Photocatalyst
A photocatalyst includes a composite fiber having at least two crystalline semi-conductors that provide a heterojunction structure in the composite fiber.
1. A photocatalyst comprising a composite fiber including at least three n-type crystalline semiconductor materials, wherein
the n-type crystalline semiconductor materials form a heterojunction structure in the composite fiber, and
the n-type crystalline semiconductor materials include bismuth oxide, titanium dioxide, and zinc oxide.
2. The photocatalyst of claim 1 , wherein the n-type crystalline semiconductor materials have band position alignments which allow vectorial displacement of electrons and holes.
3. The photocatalyst of claim 1 , wherein the composite fiber includes a p-type semiconductor material selected from the group consisting of copper (I) oxide, copper (II) oxide, cadmium telluride, and combinations thereof.
4. The photocatalyst of claim 1 , wherein the n-type crystalline semiconductor materials are prepared from a precursor solution including bismuth oxide in a concentration from about 0.1% to about 1%, a precursor solution including zinc oxide in a concentration from about 0.1% to about 1%, and a precursor solution including titanium dioxide in a concentration from about 1% to about 10%.
5. The photocatalyst of claim 1 , wherein the composite fiber has a nanostructure.
6. The photocatalyst of claim 1 , wherein
the photocatalyst is capable of removing a contaminant from a fluid stream, and
the contaminant comprises a pollutant.
7. The photocatalyst of claim 1 , wherein the composite fiber further comprises a polymer coating.
8. The photocatalyst of claim 1 , further comprising a substrate holding the composite fiber.
9. The photocatalyst of claim 8 , wherein the substrate is transparent to light and is gas permeable.
10. The photocatalyst of claim 8 , wherein the substrate is flexible.
11. The photocatalyst of claim 8 , wherein the substrate is a network with a nanostructure.
12. The photocatalyst of claim 11 , wherein the network structure consists of polymeric fibers.
13. The photocatalyst of claim 12 , wherein the polymeric fibers include nylon.
14. The photocatalyst of claim 8 , wherein the composite fiber is selected from the group consisting of nanofibers, truncated nanofibers, nanowires, nanorods, and combinations thereof.
15. A photocatalyst comprising a composite fiber including at least two crystalline semiconductor materials, wherein
the at least two crystalline semiconductor materials form a heterojunction structure in the composite fiber, and
one of the at least two crystalline semiconductor materials is prepared from a precursor solution including bismuth oxide in a concentration from about 0.1% to about 1%, a precursor solution including zinc oxide in a concentration from about 0.1% to about 1%, and a precursor solution including titanium dioxide in a concentration from about 1% to about 10%.
16. The photocatalyst of claim 15 , wherein one of the crystalline semiconductor materials is a p-type semiconductor material selected from the group consisting of copper (I) oxide, copper (II) oxide, cadmium telluride, and combinations thereof.
17. The photocatalyst of claim 15 , wherein the composite fiber further comprises a polymer coating.
18. A photocatalyst comprising a composite fiber including at least two n-type crystalline semiconductor materials, wherein
the at least two n-type crystalline semiconductor materials form a heterojunction structure in the composite fiber,
the at least two n-type crystalline semiconductor materials have band position alignments which allow vectorial displacement of electrons and holes,
one of the at least two n-type semiconductor materials is bismuth oxide, and
the composite fiber includes a p-type semiconductor material selected from the group consisting of copper (I) oxide, copper (II) oxide, cadmium telluride, and combinations thereof.
19. The photocatalyst of claim 18 , wherein the at least two n-type crystalline semiconductor materials include titanium dioxide, zinc oxide, and bismuth oxide.
20. The photocatalyst of claim 19 , wherein the n-type crystalline semiconductor materials are prepared from a precursor solution including bismuth oxide in a concentration from about 0.1% to about 1%, a precursor solution including zinc oxide in a concentration from about 0.1% to about 1%, and a precursor solution including titanium dioxide in a concentration from about 1% to about 10%.
21. The photocatalyst of claim 18 , wherein the composite fiber has a nanostructure.
22. The photocatalyst of claim 18 , wherein
the photocatalyst is capable of removing a contaminant from a fluid stream, and
the contaminant comprises a pollutant.
23. The photocatalyst of claim 18 , wherein the composite fiber further comprises a polymer coating.
24. The photocatalyst of claim 18 , further comprising a substrate holding the composite fiber.
25. The photocatalyst of claim 24 , wherein the substrate is transparent to light and is gas permeable.
26. The photocatalyst of claim 24 , wherein the substrate is flexible.
27. The photocatalyst of claim 24 , wherein the substrate is a network with a nanostructure.
28. The photocatalyst of claim 27 , wherein the network structure consists of polymeric fibers.
29. The photocatalyst of claim 28 , wherein the polymeric fibers include nylon.