Anode for lithium batteries, lithium battery and method for preparing anode for lithium batteries
In forming an anode by using metallic lithium as the anode active material, the present invention provides an anode for lithium batteries which can be produced with high productivity and in which dendrite generation is prevented, so that high safety can he secured. An anode for lithium batteries according to an embodiment of the present invention comprises a structure comprising a conductive material layer in which carbon nanotubes are anchored, with a part of the carbon nanotube extending from at least one face of the surfaces of the conductive material layer, and a deposited layer formed by depositing metallic lithium on the carbon nanotubes in the structure.
1. An anode for use in a lithium battery comprising:
a conductive material layer having a flat surface for facing a separator in a lithium battery;
a plurality of randomly-spaced-and-shaped carbon nanotubes anchored in the conductive material layer, wherein each of the randomly-spaced-and-shaped carbon nanotubes comprises a portion protruding from the flat surface of the conductive material layer; and
a layer of metallic lithium placed over the plurality of randomly-spaced-and-shaped carbon nanotubes and the flat surface, wherein the layer of metallic lithium and the plurality of randomly-spaced-and-shaped carbon nanotubes in combination provide a plurality of randomly-spaced-and-shaped protrusions having a randomly-shaped metallic surface of lithium over the flat surface of the conductive material layer,
wherein in a cross-sectional perpendicular to the flat surface, the randomly-shaped metallic surface of lithium provides a randomly-shaped recess between two immediately neighboring ones of the plurality of randomly-spaced-and-shaped carbon nanotubes such that at least part of the metallic lithium deposition to the anode according to charging of the lithium battery is received in the randomly-shaped recess to suppress growth of metallic lithium dendrite toward the separator.
2. The anode according to claim 1 , wherein the density of the plurality of randomly-spaced-and-shaped carbon nanotubes protruding from the flat surface of the conductive material layer is 0.1 mg/cm 2 to 10 mg/cm 2 .
3. The anode according to claim 1 , wherein the amount of the metallic lithium in the metallic lithium layer placed over the plurality of randomly-spaced-and-shaped carbon nanotubes is 0.01 mg/cm 2 to 5 mg/cm 2 .
4. The anode according to claim 1 , wherein the plurality of randomly-spaced-and-shaped carbon nanotubes comprise carbon nanofibers.
5. The anode according to claim 1 , wherein the lithium batteries are secondary batteries.
6. A lithium battery comprising:
an anode according to claim 1 ;
a cathode;
a separator separating between the cathode and the anode; and
an electrolytic solution comprising lithium ions, the lithium ions being able to move across the separator.