Methods for forming a string of memory cells and apparatuses having a vertical string of memory cells including metal
View Patent ↗A method for forming a string of memory cells, a memory device having a string of memory cells, and a system are disclosed. The string of memory cells can include a string of planar memory cells formed as recesses in each of a plurality of control gate material formed as a vertical stack of alternating insulator and control gate material. The recesses can be lined with a dielectric material and filled with a floating gate material. Metal nano-particles can be formed on a surface of the floating gate material and/or infused into the floating gate material.
1. A memory apparatus, comprising:
a vertical string of memory cells formed at least partially in a stack of materials comprising a plurality of alternating levels of control gate material and insulator material;
wherein the stack of materials further comprises, beneath the alternating levels of control gate material and insulator material, a source, a source gate select (SGS) level above the source, a first oxide level above the SGS level, a high-K dielectric level on the first oxide level, and a second oxide level on the high-K dielectric level;
a first semiconductor material filling a trench in the SGS level, the first semiconductor material isolated from the material of the SGS level to form a channel for SGS transistors; the first semiconductor material located beneath at least a portion of the high-K dielectric level;
wherein the memory cells of the string comprise,
floating gate material comprising polysilicon, the floating gate material located between respective alternating layers of insulator material and having a first surface adjacent to respective control gate material of the levels of control gate material extending between such respective alternating layers of insulator material;
tunnel dielectric material contacting the floating gate material, on a second surface opposite the first surface of the floating gate material;
metal along an interface between the tunnel dielectric material and the floating gate material, wherein the metal comprises metal nano-particles infused into the floating gate material; and
a second semiconductor material adjacent to the tunnel dielectric material, the second semiconductor material forming a memory cell channel for the string of memory cells, the second semiconductor material coupled to the first semiconductor material.
2. The apparatus of claim 1 , wherein the control gate material comprises polysilicon, the apparatus further comprising interpoly dielectric material formed between the level of control gate material and the floating gate material.
3. The apparatus of claim 1 , wherein metal along an interface between the tunnel dielectric and the floating gate further comprises metal nano-particles covered by the tunnel dielectric.
4. The apparatus of claim 1 , wherein metal along an interface between the tunnel dielectric material and the floating gate material further comprises metal nano-particles on the surface of the floating gate material.
5. The apparatus of claim 1 , wherein metal along an interface between the tunnel dielectric material and the floating gate material further comprises metal nano-particles on the surface of the floating gate material and covered by the tunnel dielectric material.
6. The apparatus of claim 1 , wherein the apparatus comprises a system including a controller coupled to a memory device including the string of memory cells.
7. An apparatus, comprising:
levels of control gate material insulated from adjacent levels of control gate materials by alternating levels of insulator material;
additional levels of material beneath the alternating levels of control gate material and insulator material, comprising a source level, a source gate select (SGS) level above the source level, a first oxide level above the SGS level, a high-K dielectric level on the first oxide level, and a second oxide level on the high-K dielectric level;
a first semiconductor material filling a trench in the SGS level, the first semiconductor material isolated from the material of the SGS level to form a channel for SGS transistors; the first semiconductor material located beneath at least a portion of the high-K dielectric level;
a string of memory cells formed between the alternating layers of insulating material, comprising,
recesses in the levels of control gate material;
respective dielectric material in the recesses adjacent to the control gate material;
respective floating gate material comprising polysilicon in the recesses;
tunnel dielectric material contacting the floating gate material, with the floating gate material extending within the respective recess and between the tunnel dielectric material and the dielectric material adjacent the control gate material; and
metal nano-particles disposed along an interface between the tunnel dielectric material and the floating gate material, including metal nano-particles infused into the floating gate material; and
a second semiconductor material adjacent to the tunnel dielectric material of the memory cells, the second semiconductor material forming a memory cell channel for the string of memory cells, the second semiconductor material coupled to the first semiconductor material.
8. The apparatus of claim 7 , further comprising levels of insulator material alternating between adjacent levels of control gate material.
9. The apparatus of claim 7 , wherein the dielectric material is an oxide-nitride-oxide film.
10. The apparatus of claim 7 , wherein the metal nano-particles comprise one or more of:
ruthenium (Ru), ruthenium oxide (RuO x , titanium nitride (TiN), titanium aluminum nitride (TiAlN), tungsten nitride (WN), tungsten carbon nitride (WCN), tungsten silicide (WSi x ), tantalum nitride (TaN), tantalum aluminum nitride (TaAlN),ruthenium silicide (RuSi), hafnium silicide (HfSi), hafnium (Hf), zirconium (Zr), zirconium silicide (ZrSi), cobalt silicide (CoSi), or nickel silicide (NiSi).
11. The apparatus of claim 7 , wherein the floating gate material comprises a polysilicon material.
12. The apparatus of claim 7 , wherein the metal is a nitridization stabilized metal.
13. The apparatus of claim 1 , further comprising a buffer level above the source and beneath the SGS level.
14. The apparatus of claim 1 , wherein the buffer level comprises polysilicon.
15. The apparatus of claim 1 , further comprising an insulator level above the source and beneath the SGS level.
16. The apparatus of claim 1 , further comprising a buffer level comprising polysilicon located between the source and the insulator level; wherein the first semiconductor material extends through the insulator level to contact the buffer level.
17. The apparatus of claim 1 , further comprising dielectric material formed between the control gate material and the floating gate material.