Electrode complex, method of producing electrode complex, and lithium battery

1. An electrode complex comprising:

a comprising (i) a porous active material molded body including active material particles and noble metal particles, and (ii) a solid electrolyte layer formed on a surface of the active material molded body; and

a current collector bonded to an active material molded particle exposed on a surface of the complex,

wherein the active material particles include a lithium double oxide,

the noble metal particles include a noble metal having a melting point of 1000° C. or higher, and the solid electrolyte layer includes a solid electrolyte, and

a content of the noble metal particles in the active material molded body is in a range of 0.1% by weight to 10% by weight,

wherein the active material molded body has a porosity in a range of 10% to 50%.

2. The electrode complex according to claim 1 , wherein the active material molded body includes a communication hole, and

the solid electrolyte layer is formed even in the communication hole.

3. The electrode complex according to claim 1 , wherein the noble metal is at least one of palladium and platinum.

4. The electrode complex according to claim 1 , wherein the noble metal particles have an average particle diameter of 0.1 μm to 10 μm.

5. The electrode complex according to claim 1 , wherein the average particle diameter of the active material particles is greater than the average particle diameter of the noble metal particles.

6. The electrode complex according to claim 1 , wherein the complex includes a first portion in which the active material molded body and the solid electrolyte layer are exposed and a second portion in which the solid electrolyte layer is singly exposed, and

the current collector is bonded to the first portion.

7. The electrode complex according to claim 1 , wherein the lithium double oxide is LiCoO 2 .

8. The electrode complex according to claim 1 , wherein the solid electrolyte is Li 0.35 La 0.55 TiO 3 .

9. The electrode complex according to claim 1 , wherein the content of the noble metal particles in the active material molded body is in the range of 0.1% by weight to 10% by weight relative to a total amount of the noble metal particles and the active material particles.

10. A lithium battery comprising:

the electrode complex according to claim 6 ; and

an electrode which is bonded to the second portion.

11. An electrode complex comprising:

a porous active material molded body including active material particles and noble metal particles; and

an electrolyte layer formed on a surface of the active material molded body,

wherein the active material particles include a lithium double oxide,

the noble metal particles include a noble metal having a melting point of 1000° C. or higher, and

the electrolyte layer includes a first electrolyte that is formed on the surface of the active material molded body and a second electrolyte that is filled in a gap between the active material molded body and the first electrolyte, the second electrolyte including an amorphous electrolyte,

a content of the noble metal particles in the active material molded body is in a range of 0.1% by weight to 10% by weight,

wherein the active material molded body has a porosity in a range of 10% to 50%.

12. The electrode complex according to claim 11 , wherein the second electrolyte includes Si or B.

13. An electrode complex comprising:

a porous active material molded body including active material particles and noble metal particles;

an electrolyte layer formed on a surface of the active material molded body; and

an electrolytic solution impregnation layer formed on a surface of the electrolyte layer,

wherein the active material particles include a lithium double oxide,

the noble metal particles include a noble metal having a melting point of 1000° C. or higher, and

the electrolyte layer includes a solid electrolyte that is formed on the surface of the active material molded body and an electrolytic solution that is filled in a gap between the active material molded body and the solid electrolyte,

a content of the noble metal particles in the active material molded body is in a range of 0.1% by weight to 10% by weight,

wherein the active material molded body has a porosity in a range of 10% to 50%.

14. A method of producing an electrode complex, comprising:

heating active material particles which contain a lithium double oxide and noble metal particles which contain a noble metal having a melting point of 1000° C. or higher to obtain a porous active material molded body to which a plurality of the active material particles and a plurality of the noble metal particles are connected;

applying and then heating a liquid material which contains a forming material of an inorganic solid electrolyte to obtain a complex in which a solid electrolyte layer is formed on the surface of the active material molded body; and

bonding a current collector to the active material molded body exposed to the surface of the complex,

wherein a content of the noble metal particles in the active material molded body is in a range of 0.1% by weight to 10% by weight,

wherein the active material molded body has a porosity in a range of 10% to 50%.

15. The method of producing an electrode complex according to claim 14 , wherein the active material molded body includes a communication hole.

16. The method of producing an electrode complex according to claim 14 , wherein the heating of the active material particles includes molding a mixture of the plurality of active material particles and the plurality of noble metal particles through compression and then heating the mixture.

17. The method of producing an electrode complex according to claim 14 , wherein the heating of the active material particles includes heating a slurry formed by dispersing a mixture of the plurality of active material particles and the plurality of noble metal particles in a solvent.

18. The method of producing an electrode complex according to claim 14 , wherein the heating of the active material particles is performed in a temperature range of 850° C. to lower than 1000° C.