Metal-organic frameworks for adsorption and separation of noble gases

1. A method comprising:

exposing a gas mixture comprising a noble gas to a metal organic framework (MOF), including an organic electron donor having the formula of:

wherein R 1 and R 2 are independently selected from a branched or straight chain alkyl moiety that may be substituted, or

wherein R a , R b , R c , R d , R e , R f , R g , and R h are independently selected from a hydrogen moiety, a straight or branched chain alkyl moiety having one to three carbons, an amine moiety, an ether moiety or a halide moiety and R i and R j are independently selected from a trifluoromethyl, a straight or branched chain alkyl moiety having one to three carbons, or a phenyl moiety; with the proviso that R a , R b , R c , R d , R e , R f , R g , and R h are not each selected from a hydrogen moiety when R i and R j are each a trifluoromethyl moiety.

2. The method of claim 1 , wherein the electron donor is the electron donor of General Formula I and R 1 and R 2 are independently an alkyl moiety having one to three carbon atoms.

3. The method of claim 2 , wherein R 1 and R 2 are each an ethyl moiety.

4. The method of claim 2 , wherein R 1 and R 2 are each a methyl moiety.

5. The method of claim 2 , wherein R 1 and R 2 area methyl moiety and an ethyl moiety, respectively.

6. The method of claim 1 , wherein the electron donor is the electron donor of General Formula II and R i and R j are each trifluoromethyl.

7. The method of claim 6 , wherein R c and R f are each an unsubstituted amine moiety.

8. The method of claim 6 , wherein R c and R f are each a methyl moiety.

9. The method of claim 6 , wherein R b , R c , R f and R g are each a chloride moiety.

10. The method of claim 1 , wherein the electron donor is the electron donor of General Formula II and R i and R j are each ethyl.

11. The method of claim 1 , wherein the electron donor is the electron donor of General Formula II and R i and R j are each phenyl.

12. The method of claim 1 , wherein exposing the gas mixture to the MOF comprises exposing at a first pressure for a first time period and, after the first time period, the method comprises exposing any noble gas adsorbed to the MOF to a different second pressure.

13. The method of claim 1 , wherein exposing the gas mixture to the MOF comprises exposing at a first temperature for a first time period and, after the first time period, the method comprises exposing any noble gas adsorbed to the MOF to a different second temperature.

14. An adsorbent bed operable to adsorb a noble gas from a mixture of gases, the adsorbent bed comprising:

a metal organic framework (MOF) including an organic electron donor having the formula of:

wherein R 1 and R 2 are independently selected from a branched or straight chain alkyl moiety that may be substituted, or

wherein R a , R b , R c , R d , R e , R f , R g and R h are independently selected from a hydrogen moiety, a straight or branched chain alkyl moiety having one to three carbons, an amine moiety, an ether moiety or a halide moiety and R i and R j are independently selected from a trifluoromethyl, a straight or branched chain alkyl moiety having one to three carbons, or a phenyl moiety; with the proviso that R a , R b , R c , R d , R e , R f , R g , and R h are not each selected from a hydrogen moiety when R i and R j are each a trifluoromethyl moiety.

15. The bed of claim 14 , wherein the electron donor is the electron donor of General Formula I and R 1 and R 2 are independently an alkyl moiety having one to three carbon atoms.

16. The bed of claim 15 , wherein R 1 is an ethyl moiety.

17. The bed of claim 14 , wherein the electron donor is the electron donor of General Formula II and R i and R j are each trifluoromethyl.

18. A method comprising:

exposing a gas mixture comprising a noble gas to a metal organic framework (MOF) comprising cobalt formate; and

separating the noble gas from the gas mixture.