IP Library Granted Patent US 10,036,096
Granted Patent B2
US 10,036,096 · App. 14/832,742 · Granted Jul 31, 2018

System and method for parallel solution extraction of one or more metal values from metal-bearing materials

Inventors: Anand Raman (Phoenix, AZ); Jason M Morgan (Morenci, AZ); Barbara J Savage (Silver City, NM); David G Meadows (Phoenix, AZ); Wayne W Hazen (Lakewood, CO)
Assignee: FREEPORT MINERALS CORPORATION
C25C1/22B01D11/0488C22B3/0005C22B3/02C22B3/44C22B11/04C22B19/00C22B23/0407C22B23/0453C22B23/0461C22B34/34C22B59/00C22B60/0221C22B60/0252C22B60/0278C22B61/00C25C1/08C25C1/10C25C7/00Y02P10/234
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Quick Facts
Patent No.
US 10,036,096
App. No.
14/832,742
Granted
Jul 31, 2018
Kind
B2
Abstract

The present disclosure relates to a process and system for recovery of one or more metal values using solution extraction techniques and to a system for metal value recovery. In an exemplary embodiment, the solution extraction system comprises a first solution extraction circuit and a second solution extraction circuit. A first metal-bearing solution is provided to the first and second circuit, and a second metal-bearing solution is provided to the first circuit. The first circuit produces a first rich electrolyte solution, which can be forwarded to primary metal value recovery, and a low-grade raffinate, which is forwarded to secondary metal value recovery. The second circuit produces a second rich electrolyte solution, which is also forwarded to primary metal value recovery. The first and second solution extraction circuits have independent organic phases and each circuit can operate independently of the other circuit.

Claims (35)

1. A process comprising:

feeding a first metal-bearing solution to a first solution extraction circuit and a second solution extraction circuit;

feeding a second metal-bearing solution to the first solution extraction circuit;

producing a low-grade raffinate from the first solution extraction circuit; and

subjecting the low-grade raffinate to a selective precipitation process to precipitate a metal ion.

2. The process of claim 1 , wherein the metal ion is uranium.

3. The process of claim 2 , wherein the low-grade raffinate comprises a secondary metal value.

4. The process of claim 3 , wherein the secondary metal value is cobalt.

5. The process of claim 2 , wherein the uranium precipitates as a solid and further comprising recycling the solid to a reactive process.

6. The process of claim 3 , wherein the subjecting the low-grade raffinate to the selective precipitation process yields an electrolyte containing a secondary metal value.

7. The process of claim 6 , further comprising forwarding the electrolyte to a secondary metal recovery process.

8. The process of claim 7 , wherein the secondary metal value comprises at least one of silver, platinum group metals, molybdenum, zinc, nickel, cobalt, uranium, rhenium, rare earth and actinide metals.

9. The process of claim 1 , wherein the first metal-bearing solution is a high-grade pregnant leach solution.

10. The process of claim 1 , wherein the second metal-bearing solution is a low-grade pregnant leach solution.

11. A process comprising:

feeding a first metal-bearing solution to a first solution extraction circuit and a second solution extraction circuit;

feeding a second metal-bearing solution to the first solution extraction circuit; producing a low-grade raffinate from the first solution extraction circuit;

subjecting the low-grade raffinate to a secondary metal value recovery process.

12. The process of claim 11 , wherein the low-grade raffinate comprises a secondary metal value comprising at least one of silver, platinum group metals, molybdenum, zinc, nickel, cobalt, uranium, rhenium, rare earth and actinide metals.

13. The process of claim 12 , wherein the secondary metal value recovery process comprises a selective precipitation process to precipitate a metal ion.

14. The process of claim 13 , wherein the metal ion comprises uranium.

15. A method for extracting metal value comprising:

performing a solution extraction process comprising feeding a first stream of a first metal-bearing solution to a first circuit of a solution extraction system,

feeding a second stream of the first metal-bearing solution to a second circuit of the solution extraction system,

feeding a second metal-bearing solution to the first circuit of the solution extraction system,

producing a first rich electrolyte solution with a stripping unit of the first circuit of the solution extraction system,

producing a second rich electrolyte solution with a stripping unit of the second circuit of the solution extraction system; and

producing a low-grade raffinate from an extractor of the first circuit of the solution extraction system;

performing a primary metal value recovery process on the first rich electrolyte solution and the second rich electrolyte solution; and

subjecting the low-grade raffinate to a selective precipitation process to precipitate a metal ion.

16. The method of claim 15 , wherein the metal ion is uranium.

17. The method of claim 16 , wherein the low-grade raffinate comprises a secondary metal value.

18. The method of claim 17 , wherein the secondary metal value comprises cobalt.

19. The method of claim 16 , wherein the uranium precipitates as a solid and further comprising recycling the solid to a reactive process.

20. The method of claim 17 , wherein the subjecting the low-grade raffinate to the selective precipitation process yields an electrolyte containing the secondary metal value.

Assignments (3)
CHANGE OF NAME Recorded Sep 21, 2015
From: FREEPORT-MCMORAN CORPORATION
To: FREEPORT MINERALS CORPORATION
Reel/Frame 036642/0025 →
MERGER Recorded Sep 18, 2015
From: FREEPORT-MCMORAN CORPORATION
To: FREEPORT-MCMORAN CORPORATION
Reel/Frame 036599/0988 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 17, 2015
From: RAMAN, ANAND; MORGAN, JASON M; SAVAGE, BARBARA J; MEADOWS, DAVID G; HAZEN, WAYNE W
To: FREEPORT-MCMORAN CORPORATION
Reel/Frame 036589/0393 →
Continuity (3)
Continuation 13837158 · Mar 15, 2013
Division 13331699 · Dec 20, 2011
Related Publication 20150361527A1 · Dec 17, 2015