Intermetallic nanoparticles
A process for preparing intermetallic nanoparticles of two or more metals is provided. In particular, the process includes the steps: a) dispersing nanoparticles of a first metal in a solvent to prepare a first metal solution, b) forming a reaction mixture with the first metal solution and a reducing agent, c) heating the reaction mixture to a reaction temperature; and d) adding a second metal solution containing a salt of a second metal to the reaction mixture. During this process, intermetallic nanoparticles, which contain a compound with the first and second metals are formed. The intermetallic nanoparticles with uniform size and a narrow size distribution is also provided. An electrochemical device such as a battery with the intermetallic nanoparticles is also provided.
1. Intermetallic nanoparticles comprising:
a compound comprising Sn and Cu, and the average diameter of the intermetallic nanoparticles is from about 100 nm to about 400 nm.
2. The intermetallic nanoparticles of claim 1 , wherein the intermetallic particles have a polydispersity less than 0.5.
3. The intermetallic nanoparticles of claim 2 , wherein the intermetallic nanoparticles have a polydispersity of about 0.2.
4. The intermetallic nanoparticles of claim 2 , wherein the compound is selected from the group consisting of Cu 6 Sn 5 and Cu 3 Sn.
5. The intermetallic nanoparticles of claim 4 , wherein the nanoparticles have Cu and Sn in a single phase.
6. An electrochemical device comprising:
an anode;
a cathode comprising intermetallic nanoparticles comprising Sn and Cu, wherein the intermetallic nanoparticles a compound comprising Sn and Cu, and the average diameter of the intermetallic nanoparticles from about 300 nm to about 400 nm; and
an electrolyte.
7. The electrochemical device of claim 6 , wherein the electrochemical device is a lithium-ion battery.
8. The electrochemical device of claim 7 wherein the capacity is greater than 80 mA/g at 0.5 V during the discharge cycle.