Multidimensional spectrometer
View Patent ↗A multidimensional spectrometer encodes frequency information into laser pulses so that a frequency insensitive detector may be used to collect data for a multi-dimensional spectrograph only from intensity information and knowledge of a modulation providing the encoding. In one embodiment the frequency encoding may be done by a conventional interferometer greatly simplifying construction of the spectrometer.
1. A multi-dimensional spectrometer comprising:
a first spectral modulator producing at least one first modulated light pulse passing along a first optical path;
a second spectral modulator producing at least one second modulated light pulse passing along a second optical path;
a sample volume positioned at an intersection of the first and second light pulses;
a detector positioned to measure an intensity of at least one of the first and second light pulses after passage through the sample volume; and
a controller communicating with the detector and the first and second spectral modulator and operating to collect the intensity measured soley by the detector and modulation information during a modulation of the first and second light pulses so as to permit generation of a two dimensional spectrum of a sample in the sample volume solely from the intensity and modulation information;
wherein the detector provides the intensity without discriminating among light frequencies.
2. The multi-dimensional spectrometer of claim 1 wherein the detector is a single photo detector.
3. The multi-dimensional spectrometer of claim 1 wherein the first and second spectral modulators are pulse shapers.
4. The multi-dimensional spectrometer of claim 3 wherein the pulse shapers provide a spectrally dispersing element followed by a spectrally reconstituting element, the spectrally dispersing element and spectrally reconstituting element positioned on either side of an electrically controlled spatial modulator.
5. The multi-dimensional spectrometer of claim 1 further including a processor receiving only intensity data from the detector and modulation data from a controller and applying a multi-dimensional Fourier transform to the data as a function of the modulation to provide a multi-dimensional spectrograph of a sample in the sample volume.
6. The multi-dimensional spectrometer of claim 1 further including a polarizer setting a polarization of a least one of the first and second light pulses.
7. The multi-dimensional spectrometer of claim 1 further including an electronically controlled phase shifting device communicating with the controller to alter the phase of at least one of the light pulses in the first and second pair of light pulses.
8. The multi-dimensional spectrometer of claim 1 wherein the first and second light paths are angled with respect to each other and further including a beam stop for absorbing an other of the first and second light pulses not received by the detector.
9. The multi-dimensional spectrometer of claim 1 further including at least one beam position detector and wherein the controller further operates to automatically align the first and second light pulses with the sample volume by monitoring the beam position detector.
10. The multi-dimensional spectrometer of claim 1 further including a beam splitter receiving a light pulse from a single laser source to provide a received light pulse to the first and second spectral modulator; and
further including an optical delay element positioned in an optical path of at least one of the first and second spectral modulators; and
wherein the controller further communicates with the optical delay element to control a time separation between the first and second light pulses.
11. A method of generating a multi-dimensional spectrograph comprising the steps of:
(a) generating at least one first light pulse passing along a first optical path;
(b) generating at least one second light pulse passing along a second optical path intersecting the first optical path at a sample volume holding a material to be analyzed;
(c) detecting an intensity of at least one of the first and second light pulses after passage through the material using a detector providing a measure of light intensity without discriminating among light frequencies; and
(d) modulating the first and second light pulses to permit generation of a two dimensional spectrum of a sample in the sample volume solely from the detected intensity and modulation information.
12. The method of claim 11 wherein the detector is a single photo detector.
13. The method of claim 11 wherein the first and second spectral modulators are pulse shapers.
14. The method of claim 13 wherein the pulse shapers provide a spectrally dispersing element followed by a spectrally reconstituting element, the spectrally dispersing element and spectrally reconstituting element positioned on either side of an electrically controlled spatial modulator.
15. The method of claim 11 further including a processor receiving only intensity data from the detector and modulation data from a controller and applying a multi-dimensional Fourier transform to the data as a function of the modulation to provide a multi-dimensional spectrograph of a sample in the sample volume.
16. The method of claim 11 further including the step of applying a two-dimensional Fourier transform to detected intensity information to provide a two-dimensional spectrograph of a sample in the sample volume.
17. The method of claim 1 wherein the controller outputs a two-dimensional spectrograph.