Integrated circuits having copper bonding structures with silicon carbon nitride passivation layers thereon and methods for fabricating same
View Patent ↗Integrated circuits having copper bonding structures with silicon carbon nitride passivation layers and methods for making the same are provided. In an exemplary embodiment, an integrated circuit includes a substrate and a copper bonding structure having a contact surface. The copper bonding structure overlies the substrate. A passivation layer formed of silicon carbon nitride is disposed on the contact surface.
1. A integrated circuit comprising:
a substrate;
a copper bond pad having a contact surface, the copper bond pad overlying the substrate;
a passivation layer comprising silicon carbon nitride disposed on the contact surface; and
a conductive element bonded to the copper bond pad through the passivation layer with a weld.
2. The integrated circuit of claim 1 , wherein the passivation layer has a thickness of from about 3 to about 15 nanometers (nm).
3. The integrated circuit of claim 2 , wherein the passivation layer has a thickness of from about 5 to about 8 nm.
4. The integrated circuit of claim 1 , wherein the copper bond pad comprises pure copper, doped copper, or a copper alloy.
5. The integrated circuit of claim 4 , wherein the doped copper comprises at least 90 weight percent (wt %) copper based on a total weight of the bond pad.
6. The integrated circuit of claim 5 , wherein the doped copper comprises aluminum, manganese, gold or a combination thereof.
7. The integrated circuit of claim 4 , wherein the copper alloy comprises at least 55 wt % copper based on a total weight of the copper bond pad.
8. The integrated circuit of claim 7 , wherein the copper alloy comprises aluminum, gold, or a combination thereof.
9. The integrated circuit of claim 1 , wherein the conductive element is bonded to the copper bond pad through the passivation layer with a ball bond forming the weld.
10. The integrated circuit of claim 9 , wherein the conductive element is a wire.
11. The integrated circuit of claim 1 , wherein the passivation layer comprises stoichiometric silicon carbon nitride SiCN.
12. A method for fabricating an integrated circuit comprising the steps of:
providing a semiconductor substrate having a copper bond pad overlying a surface of the semiconductor substrate, the copper bond pad having a contact surface;
forming a passivation layer comprising silicon carbon nitride on the contact surface of the copper bond pad using a chemical vapor deposition (CVD) technique; and
bonding a conductive element to the copper bond pad through the passivation layer with a weld.
13. The method of claim 12 , wherein forming the passivation layer comprises forming the passivation layer by plasma enhanced chemical vapor deposition (PECVD).
14. The method of claim 13 , wherein the PECVD is performed at a temperature in a range of from about 250 to about 400° C.
15. The method of claim 13 , wherein the PECVD is performed using radio frequency (RF) energy in a range of from about 180 to about 500 Watts.
16. The method of claim 13 , wherein the PECVD is performed at a deposition rate of no greater than about 3 nanometers (nm) per 5 seconds (s) (0.6 nm/s).
17. The method of claim 16 , wherein the PECVD is performed at a deposition rate of no greater than about 3 nm per 8 seconds (s) (3 nm/8 s).
18. The method of claim 13 , wherein the PECVD is performed for a period of time required to form the passivation layer having a thickness from about 3 to about 15 nanometers (nm).
19. The method of claim 12 , further comprising electrically coupling the copper bond pad to the conductive element after forming the passivation layer.
20. A method for fabricating an integrated circuit, the method comprising the steps of:
providing a semiconductor substrate having a copper bond pad overlying a surface of the semiconductor substrate, the copper bond pad having a contact surface;
depositing a passivation layer comprising silicon carbon nitride on the contact surface of the copper bond pad using plasma-enhanced chemical vapor deposition; and
electrically coupling a conductive element to the copper bond pad through the passivation layer with a weld after depositing the passivation layer.