Thermally and electrically conductive structure, method of applying a carbon coating to same, and method of reducing a contact resistance of same
View Patent ↗A thermally and electrically conductive structure comprises a carbon nanotube ( 110 ) having an outer surface ( 111 ) and a carbon coating ( 120 ) covering at least a portion of the outer surface of the carbon nanotube. The carbon coating may be applied to the carbon nanotube by providing a nitrile-containing polymer, coating the carbon nanotube with the nitrile-containing polymer, and pyrolyzing the nitrile-containing polymer in order to form the carbon coating on the carbon nanotube. The carbon nanotube may further be coated with a low contact resistance layer ( 130 ) exterior to the carbon coating and a metal layer ( 140 ) exterior to the low contact resistance layer.
1. A method of reducing a contact resistance of a carbon nanotube, the method comprising:
coating the carbon nanotube with the nitrile-containing polymer;
pyrolyzing the nitrile-containing polymer in order to form a carbon coating on the carbon nanotube;
forming a carbide-forming metal layer exterior to the carbon coating; and
forming a metal layer exterior to the carbide-forming metal layer.
2. The method of claim 1 , wherein pyrolyzing the nitrile-containing polymer comprises pyrolyzing the nitrile-containing polymer at a temperature greater than 500 degrees Celsius.
3. The method of claim 2 , wherein pyrolyzing the nitrile-containing polymer comprises pyrolyzing the nitrile-containing polymer in a tube furnace at approximately 700 degrees Celsius for approximately six hours in argon.
4. The method of claim 1 , wherein coating the carbon nanotube comprises dispersing the nitrile-containing polymer in a solvent such that the nitrile-containing polymer is adsorbed to the carbon nanotube.
5. The method of claim 1 , further comprising performing an acid treatment on the carbon nanotube.
6. The method of claim 1 , wherein coating the carbon nanotube comprises electrospinning the nitrile-containing polymer and the carbon nanotube in order to create a nanofiber composite.
7. The method of claim 1 , wherein coating the carbon nanotube with the nitrile-containing polymer comprises:
acidifying the carbon nanotube; and
attaching the nitrile-containing polymer, comprising a block copolymer, to the carbon nanotube using a colloidal chemistry method.
8. A method of reducing a contact resistance of a carbon nanotube, the method comprising:
coating the carbon nanotube with a nitrile-containing polymer;
pyrolyzing the nitrile-containing polymer in order to form a carbon coating on the carbon nanotube;
forming a polymer layer exterior to the carbon coating; and
forming a metal layer exterior to the polymer layer.
9. The method of claim 8 , wherein pyrolyzing the nitrile-containing polymer comprises pyrolyzing the nitrile-containing polymer at a temperature greater than 500 degrees Celsius.
10. The method of claim 9 , wherein pyrolyzing the nitrile-containing polymer comprises pyrolyzing the nitrile-containing polymer in a tube furnace at approximately 700 degrees Celsius for approximately six hours in argon.
11. The method of claim 8 , wherein coating the carbon nanotube comprises dispersing the nitrile-containing polymer in a solvent such that the nitrile-containing polymer is adsorbed to the carbon nanotube.
12. The method of claim 8 , further comprising performing an acid treatment on the carbon nanotube.
13. The method of claim 8 , wherein coating the carbon nanotube comprises electrospinning the nitrile-containing polymer and the carbon nanotube in order to create a nanofiber composite.
14. The method of claim 8 , wherein coating the carbon nanotube with the nitrile-containing polymer comprises:
acidifying the carbon nanotube; and
attaching the nitrile-containing polymer, comprising a block copolymer, to the carbon nanotube using a colloidal chemistry method.