Light-emitting element, light-emitting device, electronic device, and lighting device
A light-emitting layer, which is a stack of a first light-emitting layer and a second light-emitting layer, is provided between an anode and a cathode. The first light-emitting layer is formed on the anode side and contains a first light-emitting substance converting triplet excitation energy into light emission, a first organic compound having an electron-transport property, and a second organic compound having a hole-transport property. The second light-emitting layer contains a second light-emitting substance converting triplet excitation energy into light emission, the first organic compound, and a third organic compound having a hole-transport property. The second organic compound has a lower HOMO level than the third organic compound. The first light-emitting substance emits light with a wavelength shorter than that of light emitted from the second light-emitting substance. The first and the second organic compounds form an exciplex. The first and the third organic compounds form an exciplex.
1. A light-emitting element comprising:
a first light-emitting layer over an anode, the first light-emitting layer comprising a first light-emitting substance, a first organic compound having an electron-transport property, and a second organic compound having a hole-transport property;
a second light-emitting layer over the first light-emitting layer, the second light-emitting layer comprising a second light-emitting substance, the first organic compound, and a third organic compound having a hole-transport property; and
a cathode over the second light-emitting layer,
wherein the first organic compound and the second organic compound form a first exciplex,
wherein the first organic compound and the third organic compound form a second exciplex, and
wherein an energy of the first exciplex is transferred from both a singlet state and a triplet state to the first light-emitting substance.
2. The light-emitting element according to claim 1 , wherein a lower highest occupied molecular orbital level of the second organic compound is lower than that of the third organic compound.
3. The light-emitting element according to claim 1 , wherein the first light-emitting substance emits light with a wavelength shorter than a wavelength of light emitted from the second light-emitting substance.
4. The light-emitting element according to claim 1 , wherein the first exciplex has higher excitation energy than the second exciplex.
5. The light-emitting element according to claim 1 ,
wherein the first exciplex is formed from an anion of the first organic compound and a cation of the second organic compound, and
wherein the second exciplex is formed from an anion of the first organic compound and a cation of the third organic compound.
6. The light-emitting element according to claim 1 ,
wherein the first light-emitting substance is a phosphorescent compound or a thermally activated delayed fluorescence material, and
wherein the second light-emitting substance is a phosphorescent compound or a thermally activated delayed fluorescence material.
7. The light-emitting element according to claim 1 ,
wherein the first organic compound is a 7-electron deficient heteroaromatic compound,
wherein the second organic compound is a 7-electron rich heteroaromatic compound or an aromatic amine compound, and
wherein the third organic compound is a 7-electron rich heteroaromatic compound or an aromatic amine compound.
8. The light-emitting element according to claim 1 ,
wherein the first organic compound is 2-[3′-(dibenzothiophen-4-yl)biphenyl-3-yl]dibenzo[f,h]quinoxaline,
wherein the second organic compound is
N-(1,1′-biphenyl-4-yl)-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9,9-dimethyl-9H-fluoren-2-amine, and
wherein the third organic compound is
N,N′-bis(9,9-dimethylfluoren-2-yl)-N,N′-di(biphenyl-4-yl)-1,4-phenylenediamine.
9. A light-emitting device comprising:
a transistor over a substrate; and
the light-emitting element according to claim 1 over the transistor.
10. A light-emitting element comprising:
a first stacked layer over an anode;
a charge generation layer over the first stacked layer;
a second stacked layer over the charge generation layer, at least one of the first stacked layer and the second stacked layer comprising:
a first light-emitting layer over an anode, the first light-emitting layer comprising a first light-emitting substance, a first organic compound having an electron-transport property, and a second organic compound having a hole-transport property;
a second light-emitting layer over the first light-emitting layer, the second light-emitting layer comprising a second light-emitting substance, the first organic compound, and a third organic compound having a hole-transport property; and
a cathode over the second stacked layer,
wherein the first organic compound and the second organic compound form a first exciplex,
wherein the first organic compound and the third organic compound form a second exciplex, and
wherein an energy of the first exciplex is transferred from both a singlet state and a triplet state to the first light-emitting substance.
11. The light-emitting element according to claim 10 , wherein a lower highest occupied molecular orbital level of the second organic compound is lower than that of the third organic compound.
12. The light-emitting element according to claim 10 , wherein the first light-emitting substance emits light with a wavelength shorter than a wavelength of light emitted from the second light-emitting substance.
13. The light-emitting element according to claim 10 , wherein the first exciplex has higher excitation energy than the second exciplex.
14. The light-emitting element according to claim 10 ,
wherein the first exciplex is formed from an anion of the first organic compound and a cation of the second organic compound, and
wherein the second exciplex is formed from an anion of the first organic compound and a cation of the third organic compound.
15. The light-emitting element according to claim 10 ,
wherein the first light-emitting substance is a phosphorescent compound or a thermally activated delayed fluorescence material, and
wherein the second light-emitting substance is a phosphorescent compound or a thermally activated delayed fluorescence material.
16. The light-emitting element according to claim 10 ,
wherein the first organic compound is a π-electron deficient heteroaromatic compound,
wherein the second organic compound is a π-electron rich heteroaromatic compound or an aromatic amine compound, and
wherein the third organic compound is a n-electron rich heteroaromatic compound or an aromatic amine compound.
17. The light-emitting element according to claim 10 ,
wherein the first organic compound is 2-[3′-(dibenzothiophen-4-yl)biphenyl-3-yl]dibenzo[f,h]quinoxaline,
wherein the second organic compound is
N-(1,1′-biphenyl-4-yl)-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9,9-dimethyl-9H-fluoren-2-amine, and
wherein the third organic compound is
N,N′-bis(9,9-dimethylfluoren-2-yl)-N,N′-di(biphenyl-4-yl)-1,4-phenylenediamine.
18. A light-emitting device comprising:
a transistor over a substrate; and
the light-emitting element according to claim 10 over the transistor.