Coating liquid for forming light emitting layer, organic electroluminescent element, method for manufacturing organic electroluminescent element, and lighting/display device
One objective of the present invention is to provide a coating liquid for forming a light emitting layer, which improves quantum efficiency. Another objective of the present invention is to provide: an organic electroluminescent element which is formed by means of this coating liquid for forming a light emitting layer; a lighting device, a display device and a white electroluminescent device, each of which is provided with this organic electroluminescent element; and a method for manufacturing an organic electroluminescent element. A coating liquid for forming a light emitting layer according to the present invention is used for the purpose of forming a light emitting layer, which is one of one or more organic layers held between a positive electrode and a negative electrode, and this coating liquid for forming a light emitting layer is characterized by containing a thermally activated delayed fluorescent compound.
1. A coating solution for forming a luminous layer included in one or more organic layers disposed between an anode and a cathode, the coating solution comprising:
a thermally-activated delayed fluorescent, compound, and
a heavy atom compound having an external heavy-atom effect to promote intersystem crossing of the thermally-activated delayed fluorescent compound from a triplet excited state to a singlet excited state to increase a fluorescent intensity,
wherein the heavy atom compound is a phosphorescent metal complex,
a lowest excited triplet energy level (T 1 (TADF)) of the thermally-activated delayed fluorescent compound and a lowest excited triplet energy level (T 1 (P)) of the phosphorescent metal complex are within ranges allowing transfer of energy electrons therebetween,
a difference in energy between a lowest excited singlet energy level (S 1 (TADF)) of the thermally-activated delayed fluorescent compound and the lowest excited triplet energy level (T 1 (P)) of the phosphorescent metal complex is within a range represented by Expression (1):
−0.2 eV≤[ S 1 (TADF)- T 1 ( P )]≤1.0 eV (1), and
a difference in energy between the lowest excited triplet energy level (T 1 (TADF)) of the thermally-activated delayed fluorescent compound and the lowest excited triplet energy level (T 1 (P)) of the phosphorescent metal complex is within a range represented by Expression (3):
−0.2 eV≤[ T 1 (TADF)− T 1 ( P )]≤0.5 eV (3)
2. The coating solution for forming the luminous layer according to claim 1 , wherein the difference in energy between the lowest excited singlet energy level (S 1 (TADF)) of the thermally-activated delayed fluorescent compound and the lowest excited triplet energy level (T 1 (P)) of the phosphorescent metal complex is within a range represented by Expression (2)
0 eV≤[ S 1 (TADF)− T 1 ( P )]≤0.2 eV (2).
3. The coating solution for forming the luminous layer according to claim 1 , wherein the difference in energy between the lowest excited triplet energy level (T 1 (TADF)) the thermally-activated delayed fluorescent compound and the lowest excited triplet energy level (T 1 (P)) of the phosphorescent metal complex is within a range represented by Expression (4):
0 eV≤[ T 1 (TADF)− T 1 ( P )]≤0.1 eV (4).
4. The coating solution for forming the luminous layer according to claim 1 , wherein the lowest excited triplet energy level (T 1 (TADF)) of the thermally-activated delayed fluorescent compound is within a range of 2.4 to 3.5 eV.
5. The coating solution for forming the luminous layer according to claim 1 , wherein the phosphorescent metal complex has a structure represented by Formula (I)
where M represents Ir, Pt, Rh, Ru, Ag, Cu p or Qs, A 1 and A 2 each represent a carbon or nitrogen atom; ring Z 1 represents a membered aromatic aromatic hydrocarbon ring group or 5- or 6-membered aromatic heterocyclic ring group containing A 1 and A 2 ; B 1 to B 5 each represent a carbon or nitrogen atom so that B 1 to B 5 form a 5-membered aromatic heterocyclic ring group, and B 1 to B 5 each optionally have a substituent; the ring Z 1 optionally has a substituent, or optionally has a condensed ring structure formed through bonding of substituents; substituents of ligands are optionally bonded to each other to bond the ligands to each other; L represents a monoanionic bidentate ligand coordinated with M; m represents an integer of 0 to 2; n represents an integer of 1 to 3; m+n is 2 or 3; when m is 2, two Ls are same or different, and when n is 2 or 3, two or three ligands each having the ring Z 1 and the aromatic heterocyclic ring group represented by B 1 to B 5 are same or different.
6. The coating solution for forming the luminous layer according to claim 1 , further comprising a host compound.
7. An organic electroluminescent element comprising a luminous layer included in one or more organic layers disposed between an anode and a cathode, wherein the luminous layer is made from the coating solution for forming the luminous layer according to claim 1 .
8. A lighting device comprising the organic electroluminescent element according to claim 7 .
9. A display device comprising the organic electroluminescent element according to claim 7 .
10. A white electroluminescent device which has a single luminous layer disposed between an anode and a cathode, the white electroluminescent device comprising:
the organic electroluminescent element according to claim 7 .
11. A method of producing an organic electroluminescent element including one or more organic layers disposed between an anode and a cathode, the method comprising:
forming a luminous layer with the coating solution for forming the luminous layer according to claim 1 , the luminous layer being one of the organic layers.