Method for producing magnetic particles, magnetic particles, and magnetic body
This method for producing magnetic particles comprises a nitriding treatment step for applying a nitriding treatment to material particles each having a core-shell structure in which an aluminum oxide layer is formed on the surface of an iron microparticle, and nitriding the iron microparticles while maintaining the core-shell structure.
1. A magnetic particle producing method, comprising:
a nitridation treatment step of subjecting material particles each having a core-shell structure in which an aluminum oxide layer is formed on a surface of an iron fine particle to nitridation treatment to nitride iron fine particles with the core-shell structure being maintained,
wherein the method further includes, before the nitridation treatment step, an oxidation treatment step of subjecting the material particles to oxidation treatment and a reduction treatment step of subjecting the material particles having undergone the oxidation treatment to reduction treatment, and
wherein in the nitridation treatment step, the nitridation treatment is performed on the material particles having undergone the reduction treatment.
2. The magnetic particle producing method according to claim 1 , including a drying and reduction treatment step of subjecting the material particles to drying and reduction treatment before the nitridation treatment step,
wherein in the nitridation treatment step, the nitridation treatment is performed on the material particles having undergone the drying and reduction treatment.
3. The magnetic particle producing method according to claim 2 , wherein the drying and reduction treatment is performed by, as supplying hydrogen gas or hydrogen gas-containing inert gas, heating the material particles to a temperature of 200° C. to 500° C. in a hydrogen gas atmosphere or a hydrogen gas-containing inert gas atmosphere and retaining the temperature for 1 to 20 hours.
4. The magnetic particle producing method according to claim 1 , wherein the oxidation treatment is performed by heating the material particles to a temperature of 100° C. to 500° C. in air and retaining the temperature for 1 to 20 hours.
5. The magnetic particle producing method according to claim 1 , wherein the reduction treatment is performed by, as supplying mixed gas of hydrogen gas and nitrogen gas to the material particles, heating the material particles to a temperature of 200° C. to 500° C. and retaining the temperature for 1 to 20 hours.
6. The magnetic particle producing method according to claim 1 , wherein the nitridation treatment is performed by, as supplying nitrogen element-containing gas to the material particles, heating the material particles to a temperature of 140° C. to 200° C. and retaining the temperature for 3 to 50 hours.
7. The magnetic particle producing method according to claim 2 , wherein the drying and reduction treatment step comes before the nitridation treatment step, and the oxidation treatment step and the reduction treatment step come in this order after the drying and reduction treatment step.
8. The magnetic particle producing method according to claim 1 , wherein the material particles take on a spherical shape and have a particle size of less than 200 nm.
9. The magnetic particle producing method according to claim 2 , wherein the nitridation treatment is performed by, as supplying nitrogen element-containing gas to the material particles, heating the material particles to a temperature of 140° C. to 200° C. and retaining the temperature for 3 to 50 hours.
10. The magnetic particle producing method according to claim 3 , wherein the nitridation treatment is performed by, as supplying nitrogen element-containing gas to the material particles, heating the material particles to a temperature of 140° C. to 200° C. and retaining the temperature for 3 to 50 hours.