Conversion of 2,3-butanediol to 2-butanol, olefins and fuels
Embodiments of an integrated method for step-wise conversion of 2,3-butanediol to 2-butanol, and optionally to hydrocarbons, are disclosed. The method includes providing an acidic catalyst, exposing a composition comprising aqueous 2,3-butanediol to the acidic catalyst to produce an intermediate composition comprising methyl ethyl ketone, providing a hydrogenation catalyst that is spatially separated from the acidic catalyst, and subsequently exposing the intermediate composition to the hydrogenation catalyst to produce a composition comprising 2-butanol. The method may further include subsequently exposing the composition comprising 2-butanol to a deoxygenation catalyst, and deoxygenating the 2-butanol to form hydrocarbons. In some embodiments, the hydrocarbons comprise olefins, such as butenes, and the method may further include subsequently exposing the hydrocarbons to a hydrogenation catalyst to form saturated hydrocarbons.
1. A method, comprising:
converting 2,3-butanediol to 2-butanol by
exposing a composition comprising aqueous 2,3-butanediol to an acidic catalyst to produce an intermediate composition comprising methyl ethyl ketone, and
subsequently exposing the intermediate composition to a hydrogenation catalyst to produce a composition comprising 2-butanol, wherein the hydrogenation catalyst is spatially separated from the acidic catalyst.
2. The method of claim 1 , wherein the composition comprises 50-95 wt % 2,3-butanediol.
3. The method of claim 1 , wherein the acidic catalyst is a solid acid catalyst.
4. The method of claim 1 , wherein the acidic catalyst comprises an H-ZSM-5 zeolite, an amorphous silicoaluminate, alumina, niobic acid, or a combination thereof.
5. The method of claim 1 , wherein the composition is exposed to the acidic catalyst at a temperature within a range of 150° C. to 500° C. and/or at a pressure within a range of 10 psig to 1200 psig.
6. The method of claim 1 , wherein the hydrogenation catalyst comprises Ru/C, Raney nickel, Re/Ni/C, Pt/C, or a combination thereof.
7. The method of claim 1 , wherein the intermediate composition is exposed to the hydrogenation catalyst at a temperature within a range of 60° C. to 300° C. and/or a pressure within a range of 10 psig to 1200 psig.
8. The method of claim 1 , further comprising:
subsequently exposing the composition comprising 2-butanol to a deoxygenation catalyst; and
deoxygenating the 2-butanol to produce hydrocarbons.
9. The method of claim 8 , wherein the deoxygenation catalyst comprises a solid acid catalyst.
10. The method of claim 8 , wherein:
the 2-butanol is exposed to the deoxygenation catalyst at a temperature within a range of 200° C. to 275° C., and the hydrocarbons comprise unbranched C4-C12 olefins, branched C4-C12 olefins, or a combination thereof;
the 2-butanol is exposed to the deoxygenation catalyst at a temperature between 275° C. and 350° C., and the hydrocarbons comprise a mixture of aromatics, unbranched olefins, and branched olefins; or
the 2-butanol is exposed to the deoxygenation catalyst at a temperature within a range of 350° C. to 500° C., and the hydrocarbons comprise at least 40% aromatic hydrocarbons.
11. The method of claim 8 , wherein the hydrocarbons comprise olefins, the method further comprising exposing the olefins to a subsequent hydrogenation catalyst to form saturated hydrocarbons.
12. The method of claim 1 , wherein the acidic catalyst is disposed within a first column, the hydrogenation catalyst is disposed within a second column, and the method further comprises:
flowing the aqueous composition comprising 2,3-butanediol through the first column to produce the intermediate composition; and
concurrently flowing the intermediate composition and hydrogen through the second column to produce the composition comprising 2-butanol.
13. The method of claim 12 , further comprising concurrently flowing hydrogen through the first column with the composition.
14. The method of claim 12 , wherein a deoxygenation catalyst is disposed within a third column, and the method further comprises flowing the composition comprising 2-butanol through the third column to produce hydrocarbons.
15. The method of claim 14 , wherein the hydrocarbons comprise olefins, a hydrogenation catalyst is disposed within a fourth column, and the method further comprises flowing the hydrocarbons through the fourth column to produce saturated hydrocarbons.
16. A method, comprising:
converting 2,3-butanediol to hydrocarbons by
flowing an aqueous composition comprising 50-95 wt % 2,3-butanediol through an acidic catalyst bed disposed in a first column to produce an intermediate composition comprising methyl ethyl ketone,
flowing the intermediate composition and hydrogen concurrently through a hydrogenation catalyst bed disposed in a second column to produce a composition comprising 2-butanol, and
flowing the composition comprising 2-butanol through a deoxygenation catalyst bed disposed in a third column to produce hydrocarbons.
17. The method of claim 16 , wherein the hydrocarbons comprise olefins, the method further comprising flowing the hydrocarbons through a subsequent hydrogenation catalyst disposed in a fourth column to produce saturated hydrocarbons.
18. A method, comprising:
concurrently flowing hydrogen and an aqueous composition comprising 50-95 wt % 2,3-butanediol through a column including an acidic catalyst bed and a hydrogenation catalyst bed positioned distal to the acidic catalyst bed to produce a composition comprising 2-butanol.
19. The method of claim 18 , wherein the column further includes a deoxygenation catalyst bed positioned distal to the hydrogenation catalyst bed, and flowing the composition comprising aqueous 2,3-butanediol through the column produces a composition comprising hydrocarbons.
20. The method of claim 19 , wherein the column further includes a subsequent hydrogenation catalyst bed positioned distal to the deoxygenation catalyst bed, and flowing the composition comprising aqueous 2,3-butanediol through the column produces a composition comprising saturated hydrocarbons.