Activated carbon for an electric double-layer capacitor electrode and manufacturing method for same
There are disclosed activated carbon for use in an electric double-layer capacitor electrode, the carbon being capable of improving rate characteristics and float characteristics of the electric double-layer capacitor electrode, and a method for manufacturing the activated carbon. The method for manufacturing the activated carbon for use in the electric double-layer capacitor electrode, comprising the steps of: grinding a carbon raw material to adjust an average particle diameter of the carbon raw material into a range of 1 μm to 15 μm; mixing the carbon raw material whose average particle diameter has been adjusted, with an alkali activator to obtain a mixture; and an activation treatment comprising heating the mixture under an atmosphere of an inert gas and then under an atmosphere of a mixed gas of the inert gas and water vapor.
1. A method for manufacturing an activated carbon for use in an electric double-layer capacitor electrode, comprising:
mixing a carbon raw material having an average particle diameter ranging from 1 μm to 15 μm with an alkali activator to obtain a mixture;
heating the mixture from room temperature to a final temperature ranging from 700° C. to 900° C. at a heating rate ranging from 5° C./min to 30° C./min; and
maintaining the mixture at the final temperature for 10 minutes to 2 hours to manufacture an activated carbon, wherein the carbon raw material is mixed with the alkali activator in a weight ratio of 1.0:1.7 to 1.0:5.0,
wherein the heating step comprises:
heating the mixture under an atmosphere of an inert gas from room temperature to a first temperature below the final temperature;
introducing water vapor under the atmosphere of the first temperature; and
heating the mixture to the final temperature under the atmosphere in which the inert gas is mixed with the water vapor,
wherein the water vapor is introduced into the atmosphere of the inert gas when a temperature of the mixture is 500° C. to 900° C., the water vapor is introduced at a ratio of 0.1 g to 1.5 g per one liter of the inert gas,
wherein the manufactured activated carbon comprises characteristics of:
a ratio α of adsorption amounts in a range of 0.10≤α≤0.22, in a nitrogen gas adsorption isotherm obtained by nitrogen gas adsorption at a liquid nitrogen temperature, the ratio α being represented by the following equation (1):
α=( Va (0.385)− Va (0.273))/( Va (0.273)− Va (0.01)) (1)
wherein Va (0.01) represents a nitrogen gas adsorption amount at a relative pressure (p/p 0 ) of 0.01, Va (0.273) represents a nitrogen gas adsorption amount at a relative pressure (p/p 0 ) of 0.273, and Va (0.385) represents a nitrogen gas adsorption amount at a relative pressure (p/p 0 ) of 0.385, wherein p represents an adsorption equilibrium pressure and p 0 represents a saturated vapor pressure;
an area β of adsorption/desorption hysteresis in a range of 1.5 cm 3 (STP)/g≤β≤5.0 cm 3 (STP)/g,
wherein STP means standard temperature and pressure, and wherein the area is obtained by a difference between the adsorption amount indicated by a nitrogen gas adsorption isotherm and a desorption amount indicated by a nitrogen gas desorption isotherm in a range of 0.273≤p/p 0 ≤0.900; and
a specific surface area by a BET method of from 1500 m 2 /g to 2300 m 2 /g.
2. The method for manufacturing the activated carbon for use in the electric double-layer capacitor electrode according to claim 1 ,
sintering the carbon raw material prior to the mixing step.