Electroconductive nanowire network, and electroconductive substrate and transparent electrode using same, and method for manufacturing electroconductive nanowire network, electroconductive substrate, and transparent electrode
There are provided a conductive nanowire network, a conductive board and transparent electrode utilizing it, and a method for producing the same. The conductive nanowire network of the invention has essentially unbroken, continuous conductive nanowires randomly formed into a network. In the method for producing a conductive nanowire network according to the invention, nanofibers are applied in a random network-like fashion onto a substrate covered with a conductive layer, the conductive layer regions that are not covered with the nanofibers are removed, and then the nanofibers are removed. The network structure (wire diameter and network density) are also controlled to obtain a transparent electrode exhibiting both transparency and conductivity.
1. A conductive board comprising a substrate having supported thereon a conductive nanowire, the conductive nanowire comprising aluminum, the conductive nanowire comprising an essentially unbroken, continuous conductive nanowire randomly formed into a network, wherein the conductive board has a light transmittance in the visible light region of 50% or greater, and a surface electric resistivity of 500 Ω/sq or lower.
2. A conductive board according to claim 1 , wherein the substrate is transparent.
3. A conductive board according to claim 1 , wherein the substrate comprises a flexible resin.
4. A conductive board according to claim 1 , wherein the conductive board comprises a transparent electrode.
5. A conductive board according to claim 1 , wherein said conductive board is obtained by a method comprising:
a) providing a substrate covered with a conductive layer comprising aluminum,
b) depositing nanofibers having a mean diameter of no greater than 5000 nm in a random network-like fashion onto the substrate covered with the conductive layer,
c) subjecting the substrate to heat treatment so as to have the nanofibers adhere to the conductive layer,
d) removing by dissolution the regions of the conductive layer on the substrate that are not covered with the nanofibers, and
e) removing from the substrate the nanofibers by dissolution with a solvent to produce the conductive nanowire network.
6. A conductive board according to claim 5 , wherein said depositing comprises depositing the nanofibers by electrospinning.
7. A conductive board according to claim 5 , further comprising heat treating the nanofibers at a temperature above a glass transition temperature of the nanofibers.