Material for organic electroluminescent element, organic electroluminescent element, illumination device, and display device
A material for an organic electroluminescent element contains a compound represented by Formula (1): where R 1 to R 3 independently represent a group such as a deuterium atom and a halogen atom; at least one of R 1 to R 3 is a group represented by Formula (2); if pluralities of R 1 to R 3 are present, these substituents may be the same or different or may be bonded to each other to form a ring; n1 represents an integer of 0 to 8; n2 represents an integer of 0 to 3; n3 represents an integer of 0 to 4; n1+n2+n3 is 1 or more; Cbz represents a carbazolyl group; X represents an oxygen atom or a sulfur atom; and L 1 represents a single bond or a divalent linking group.
1. A material for an organic electroluminescent element, comprising a compound represented by Formula (4):
where R 2 , R 3 , R 1 ′, and R 1 ″ each independently represent a deuterium atom, a halogen atom, a cyano group, an alkyl group, an alkenyl group, an alkynyl group, an alkoxy group, a carbonyl group, an amino group, a silyl group, a hydroxy group, a thiol group, a phosphine oxide group, an aromatic hydrocarbon ring group, an aromatic heterocyclic group, a non-aromatic hydrocarbon ring group, or a non-aromatic heterocyclic group, and may further have an optional substituent; at least one of R 2 , R 3 , R 1 ′, and R 1 ″ is a group represented by Formula (2); if pluralities of R 2 's, R 3 's, R 1 ″'s, and R 1 ″'s are present, these R 2 's, R 3 's, R 1 ′'s, and R 1 ″'s may be the same or different or may be bonded to each other to form a ring; n2 represents an integer of 0 to 3; n3, n1a, and n1b each independently represent an integer of 0 to 4; n2+n3+n1a+n1b is 1 or more; X represents an oxygen atom or a sulfur atom; L1 represents a single bond or a divalent linking group
where * represents a binding site to the structure represented by Formula (4); L 2 represents a single bond; R 4 represents a substituent; R 5 represents a deuterium atom, a halogen atom, a cyano group, an alkyl group, an alkenyl group, an alkynyl group, an alkoxy group, a carbonyl group, a silyl group, a phosphine oxide group, an aromatic hydrocarbon ring group, an aromatic heterocyclic group bonded to a phenyl group via a carbon atom of the aromatic heterocyclic group, a non-aromatic hydrocarbon ring group, or a non-aromatic heterocyclic group; R 5 may further have optional substituents; if pluralities of R 5 's are present, these substituents may be the same or different, provided that R 5 's are not bonded to each other to form a ring; n4 represents an integer of 0; n5 represents an integer of 0 to 5; m represents an integer of 2 to 10.
2. The material for an organic electroluminescent element according to claim 1 ,
wherein the compound represented by Formula (4) is a compound represented by Formula (7):
where R 2 , R 3 , R 1 ′, R 1 ″, n2, n3, n1a, n1b, X, and L 1 are the same as R 2 , R 3 , R 1 ′, R 1 ″, n2, n3, n1a, n1b, X, and L 1 defined in Formula (4).
3. The material for an organic electroluminescent element according to claim 1 ,
wherein the group represented by Formula (2) is a group represented by Formula (5):
where * represents a binding site to a structure represented by Formula (4); L 2 represents a single bond; R 4 represents a substituent; R 5 represents a deuterium atom, a halogen atom, a cyano group, an alkyl group, an alkenyl group, an alkynyl group, an alkoxy group, a carbonyl group, a silyl group, a phosphine oxide group, an aromatic hydrocarbon ring group, a non-aromatic hydrocarbon ring group, or a non-aromatic heterocyclic group; R 5 may further have optional substituents, and the optional substituents may be bonded to each other to form a ring; if pluralities of R 5 's are present, these R 5 's may be the same or different provided that the R 5 's are not bonded to each other to form a ring; n4 represents an integer of 0; n5 represents an integer of 0 to 5; m represents an integer of 2 to 10.
4. The material for an organic electroluminescent element according to claim 1 ,
wherein m in Formula (2) represents an integer of 2 to 5.
5. The material for an organic electroluminescent element according to claim 1 ,
wherein L 1 in Formula (4) represents a single bond.
6. The material for an organic electroluminescent element according to claim 1 ,
wherein X in Formula (4) represents an oxygen atom.
7. An organic electroluminescent element, comprising:
an anode,
a cathode, and
an organic layer composed of at least one organic layer including a luminous layer, the organic layer being disposed between the anode and the cathode,
wherein the at least one organic layer contains the material for an organic electroluminescent element according to claim 1 .
8. The organic electroluminescent element according to claim 7 ,
wherein the at least one organic layer further contains a phosphorescent compound represented by Formula (DP):
where M represents Ir, Pt, Rh, Ru, Ag, Cu, or Os; A 1 , A 2 , B 1 , and B 2 each independently represent a carbon atom or a nitrogen atom; ring Z 1 represents a 6-membered aromatic hydrocarbon ring or 5- or 6-membered aromatic heterocyclic ring including A 1 and A 2 ; ring Z 2 represents a 5- or 6-membered aromatic heterocyclic ring including B 1 and B 2 ; ring Z 1 and ring Z 2 may have optional substituents, and the optional substituents may be bonded to form a fused ring structure; substituents of ligands may be bonded to each other to link the ligands; L′ represents a monoanionic bidentate ligand coordinated with M; m′ represents an integer of 0 to 2; n′ represents an integer of 1 to 3; m′+n′ is 2 or 3; if m′ and n′ both are 1 or more, ligands represented by ring Z 1 and ring Z 2 may be the same as or different from L′.
9. The organic electroluminescent element according to claim 7 , wherein a color of light emitted is white.
10. An illumination device, comprising the organic electroluminescent element according to claim 7 .
11. A display device, comprising the organic electroluminescent element according to claim 7 .