IP Library Granted Patent US 9,276,008
Granted Patent B2
US 9,276,008 · App. 14/661,729 · Granted Mar 1, 2016

Embedded NVM in a HKMG process

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Quick Facts
Patent No.
US 9,276,008
App. No.
14/661,729
Granted
Mar 1, 2016
Kind
B2
Abstract

A process integration is disclosed for fabricating complete, planar non-volatile memory (NVM) cells ( 110 ) prior to the formation of high-k metal gate electrodes for CMOS transistors ( 212, 213 ) using a planarized dielectric layer ( 26 ) and protective mask ( 28 ) to enable use of a gate-last HKMG CMOS process flow without interfering with the operation or reliability of the NVM cells.

Claims (26)

1. A method of making a semiconductor device comprising:

forming a non-volatile memory cell comprising a first patterned polysilicon gate electrode and aligned source/drain regions formed in a substrate;

forming a MOSFET transistor comprising a sacrificial polysilicon gate electrode and aligned source/drain regions formed in the substrate;

forming a planarized first dielectric layer over the semiconductor device to cover the non-volatile memory cell and MOSFET transistor except for a top portion of the first patterned polysilicon gate electrode and sacrificial polysilicon gate electrode;

selectively forming a patterned protective layer to cover the first patterned polysilicon gate electrode and to expose the sacrificial polysilicon gate electrode;

removing the sacrificial polysilicon gate electrode to form a gate electrode opening in the planarized first dielectric layer while protecting the first patterned polysilicon gate electrode with the patterned protective layer; and

forming a metal-gate electrode in the gate electrode opening while protecting the first patterned polysilicon gate electrode with the patterned protective layer.

2. The method of claim 1 , further comprising removing the patterned protective layer and planarizing the semiconductor device with a chemical mechanical polish process.

3. The method of claim 1 , where forming the non-volatile memory cell comprises forming a split-gate flash memory cell comprising a patterned polysilicon control and select gate structure with aligned source/drain regions formed in the substrate.

4. The method of claim 1 , where forming the non-volatile memory cell comprises forming a split-gate memory cell with a charge storage layer containing nanoclusters.

5. The method of claim 1 , where forming the non-volatile memory cell comprises forming a memory cell with a charge storage layer containing silicon nitride.

6. The method of claim 1 , where forming the non-volatile memory cell comprises forming a memory cell comprising a nitride storage layer and a patterned polysilicon control gate structure with aligned source/drain regions formed in the substrate.

7. The method of claim 1 , where forming the planarized first dielectric layer comprises:

depositing a conformal oxide layer to cover the non-volatile memory cell and the MOSFET transistor, and

planarizing the conformal oxide layer with a chemical mechanical polish process to form the planarized first dielectric layer.

8. The method of claim 5 , where removing the sacrificial polysilicon gate electrode comprises:

applying one or more poly etch processes to remove one or more polysilicon layers from the sacrificial polysilicon gate electrode; and

applying one or more dielectric etch processes to remove one or more gate dielectric layers exposed by removing the sacrificial polysilicon gate electrode, thereby exposing the substrate with gate electrode opening in the planarized first dielectric layer.

9. The method of 8 , where forming the metal-gate electrode comprises:

forming one or more high-k dielectric layers in the gate electrode opening using a metal oxide layer or a hafnium-based dielectric layer; and

depositing one or more metal gate electrode layers over the one or more high-k dielectric layers to fill the gate electrode opening; and

removing the patterned protective layer and forming a high-k metal-gate electrode that is substantially coplanar with the first patterned polysilicon gate electrode.

10. The method of 8 , where forming the metal-gate electrode comprises:

forming one or more high-k dielectric layers in the gate electrode opening using a metal oxide layer or a hafnium-based dielectric layer; and

depositing one or more metal gate electrode layers over the one or more high-k dielectric layers to fill the gate electrode opening; and

applying one or more polish and/or etch steps to remove the patterned protective layer and form a high-k metal-gate electrode that is substantially coplanar with the first patterned polysilicon gate electrode.

Assignments (22)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042985 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042762 FRAME 0145. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051145/0184 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051030/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0387 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050745/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042985/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042762/0145 →
MERGER Recorded Jan 3, 2017
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
Reel/Frame 041144/0363 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12092129 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Jul 14, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039361/0212 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
SECURITY AGREEMENT SUPPLEMENT Recorded Mar 7, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 038017/0058 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 7, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 7, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037458/0359 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037357/0974 →
SUPPLEMENT TO IP SECURITY AGREEMENT Recorded May 4, 2015
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 035571/0095 →
SUPPLEMENT TO IP SECURITY AGREEMENT Recorded May 4, 2015
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
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SUPPLEMENT TO IP SECURITY AGREEMENT Recorded May 4, 2015
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 035571/0112 →