Carbon material, fuel cell, and method for producing carbon material
A carbon material according to an embodiment contains: 2% by mass or more and 15% by mass or less of nitrogen and 0.3% by mass or more and 2.5% by mass or less of sulfur, and 40% by mass or more of the nitrogen is a graphitic nitrogen.
1. A method for producing a carbon material, comprising:
a salt synthesis step of synthesizing a protonic salt from sulfuric acid and a primary to tertiary amine: NR 1 R 2 R 3 wherein at least one of R 1 , R 2 and R 3 represents a hydrocarbon that may have a hetero atom with the remainder representing a hydrogen atom and wherein the primary to tertiary amine has a C/N ratio of 1 or more; and
a carbonization step of subjecting the protonic salt to a heat treatment at 600° C. or more and 1200° C. or less under an inert atmosphere.
2. The method for producing a carbon material according to claim 1 , wherein the salt is in the form of a solid.
3. The method for producing a carbon material according to claim 1 , further comprising, after the carbonization step, an alkaline solution immersion step.
4. The method for producing a carbon material according to claim 1 , wherein the amine is cyanomethylamine, allylamine, vinylimidazole or phenylenediamine.
5. The method for producing a carbon material according to claim 4 , wherein the amine is phenylenediamine, and a specific surface area of the carbon material is 500 m 2 /g or more.