Electrochemical cell, method of fabricating the same and method of generating current
In various embodiments, an electrochemical cell is provided. The electrochemical cell may include a first electrode including a first metal oxide layer, the first layer having a first surface. The electrochemical cell may further include a second electrode including a second metal oxide layer, the second layer having a second surface, the second layer parallel to the first layer. The electrochemical cell may also include an electrolyte in direct physical contact with the first electrode and the second electrode. The first surface may be in direct physical contact to the second surface.
1. An electrochemical cell which reversibly converts chemical potential energy from a species into electrons comprising, in combination:
a first electrode and a first current collector electrically connected to the first electrode; and
a second electrode and a second current collector electrically connected to the second electrode;
wherein the first electrode is in direct physical contact with the second electrode at an interface forming a depletion region; and
wherein at least one of the first and second electrode comprises a semiconductor formed as a first metal oxide layer, and in response to introduction of the species at the first electrode the species is oxidized at the first electrode and an oxidant is reduced at the second electrode; first
wherein the first current collector is positioned on a surface of the first electrode opposite the first surface, and the second current collector is positioned on a surface of the second electrode opposite the second surface, such that electrons are transported between the first electrode and the second electrode via the current collector, and electrons do not pass from the first electrode to the second electrode through the depletion region.
2. The electrochemical cell of claim 1 , wherein the first electrode comprises a first semiconductor formed as the first metal oxide layer, and the second electrode comprises a second semiconductor formed as a second metal oxide layer.
3. The electrochemical cell of claim 2 , wherein the first semiconductor comprises a material different from the second semiconductor.
4. The electrochemical cell of claim 1 , wherein the depletion region allows for ions to pass between the electrodes.
5. The electrochemical cell of claim 1 , further comprising a load having a first end and a second end;
wherein the first end of the load is in electrical connection with the first electrode; and
wherein the second end of the load is in electrical connection with the second electrode.
6. The electrochemical cell of claim 1 , further comprising:
a power supply having a first end and a second end;
wherein the first end of the power supply is in electrical connection with the first electrode; and
wherein the second end of the power supply is in electrical connection with the second electrode.
7. An electrochemical cell which reversibly converts chemical potential energy from an electrochemical species into electrons, made by the process comprising the steps of:
bringing a first surface of a first electrode into direct physical contact with a second surface of a second electrode; and
forming a depletion region at an interface between the first surface and the second surface once electrical equilibrium has been established, wherein ions can pass between electrodes through the depletion region, but electrons do not pass between electrodes through the depletion region.
8. The electrochemical cell of claim 7 further comprising the step of attaching a current collector to the electrodes such that in response to introduction of the electrochemical species at the first electrode current flows between the electrodes through the current collector.
9. The electrochemical cell of claim 2 , wherein the first semiconductor comprises a material which is the same as the second semiconductor.