IP Library Granted Patent US 9,349,801
Granted Patent B2
US 9,349,801 · App. 14/828,718 · Granted May 24, 2016

Method and system for diamond-based oxygen sensor

Inventors: Mihai Brezeanu (Bucharest, RO); Bogdan-Catalin Serban (Bucharest, RO); Viorel Georgel Dumitru (Prahova, RO); Octavian Buiu (Bucharest, RO)
Assignee: Honeywell International Inc.
H01L29/1602G01N27/4141H01L29/45
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Quick Facts
Patent No.
US 9,349,801
App. No.
14/828,718
Granted
May 24, 2016
Kind
B2
Abstract

A diamond based oxygen sensor is able to function in harsh environment conditions. The oxygen sensor includes a gateless field effect transistor including a synthetic, quasi-intrinsic, hydrogen-passivated, monocrystalline diamond layer exhibiting a 2-dimension hole gas effect. The oxygen sensor also includes a sensing layer comprising yttrium-stabilized zirconia deposited onto a surface of the gateless field effect transistor.

Claims (34)

1. An oxygen sensor, comprising:

a gateless field effect transistor (FET) ( 100 ) including a synthetic, quasi-intrinsic, hydrogen-passivated diamond layer ( 116 ) exhibiting a 2-dimension hole gas effect; and

an oxygen-sensing layer ( 124 ) including a yttrium-stabilized zirconia (YSZ) supported by the gateless FET ( 100 ).

2. The oxygen sensor of claim 1 , the gateless FET ( 100 ) further including:

a first highly-doped p-type region ( 118 ) implanted within the monocrystalline diamond layer ( 116 );

a second highly-doped p-type region ( 120 ) implanted within the monocrystalline diamond layer ( 116 ); and

a 2-dimension hole gas conductive channel ( 128 ) within the monocrystalline diamond layer ( 116 ) between the first highly-doped p-type region ( 118 ) and the second highly-doped p-type region ( 120 ).

3. The oxygen sensor of claim 2 , the gateless FET ( 100 ) further including:

an ohmic source contact ( 122 ) electrically coupled to the first highly-doped p-type region ( 118 ); and

an ohmic drain contact ( 126 ) electrically coupled to the second highly-doped p-type region ( 120 );

wherein the oxygen-sensing layer ( 124 ) is supported by the 2-dimension hole gas conductive channel ( 128 ) and electrically coupled between the ohmic source contact ( 122 ) and the ohmic drain contact ( 126 ).

4. The oxygen sensor of claim 2 , the gateless FET ( 100 ) further including a polycrystalline diamond substrate ( 114 ), wherein the monocrystalline diamond layer ( 116 ) is grown on a first side of the polycrystalline diamond substrate ( 114 ).

5. The oxygen sensor of claim 2 , the gateless FET ( 100 ) further including an ohmic contact substrate ( 112 ) supported by a second side of the polycrystalline diamond substrate ( 114 ).

6. The oxygen sensor of claim 2 , wherein:

the first highly-doped p-type region ( 118 ) is implanted within the monocrystalline diamond layer ( 116 ) using boron implantation; and

the second highly-doped p-type region ( 120 ) is implanted within the monocrystalline diamond layer ( 116 ) using boron implantation.

7. The oxygen sensor of claim 2 , wherein:

the 2-dimension hole gas conductive channel ( 128 ) is formed within the monocrystalline diamond layer ( 116 ) by performing hydrogen passivation.

8. The oxygen sensor of claim 3 , wherein the ohmic source contact ( 122 ) and the ohmic drain contact ( 126 ) are formed using a stack of Ti/Au.

9. A method of forming a gateless FET oxygen sensor, comprising:

forming a gateless field effect transistor (FET) ( 100 ); and

forming an oxygen-sensing layer ( 124 ) including a yttrium-stabilized zirconia (YSZ) supported by the gateless FET ( 100 ).

10. The oxygen sensor of claim 9 , wherein forming the gateless FET ( 100 ) includes:

growing a synthetic, quasi-intrinsic, hydrogen-passivated diamond layer ( 116 ) on a first side of a polycrystalline diamond substrate ( 114 );

generating a first highly-doped p-type region ( 118 ) within the monocrystalline diamond layer ( 116 );

generating a second highly-doped p-type region ( 120 ) within the monocrystalline diamond layer ( 116 ); and

generating a 2-dimension hole gas conductive channel ( 128 ) within the monocrystalline diamond layer ( 116 ) between the first highly-doped p-type region ( 118 ) and the second highly-doped p-type region ( 120 ).

11. The oxygen sensor of claim 10 , wherein forming the gateless FET ( 100 ) further includes:

disposing an ohmic source contact ( 122 ) on the first highly-doped p-type region ( 118 ); and

disposing an ohmic drain contact ( 126 ) on the second highly-doped p-type region ( 120 ).

12. The oxygen sensor of claim 10 , wherein forming the gateless FET ( 100 ) further includes disposing an ohmic contact substrate ( 112 ) on a second side of the polycrystalline diamond substrate ( 114 ).

13. The oxygen sensor of claim 10 , wherein the first highly-doped p-type region ( 118 ) and the second highly-doped p-type region ( 120 ) are generated within the monocrystalline diamond layer ( 116 ) using boron implantation.

14. The oxygen sensor of claim 10 , wherein the 2-dimension hole gas conductive channel ( 128 ) is generated within the monocrystalline diamond layer ( 116 ) by performing hydrogen passivation.

15. The oxygen sensor of claim 11 , wherein the ohmic source contact ( 122 ) and the ohmic drain contact ( 126 ) are formed using a stack of Ti/Au.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 2, 2015
From: BREZEANU, MIHAI; SERBAN, BOGDAN-CATALIN; DUMITRU, VIOREL GEORGEL; BUIU, OCTAVIAN
To: HONEYWELL INTERNATIONAL INC.
Reel/Frame 036934/0990 →
Priority Claims (1)
EP 14182173 · Aug 25, 2014 · regional
Continuity (1)
Related Publication 20160056239A1 · Feb 25, 2016