Electrolyte for electrochemical energy storage devices
An electrolyte for an electrochemical storage device is disclosed. In one embodiment, the electrolyte includes a lithium salt from about 3% to about 20% by weight, a primary solvent from about 15% to about 25% by weight, wide-temperature co-solvents from about 14% to about 55% by weight, interface forming compounds from about 0.5% to about 2.0% by weight, and a flame retardant compound from about 6% to about 60% by weight. The electrolyte interacts with the positive and negative electrodes of the electrochemical storage device to provide both high performance and improved safety such that the electrolyte offers adequate ionic conductivity over the desired operating temperature range, a wide electrochemical stability window, high capacities for both the cathode and anode, low electrode-electrolyte interfacial resistance, and reduced flammability.
1. An electrolyte for an electrochemical storage device, the electrolyte comprising:
a lithium salt from about 3% to about 20% by weight;
a primary solvent from about 15% to about 25% by weight;
wide-temperature co-solvents from about 14% to about 55% by weight;
interface forming compounds from about 0.5% to about 2.0% by weight; and
a flame retardant compound from about 6% to about 60% by weight, wherein the flame retardant compound is 2-ethoxy-2,4,4,6,6-pentafluoro-1,3,5,2λ5, 4λ5, 6λ5 triazatriphosphinine,
wherein the electrolyte interacts with at least one positive electrode configured to store and release lithium-ions and at least one negative electrode configured to store and release lithium-ions, the at least one positive electrode and the at least one negative electrode forming portions of the electrochemical storage device and at least one of the solvent or co-solvent comprises methyl butyrate.
2. The electrolyte as recited in claim 1 , wherein the electrochemical storage device further comprises a device selected from the group consisting of batteries, lithium-ion batteries, and supercapacitors.
3. The electrolyte as recited in claim 1 , wherein the electrochemical storage device further comprises a lithium-ion battery.
4. The electrolyte as recited in claim 1 wherein the lithium salt further comprises a salt selected from the group consisting of lithium hexafluorophosphate, lithium bistrifluoromethanesulfonimide (LiTFSI), lithium tetrafluoroborate (LiBF 4 ), and combinations thereof.
5. The electrolyte as recited in claim 1 , wherein the lithium salt further comprises lithium hexafluorophosphate.
6. The electrolyte as recited in claim 1 , wherein the electrochemical storage device further comprises a lithium-ion battery.