Carbon capture solvents and methods for using such solvents
A solvent for recovery of carbon dioxide from gaseous mixture, having alkanolamine, reactive amines acting as promoter or activators, glycol, and a carbonate buffer. A solvent for recovery of carbon dioxide from gaseous mixture, having alkanolamine, reactive amines acting as promoter or activators, sulfolane, and a carbonate buffer. One specific solvent contains less than about 75% by weight of water and has a single liquid phase.
1. A solvent for recovering carbon dioxide from a gaseous mixture, consisting of:
(a) 30 to 40 wt % of an alkanolamine, wherein the alkanolamine is either N-methyldiethanolamine (MDEA) or 2-amino-2-methyl-1-propanol (AMP),
(b) 10 to 18 wt % of a reactive amine, wherein reactive amine is N-aminoethylpiperazine (AEP),
(c) a carbonate buffer, and
(d) 15 to 20 wt % of a glycol,
wherein the solvent contains less than about 45% by weight of water and is in a single liquid phase.
2. The solvent as claimed in claim 1 , wherein the glycol is polyethylene glycol.
3. The solvent as claimed in claim 1 , the solvent is less than about 30% by weight of water.
4. The solvent as claimed in claim 1 , wherein the carbonate buffer is a potassium carbonate buffer.
5. The solvent as claimed in claim 1 , wherein the reactive amine is between 11% and 15 wt % of the solvent.
6. The solvent as claimed in claim 1 , wherein the carbonate buffer buffers the solution to a pH of between about 12 and 14 in the absence of CO2.
7. The solvent as claimed in claim 1 , wherein the glycol is monoethylene glycol.
8. The solvent as claimed in claim 1 , wherein the glycol is diethylene glycol (DEG).
9. A solvent for recovering carbon dioxide from a gaseous mixture, consisting of:
(a) 20 to 40 wt % of an alkanolamine,
(b) 10 to 20 wt % of a reactive amine,
(c) carbonate buffer, (d) 10 to 20 wt % of a glycol, and (e) less than 60 wt % water, wherein the solvent is in a single liquid phase, wherein the alkanolamine
is N-methyldiethanolamine (MDEA) and the reactive amine is N-aminoethylpiperazine (AEP).
10. The solvent as claimed in claim 9 , wherein the glycol is ethylene glycol.