Fuel cell device and system
Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness with the length direction being the dominant direction of thermal expansion. A reaction zone having at least one active layer therein is spaced from the first end and includes first and second opposing electrodes, associated active first and second gas passages, and electrolyte. The active first gas passage includes sub-passages extending in the y direction and spaced apart in the x direction. An artery flow passage extends from the first end along the length and into the reaction zone and is fluidicly coupled to the sub-passages of the active first gas passage. The thickness of the artery flow passage is greater than the thickness of the sub-passages. In other embodiments, fuel cell devices include second sub-passages for the active second gas passage and a second artery flow passage coupled thereto, and extending from either the first end or the second end into the reaction zone. In yet other embodiments, one or both electrodes of a fuel cell device are segmented.
1. A fuel cell device comprising:
a ceramic support structure having a length in an x direction from a first end to a second end, a width in a y direction from a first side to a second side, and a thickness in a z direction from a top surface to a bottom surface, wherein the length is greater than the width or thickness whereby the x direction of the ceramic support structure is a dominant direction of thermal expansion;
a reaction zone along a first portion of the length configured to be exposed to a heat source to heat the reaction zone to an operating reaction temperature, and at least one cold zone along a second portion of the length configured to be shielded from the heat source to remain at a low temperature below the operating reaction temperature when the reaction zone is heated;
at least one active layer within the ceramic support structure along the first portion of the length and comprising an electrolyte separating a first electrode from an opposing second electrode, wherein the first electrode is thicker in the z direction than the second electrode;
a first gas passage within the ceramic support structure adjacent the first electrode along the first portion of the length, and a second gas passage within the ceramic support structure adjacent the second electrode along the first portion of the length,
wherein the at least one active layer extends to a greater width in the y direction toward both the first and second sides than the first and second gas passages.
2. The fuel cell device of claim 1 , wherein the first electrode extends to each of the first and side sides.
3. The fuel cell device of claim 1 , wherein the second electrode is a segmented electrode having an area and a thickness and that includes a plurality of electrode material segments in a spaced pattern in the area and separated by gaps extending to at least a portion of the thickness of the segmented electrode.
4. The fuel cell device of claim 3 , further comprising a current collector extending continuously over the segmented electrode.
5. The fuel cell device of claim 4 , wherein the current collector is positioned over the gaps to form voids between the electrode material segments.
6. The fuel cell device of claim 4 , wherein the current collector fills the gaps between the electrode material segments.
7. The fuel cell device of claim 4 , wherein the segmented electrode has different physical and/or material properties than the current collector.
8. The fuel cell device of claim 7 , wherein the segmented electrode has a different composition than the current collector.
9. The fuel cell device of claim 7 , wherein the current collector comprises a different metal element than the segmented electrode.
10. The fuel cell device of claim 1 , wherein the first and/or second gas passage decreases in volume and/or area from a gas input end of the reaction zone toward a gas output end of the reaction zone.
11. A fuel cell device comprising:
a ceramic support structure having a length in an x direction from a first end to a second end, a width in a y direction from a first side to a second side, and a thickness in a z direction from a top surface to a bottom surface, wherein the length is greater than the width or thickness whereby the x direction of the ceramic support structure is a dominant direction of thermal expansion;
an active zone along a first portion of the length configured to be exposed to a heat source to heat the active zone to an operating reaction temperature, and at least one non-active end region along a second portion of the length configured to be shielded from the heat source to remain at a low temperature below the operating reaction temperature when the active zone is heated;
a triple layer active cell within the ceramic support structure in the active zone along the first portion of the length and comprising an electrolyte layer separating a first electrode layer from an opposing second electrode layer, wherein the first electrode layer is thicker in the z direction than the second electrode layer;
a first gas passage within the ceramic support structure adjacent the first electrode layer along the first portion of the length, and a second gas passage within the ceramic support structure adjacent the second electrode layer along the first portion of the length,
wherein each of the electrolyte layer, the first electrode layer and the second electrode layer of the triple layer active cell extends in the active zone to a greater width in the y direction toward both the first and second sides than the first and second gas passages.
12. The fuel cell device of claim 11 , wherein the first electrode layer extends continuously to each of the first and side sides.
13. The fuel cell device of claim 12 , wherein the second electrode layer is a segmented electrode having an area and a thickness and that includes a plurality of electrode material segments in a spaced pattern in the area and separated by gaps extending to at least a portion of the thickness of the segmented electrode.
14. The fuel cell device of claim 13 , further comprising a current collector extending continuously over the segmented electrode.
15. The fuel cell device of claim 14 , wherein the current collector is positioned over the gaps to form voids between the electrode material segments.
16. The fuel cell device of claim 14 , wherein the current collector fills the gaps between the electrode material segments.
17. The fuel cell device of claim 14 , wherein the segmented electrode has different physical and/or material properties than the current collector.
18. The fuel cell device of claim 17 , wherein the segmented electrode has a different composition than the current collector.
19. The fuel cell device of claim 17 , wherein the current collector comprises a different metal element than the segmented electrode.
20. The fuel cell device of claim 11 , wherein the first and/or second gas passage decreases in volume and/or area from a gas input end of the reaction zone toward a gas output end of the reaction zone.