Photocurable ink composition for ink jet recording and ink jet recording method
The present invention provides a photocurable ink composition for ink jet recording with excellent curability. The photocurable ink composition for ink jet recording includes polymerizable compounds, a photopolymerization initiator, and a colorant, wherein the polymerizable compounds include a vinyl ether group-containing (meth)acrylate represented by general formula (I): CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 (I) (wherein R 1 is a hydrogen atom or a methyl group, R 2 is a divalent organic residue having 2 to 20 carbon atoms, and R 3 is a hydrogen atom or a monovalent organic residue having 1 to 11 carbon atoms) and phenoxyethyl (meth)acrylate.
1. A photocurable ink composition for ink jet recording, comprising:
polymerizable compounds;
a photopolymerization initiator comprising an acylphosphine oxide compound; and
a colorant,
wherein the polymerizable compounds include a vinyl ether group-containing (meth)acrylate represented by general formula (I):
CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 (I)
(wherein R1 is a hydrogen atom or a methyl group, R2 is a divalent organic residue having 2 to 20 carbon atoms, and R3 is a hydrogen atom or a monovalent organic residue having 1 to 11 carbon atoms) and phenoxyethyl (meth)acrylate, bifunctional (meth)acrylate and isobornyl (meth)acrylate,
wherein the content of the phenoxyethyl (meth)acrylate is 10 to 50% by mass relative to the total mass of the ink composition,
wherein the content of the vinyl ether group-containing (meth)acrylate represented by general formula (I) is 10 to 45% by mass relative to the total mass of the ink composition,
wherein the content of the bifunctional (meth)acrylate is 20% by mass or less relative to the total mass of the ink composition, and
wherein the content of the isobornyl (meth)acrylate is 10 to 50% by mass relative to the total mass of the ink composition.
2. The photocurable ink composition for ink jet recording according to claim 1 , wherein the content of the phenoxyethyl (meth)acrylate is 10 to 40% by mass relative to the total mass of the ink composition.
3. The photocurable ink composition for ink jet recording according to claim 1 , wherein the content of the acylphosphine oxide compound is 7% by mass or more relative to the total mass of the ink composition.
4. The photocurable ink composition for ink jet recording according to claim 1 , wherein the content of the acylphosphine oxide compound is 7 to 15% by mass relative to the total mass of the ink composition.
5. The photocurable ink composition for ink jet recording according to claim 1 , wherein the content of the acylphosphine oxide compound is 10 to 50% by mass relative to the total mass of the ink composition.
6. The photocurable ink composition for ink jet recording according to claim 1 , wherein the vinyl ether group-containing (meth)acrylate is 2-(vinyloxyethoxy)ethyl (meth)acrylate.
7. The photocurable ink composition for ink jet recording according to claim 1 , wherein the ink composition is cured by irradiation with ultraviolet light with an emission peak wavelength in a range of 350 to 420 nm and an irradiation energy of 300 mJ/cm2 or less.
8. An ink jet recording method comprising:
ejecting the photocurable ink composition for ink jet recording according to claim 1 onto a recording medium; and
curing the ejected photocurable ink composition for ink jet recording by ultraviolet irradiation.
9. The photocurable ink composition for ink jet recording according to claim 1 , wherein the content of the isobornyl (meth)acrylate is 10 to 36.3% by mass relative to the total mass of the ink composition.
10. The photocurable ink composition for ink jet recording according to claim 1 , wherein the polymerizable compounds include polyfunctional (meth)acrylate.
11. The photocurable ink composition for ink jet recording according to claim 10 , wherein the content of the polyfunctional (meth)acrylate is 40% by mass or less relative to the total mass of the ink composition.
12. The photocurable ink composition for ink jet recording according to claim 1 , wherein the polymerizable compounds contain 15% by mass or less of bifunctional (meth)acrylate relative to the total mass of the ink composition.
13. The photocurable ink composition for ink jet recording according to claim 1 , wherein the content of the vinyl ether group-containing (meth)acrylate represented by formula (I) is 10 to 20% by mass relative to the total mass of the ink composition.