Electrochemical reduction device and method for manufacturing hydride of aromatic compound
An electrochemical reduction device includes an electrode unit, a power control unit, an organic material storage tank, a concentration measurement unit, a water storage tank, a gas-water separation unit, and a control unit. The electrode unit includes an electrolyte membrane, a reduction electrode, and an oxygen evolving electrode. The control unit controls the power control unit so as to satisfy a relation of V HER −V allow ≤V CA ≤V TRR when the potential at a reversible hydrogen electrode, the standard redox potential of the aromatic compound, and the potential of the reduction electrode are expressed as V HER , V TRR , and V CA , respectively. V allow is adjusted according to the concentration of the aromatic compound measured by the concentration measurement unit.
1. An electrochemical reduction device comprising:
an electrode unit configured to include an electrolyte membrane having ionic conductivity, a reduction electrode that is provided on one side of the electrolyte membrane and that contains a reduction catalyst for hydrogenating at least one benzene ring of an aromatic compound, and an oxygen evolving electrode that is provided on the other side of the electrolyte membrane;
a power control device configured to apply a voltage Va between the reduction electrode and the oxygen evolving electrode;
an organic material storage tank configured to store an organic liquid including the aromatic compound;
a first pathway configured to supply the organic liquid stored in the organic material storage tank and including the aromatic compound to the reduction electrode and a second pathway configured to supply the organic liquid including the aromatic compound that is nucleus-hydrogenated by the reduction electrode and an unreacted aromatic compound to the organic material storage tank;
a concentration measurement device configured to measure a concentration of the aromatic compound to be supplied to the reduction electrode, the concentration measurement device being provided in the first pathway;
a control device configured to control the power control device so as to satisfy a relation of V HER −V allow ≤V CA ≤V TRR when a potential at a reversible hydrogen electrode, a standard redox potential of the aromatic compound, a potential of the reduction electrode, and a potential difference for setting a lower limit potential used for determining a lower limit acceptable potential of the potential V CA are expressed as V HER , V TRR , V CA , and V allow , respectively; and
a lower limit potential setting device configured to determine a lower limit of the potential V CA by adjusting the potential difference V allow for setting the lower limit potential according to the concentration of the aromatic compound measured by the concentration measurement device,
wherein the oxygen evolving electrode includes a substrate composed of a first metal material and a catalyst coating the substrate and composed of a second metal material.
2. The electrochemical reduction device according to claim 1 , wherein the lower limit potential setting device increases an absolute value of the potential difference V allow for setting the lower limit potential when the concentration of the aromatic compound is decreased.
3. The electrochemical reduction device according to claim 1 , the electrochemical reduction device further comprising:
a reference electrode that is arranged to be in contact with the electrolyte membrane and to be electrically isolated from the reduction electrode and the oxygen evolving electrode and that is held at a reference electrode potential V Ref ; and
a voltage detector that detects a potential difference ΔV CA between the reference electrode and the reduction electrode, wherein
the control device acquires the potential V CA of the reduction electrode based on the potential difference ΔV CA and the reference electrode potential V Ref .
4. The electrochemical reduction device according to claim 3 , wherein the control device changes the voltage Va, and controls the potential V CA of the reduction electrode to be the potential in a predetermined range.
5. The electrochemical reduction device according to claim 4 , wherein the control device controls the power control unit so as to satisfy Va≥(V OER −V CA ) when an oxygen evolving equilibrium potential in an electrolysis of water is expressed as V OER .
6. The electrochemical reduction device according to claim 3 , wherein the reference electrode is arranged on a side that is provided with the reduction electrode on the electrolyte membrane.
7. The electrochemical reduction device according to claim 1 , wherein the reduction catalyst comprises a catalyst metal containing at least one of Pt and Pd.
8. The electrochemical reduction device according to claim 1 , wherein
the reduction electrode is composed of a metal composition which contains a first catalyst metal containing at least one of Pt and Pd, and at least one second catalyst metal selected from the group consisting of Cr, Mn, Fe, Co, Ni, Cu, Zn, Mo, Ru, Sn, W, Re, Pb, and Bi.
9. The electrochemical reduction device according to claim 8 , wherein
a form of the metal composition is an alloy of the first catalyst metal and the second catalyst metal, or an intermetallic compound composed of the first catalyst metal and the second catalyst metal.
10. The electrochemical reduction device according to claim 8 , wherein
a ratio of the first catalyst metal to a total mass of the first catalyst metal and the second catalyst metal is 10 to 95 wt %.
11. The electrochemical reduction device according to claim 8 , wherein
a ratio of the first catalyst metal to a total mass of the first catalyst metal and the second catalyst metal is 20 to 90 wt %.
12. The electrochemical reduction device according to claim 8 , wherein
a ratio of the first catalyst metal to a total mass of the first catalyst metal and the second catalyst metal is 25 to 80 wt %.