Multilayer film for resealable packaging having improved resealing
Multilayer film comprising two thin layers D and E of a thermoplastic material bonded to one another by a continuous layer A that is a hot-melt pressure-sensitive adhesive composition: a composition of styrene block copolymers (a mixture of diblock and triblock copolymers); and one or more tackifying resins with a softening temperature of 5 to 140° C.; the adhesive layer A connected to the layer D via a tie layer B, and connected to the layer E via a tie layer C, B and C being polyethylene or polypropylene modified by a cyclic anhydride of an unsaturated acid having from 4 to 8 carbon atoms, manufacture of the film by coextrusion, and Use of the film for resealable packagings.
1. A multilayer film comprising a laminatable layer D and a sealable and cleavable layer E of a thermoplastic material bonded to one another by a continuous layer A which has a thickness ranging from 7 to 50 μm and is composed of a hot-melt pressure-sensitive adhesive composition a having a melt flow index (or MFI) ranging from 0.01 to 200 g/10 minutes and comprising, on the basis of the total weight of said composition a:
from 40 to 70% by weight of a composition a1 formed of styrene block copolymers comprising at least one elastomer block, said composition a1 comprising, on the basis of its total weight:
30 to 90% by weight of at least one diblock copolymer of SI, SBI, SIB, SB, SEB, or SEP, and
10 to 70% by weight of at least one triblock copolymer of SIS, SIBS, SBS, SEBS or SEPS;
the total content of styrene units of said composition a1 varying from 10 to 40% by weight, on the basis of the total weight of a1; and
30 to 60% by weight of one or more tackifying resins a2 having a softening temperature of between 5 and 140° C.;
wherein in said multilayer film the adhesive layer A is:
connected to the layer D via a tie layer B, and
connected to the layer E via a tie layer C,
each of the two layers B and C having respectively a thickness of 1-10 μm and being respectively composed of a composition b and c comprising a polyethylene or polypropylene which are modified by a cyclic anhydride of an unsaturated acid having from 4 to 8 carbon atoms.
2. The multilayer film according to claim 1 , wherein the content of diblock copolymer in the composition a1 varies from 40 to 90%.
3. The multilayer film according to claim 1 , wherein the composition a1 comprises an SIS triblock copolymer and of an SI diblock copolymer.
4. The multilayer film according to claim 1 , wherein the tackifying resin or resins a2 have weight-average molar masses M w of between 300 and 5000 Da and are:
(i) rosins of natural or modified origin;
(ii) resins obtained by hydrogenation, polymerization or copolymerization (with an aromatic hydrocarbon) of mixtures of unsaturated aliphatic hydrocarbons having approximately 5, 9 or 10 carbon atoms resulting from petroleum fractions;
(iii) terpene resins resulting from the polymerization of terpene hydrocarbons, in the presence of Friedel-Crafts catalysts, which are optionally modified by the action of phenols;
(iv) copolymers based on natural terpenes.
5. The multilayer film according to claim 4 , wherein the tackifying resin or resins a2 are aliphatic resins belonging to the categories (ii) or (iii).
6. The multilayer film according to claim 1 , wherein the compositions b and c comprise a polyethylene or polypropylene modified by maleic anhydride.
7. The multilayer film according to claim 1 , wherein the compositions b and c are LLDPE modified by maleic anhydride.
8. The multilayer film according to claim 1 , wherein the compositions b and c are identical.
9. The multilayer film according to claim 1 , wherein the layers D and E are composed of a polyolefinic material.
10. The multilayer film according to claim 1 , wherein the thickness of the layer A varies from 8 to 25 μm.
11. The multilayer film according to claim 1 , wherein the thickness of the layer A varies from 10 to 20 μm and the thickness of the tie layers B and C is between 2 and 8 μm.
12. The multilayer film according to claim 1 , that is a film comprising five layers: the adhesive layer A, the two intermediate layers B and C and the two external layers D and E, according to the sequence D/B/A/C/E in which the “/” sign means that the faces of the layers concerned are in direct contact.
13. A process for the manufacture of a multilayer film as defined in claim 1 , comprising coextrusion of the hot-melt pressure-sensitive adhesive composition a, of the compositions b and c and of the constituent materials of the layers D and E.
14. The process for the manufacture of the multilayer film according to claim 13 , wherein the coextrusion is carried out by bubble blowing.
15. A resealable packaging comprising in said resealable packaging a multilayer film according to claim 1 .
16. The multilayer film according to claim 4 , wherein the rosin is a rosin extracted from pine gum, wood rosin extracted from tree roots and their derivatives which are hydrogenated, dehydrogenated, dimerized, polymerized or esterified by monoalcohols or polyols.
17. The multilayer film according to claim 4 , wherein the terpene resin is monoterpene.
18. The multilayer film according to claim 4 , wherein the copolymer is styrene/terpene, α-methylstyrene/terpene or vinyltoluene/terpene.
19. The multilayer film according to claim 1 , wherein layers D and E respectively independently each have a thickness of 1-150 μm.