Adhesive film and optical display including the same
An adhesive film and an optical display, the adhesive film being prepared from an adhesive composition that includes a (meth)acrylic copolymer, wherein the adhesive film has an elongation of about 750% to about 3,000%, and satisfies the following Equation 1: PB/PY=about 3.0 to about 20, wherein PB is a break point in gf of the adhesive film and PY is a yield point in gf of the adhesive film.
1. An adhesive film prepared from an adhesive composition that includes a (meth)acrylic copolymer, a crosslinking agent, and an initiator,
wherein the adhesive film:
has an elongation of about 750% to about 3,000% when measured as described in the instant application, and
satisfies the following Equation 1:
PB/PY=about 3.0 to about 20, [Equation 1]
wherein PB is a break point of the adhesive film and PY is a yield point of the adhesive film when measured as described in the instant application,
wherein the (meth)acrylic copolymer is prepared from:
a monomer mixture that includes 80 wt % to 85 wt % of a C 8 to C 20 alkyl group-containing (meth)acrylic monomer, greater than 6 wt % to about 15 wt % of a carboxylic acid group-containing (meth)acrylic monomer, and about 1 wt % to about 10 wt % of a hetero-alicyclic group-containing (meth)acrylic monomer in which a heteroatom thereof includes nitrogen or sulfur, all wt % being based on a total weight of the monomer mixture,
wherein the yield point and break point are determined as follows:
the adhesive film is cut into a dog bone shape and the yield point and the break point are measured using a TA instrument such that the adhesive film is secured to the TA instrument and stretched at a speed of 2,400 mm/min, wherein the yield point is a stress at which the specimen begins to deform physically, and the break point is a stress immediately before fracture of the specimen occurs, and
wherein the elongation is determined as follows:
the adhesive film is cut into a dog bone shape and the elongation is measured using a TA instrument such that the adhesive film is secured to the TA instrument and stretched at 2,400 mm/min, wherein the elongation is calculated according to the following equation: (Extended length until fracture upon application of tensile stress)/(original length)×100.
2. The adhesive film as claimed in claim 1 , wherein the adhesive film has an elongation of about 750% to about 1,500% when measured as described in the instant application.
3. The adhesive film as claimed in claim 1 , wherein the adhesive film satisfies the following Equation 1:
PB/PY=about 3.0 to about 5.0, [Equation 1]
wherein PB is a break point of the adhesive film and PY is a yield point of the adhesive film when measured as described in the instant application.
4. The adhesive film as claimed in claim 1 , wherein the adhesive composition further includes a silane coupling agent.
5. An optical display comprising the adhesive film as claimed in claim 1 .
6. The optical display as claimed in claim 5 , wherein the optical display includes:
a substrate;
an OLED element on the substrate;
an encapsulation layer encapsulating the OLED element; and
a first adhesive film on the encapsulation layer, the first adhesive film including the adhesive film.