplastic resin sheet including a textured layer which is formed from a polyethylene resin composition comprising a water repellent agent and which has a microscopic texture on one surface side, wherein at least the surface region of the textured layer is a cross-linked material which maintains the microscopic texture even after heated drawing. Also provided is a molded article, such as a molded container, formed by thermoforming the thermoplastic resin sheet.
1. A thermoplastic resin sheet having water repellence, comprising a textured layer formed from a polyethylene resin composition comprising a water repellent agent, having a microscopic texture on one surface side, wherein
at least a surface portion of the texture is a crosslinked material that maintains the microscopic texture even after heated drawing, and
the microscopic texture has bumps with bump heights of 70 to 200 μm.
2. The thermoplastic resin sheet according to claim 1 , wherein a styrenic resin layer is laminated on the other surface of the textured layer.
3. The thermoplastic resin sheet according to claim 2 , wherein a sealant resin layer is formed between the textured layer and the styrenic resin layer.
4. The thermoplastic resin sheet according to claim 1 wherein, on the other surface side of the textured layer, an oxygen barrier resin layer is laminated with one surface on the textured layer side such that, sequentially from the textured layer side, a sealant resin layer and a modified olefinic polymer resin layer are interposed therebetween, and on the other surface of the oxygen barrier resin layer, a styrenic resin layer is laminated such that a modified olefinic polymer resin layer is interposed therebetween.
5. The thermoplastic resin sheet according to claim 1 , wherein at least a surface portion on the one surface side of the textured layer is an electron beam-crosslinked material.
6. The thermoplastic resin sheet according to claim 1 , wherein the water repellent agent is a silicone-based water repellent agent and/or carnauba wax.
7. The thermoplastic resin sheet according to claim 1 , wherein the microscopic texture has bumps that are bell-shaped, with bump diameters of 80 to 500 μm and a bump pitch of 15 μm to 70 μm.
8. The thermoplastic resin sheet according to claim 1 , wherein the thermoplastic multilayered resin sheet has a drawing ratio for heated drawing of 0.05 to 2.5 times, and a rate of decrease of bump height of the textured layer before and after heated drawing is 30% or less.
9. The thermoplastic multilayered resin sheet according to claim 2 , wherein the styrenic resin layer is formed from a composition comprising, as a resin component, 10 to 50 mass % of a polystyrene resin and 90 to 50 mass % of a high-impact polystyrene resin, and further comprising 4.5 to 8.1 parts by mass of a rubber component with respect to 100 parts by mass of the resin component.
10. The thermoplastic multilayered resin sheet according to claim 3 wherein the sealant resin layer is formed from a resin composition comprising 90 to 95 mass % of a styrenic resin and 5 to 10 mass % of a hydrogenated styrenic thermoplastic elastomer, or 100 mass % of a hydrogenated styrenic thermoplastic elastomer, or 100 mass % of a modified olefinic polymer resin.
11. The thermoplastic multilayered resin sheet according to claim 4 , wherein the oxygen barrier resin layer comprises an ethylene-vinyl alcohol copolymer resin.
12. A molded article formed by thermoforming the thermoplastic multilayered resin sheet according to claim 1 .
13. The molded article according to claim 12 which is a molded container.
14. The molded article according to claim 13 which is a container adapted for containing a food product.
15. The molded article according to claim 14 which is a container adapted for containing yogurt.
16. The thermoplastic resin sheet according to claim 1 , wherein
the water repellent agent is a silicone-based water repellent agent comprising a composition comprising a silicone resin and a higher fatty acid amide and/or carnauba wax;
the silicone resin content with respect to the total mass of the polyethylene resin composition and the silicone-based water repellent agent is 2 to 10 mass %;
the content of carnauba wax with respect to the total mass of the polyethylene resin composition and the silicone-based water repellent agent is 3 to 10 mass %;
the polyethylene resin composition comprises linear low-density polyethylenes and/or linear medium-density polyethylenes;
at least a surface portion on the one surface side of the textured layer is an electron beam-crosslinked material formed by electron beam irradiation at an acceleration voltage of 110 to 250 kV and a radiation dose of 150 to 300 kGy;
the microscopic texture has bumps that are bell-shaped, with bump diameters of 80 to 500 μm and a bump pitch of 15 μm to 70 μm;
a thickness of the thermoplastic resin sheet is 500 μm to 1200 μm; and
the bumps are arranged in a grid arrangement positioned in columns and rows, or in a staggered arrangement.