Thermal transfer film, method for manufacturing same, and organic electroluminescent device manufacturing therefrom
The present invention relates to a thermal transfer film comprising: a photothermal conversion layer; and a diffusion member formed on the upper surface of said photothermal conversion layer, wherein the diffusion member is a thermal transfer film having about 10% or more of the haze, and also relates to a method for manufacturing same, and to an organic electroluminescent device manufactured using said method.
1. A thermal transfer film comprising:
a light-to-heat conversion layer; and
a diffusion member formed on the upper surface of the light-to-heat conversion layer,
wherein the diffusion member has a haze of about 20% to 95%.
2. The thermal transfer film according to claim 1 , wherein the diffusion member comprises a base film having a diffusion layer formed thereon or a base film including a diffusing agent.
3. The thermal transfer film according to claim 2 , wherein the diffusion layer comprises at least one of an optical pattern layer and a diffusing agent-containing layer.
4. The thermal transfer film according to claim 3 , wherein the diffusion member comprises a base film having an optical pattern layer formed at a light incident portion of the thermal transfer film.
5. The thermal transfer film according to claim 4 , wherein a difference in refractive index between the optical pattern layer and the base film ranges from about 0.03 to about 0.2.
6. The thermal transfer film according to claim 4 , wherein the optical pattern layer comprises at least one optical pattern of a lenticular lens pattern, a microlens pattern, an embossed pattern, and a prism pattern.
7. The thermal transfer film according to claim 4 , wherein the optical pattern layer is integrally formed with the base film.
8. The thermal transfer film according to claim 4 , wherein the optical pattern layer further comprises a diffusing agent.
9. The thermal transfer film according to claim 3 , wherein the diffusion member comprises a base film having the diffusing agent-containing layer formed on one surface thereof.
10. The thermal transfer film according to claim 9 , wherein a difference in refractive index between a resin of the diffusing agent-containing layer and the diffusing agent ranges from about 0.03 to about 0.25.
11. The thermal transfer film according to claim 9 , wherein the diffusing agent-containing layer has a thickness of about 1 μm to about 20 μm.
12. The thermal transfer film according to claim 9 , wherein the diffusing agent-containing layer is formed of a composition comprising a UV curable resin and a diffusing agent.
13. The thermal transfer film according to claim 12 , wherein a difference in refractive index between the UV curable resin and the diffusing agent ranges from about 0.03 to about 0.2.
14. The thermal transfer film according to claim 12 , wherein the diffusing agent is contained in an amount of about 10 wt % to about 80 wt % in the diffusing agent-containing layer.
15. The thermal transfer film according to claim 12 , wherein the UV curable resin comprises at least one of (meth)acrylic, polycarbonate, styrene, olefin, and polyester resins.
16. The thermal transfer film according to claim 12 , wherein the diffusing agent comprises at least one of silica, styrene, (meth)acrylic, olefin, polyester, polycarbonate, siloxane, calcium carbonate, and aluminum oxide diffusing agents.
17. The thermal transfer film according to claim 9 , wherein the base film further comprises an optical pattern layer formed on the other surface thereof.
18. The thermal transfer film according to claim 17 , wherein the optical pattern layer comprises at least one of a lenticular lens pattern, a microlens pattern, an embossed pattern, and a prism pattern.
19. The thermal transfer film according to claim 2 , wherein the diffusion member is a base film comprising a diffusing agent.
20. The thermal transfer film according to claim 19 , wherein a difference in refractive index between the diffusing agent and the base film ranges from about 0.03 to about 0. 25.
21. The thermal transfer film according to claim 19 , wherein the diffusing agent is contained in an amount of about 2 wt % to about 50 wt % in the base film.
22. The thermal transfer film according to claim 19 , wherein the diffusing agent comprises at least one of silica, styrene, (meth)acrylic, olefin, polyester, polycarbonate, siloxane, calcium carbonate, and aluminum oxide diffusing agents.
23. The thermal transfer film according to claim 1 , wherein the light-to-heat conversion layer comprises a cured product of a composition comprising a curable resin, a polyfunctional monomer, and a light-to-heat conversion material.
24. The thermal transfer film according to claim 23 , wherein the light-to-heat conversion material comprises at least one of dyes, pigments, carbon black, and tungsten oxide fine particles.
25. The thermal transfer film according to claim 1 , further comprising:
an interlayer stacked on the lower surface of the light-to-heat conversion layer.
26. The thermal transfer film according to claim 25 , wherein the interlayer comprises a cured product of a composition comprising a curable resin, a polyfunctional monomer, a curable fluorine compound, and an initiator.
27. An organic electroluminescent device manufactured using the thermal transfer film according to claim 1 .
28. A method for manufacturing a thermal transfer film, comprising:
forming a diffusion member, and
forming a light-to-heat conversion layer on the diffusion member,
wherein the diffusion member has a haze of about 20% to 95%.
29. The method according to claim 27 , further comprising:
forming an interlayer on the light-to-heat conversion layer.