IP Library Granted Patent US 10,000,628
Granted Patent B2
US 10,000,628 · App. 14/779,691 · Granted Jun 19, 2018

Polyarylene sulfide resin composition and use of same

Inventors: Satoru Kinouchi (Chiba, JP); Naoto Okubo (Chiba, JP)
Assignee: LION IDEMITSU COMPOSITES CO., LTD.
C08K9/06G02B6/3854G02B6/3865G02B6/3885C08K7/20C08L81/04
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Quick Facts
Patent No.
US 10,000,628
App. No.
14/779,691
Granted
Jun 19, 2018
Kind
B2
Abstract

Provided is a polyarylene sulfide resin composition which is good in strength, dimensional stability, and moldability in terms of a molded body thereof and is also capable of reducing wearing of a mold or molding machine at the time of molding of a molded body. The polyarylene sulfide resin composition contains 100 parts by mass of a polyarylene sulfide resin and 150 to 400 parts by mass of a glass bead, a sodium content of the polyarylene sulfide resin being 1,200 ppm or less, and the glass bead being surface-treated with a vinylsilane or an epoxysilane and having an average particle diameter of 30 μm or less and a ratio between a cumulative 10% particle diameter and a cumulative 90% particle diameter {(cumulative 90% particle diameter)/(cumulative 10% particle diameter)} of 2.5 or more.

Claims (20)

1. A polyarylene sulfide resin composition comprising 100 parts by mass of a polyarylene sulfide resin and 150 to 400 parts by mass of borosilicate glass beads,

a sodium content of the polyarylene sulfide resin being 1,200 ppm or less, and

the borosilicate glass beads being surface-treated with a vinylsilane and having an average particle diameter of 3 to 20 μm and a ratio between a cumulative 10% particle diameter and a cumulative 90% particle diameter {(cumulative 90% particle diameter)/(cumulative 10% particle diameter)} of the range of 2.5 to 10.

2. The polyarylene sulfide resin composition according to claim 1 , wherein the polyarylene sulfide resin is a linear type polyarylene sulfide resin.

3. The polyarylene sulfide resin composition according to claim 1 , wherein the polyarylene sulfide resin composition is for optical communication components.

4. The polyarylene sulfide resin composition according to claim 1 , wherein the polyarylene sulfide resin composition is for MT ferrules.

5. A positioning tool prepared by molding the polyarylene sulfide resin composition according to claim 1 .

6. An optical communication component prepared by molding the polyarylene sulfide resin composition according to claim 1 .

7. An MT ferrule prepared by molding the polyarylene sulfide resin composition according to claim 1 .

8. The polyarylene sulfide resin composition according to claim 1 , wherein the polyarylene sulfide resin contains p-phenylene sulfide as a constituent unit, and the constituent unit of p-phenylene sulfide is 50% or more of the total of the constituent units.

9. The polyarylene sulfide resin composition according to claim 1 , wherein a compounded amount of the polyarylene sulfide resin is 20 to 40 mass % relative to the total of the resin composition.

10. The polyarylene sulfide resin composition according to claim 1 , wherein the borosilicate glass beads are surface-treated with an acrylic silane.

11. The polyarylene sulfide resin composition according to claim 1 , wherein a compounded amount of the borosilicate glass bead is 60 to 80 mass % relative to the total of the resin composition.

12. The polyarylene sulfide resin composition according to claim 1 , wherein a spiral flow length of the polyarylene sulfide resin composition is 60 to 300 mm.

13. A molded body prepared by molding the polyarylene sulfide resin composition according to claim 1 .

14. The molded body according to claim 13 , wherein the molded body has a bending strength of 90 MPa or more.

15. The molded body according to claim 13 , wherein an Izod impact strength (unnotched) of the molded body is 7.0 kJ/m 2 or more.

16. The molded body according to claim 13 , wherein a molding shrinkage rate of the molded body is 1.00 or more in the MD direction, and 1.00 or more in the TD direction, with MD/TD being 0.90 to 1.10.

17. The molded body according to claim 13 , wherein a linear expansion coefficient of the molded body is 3.00 or less in the TD direction, and 3.00 or less in the TD direction, with MD/TD being 0.90 to 1.10.

18. The molded body according to claim 13 , wherein a weight increase rate of the molded body after a pressure cooker test for 200 hours is 0.3 or less.

Assignments (2)
CHANGE OF NAME Recorded Jan 4, 2022
From: LION IDEMITSU COMPOSITES CO.,LTD.
To: IDEMITSU FINE COMPOSITES CO.,LTD.
Reel/Frame 058541/0617 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 24, 2015
From: KINOUCHI, SATORU; OKUBO, NAOTO
To: LION IDEMITSU COMPOSITES CO., LTD.
Reel/Frame 036648/0628 →
Priority Claims (1)
JP 2013-075271 · Mar 29, 2013 · national
Continuity (1)
Related Publication 20160032085A1 · Feb 4, 2016