IP Library › Granted Patent US 9,701,852
Granted Patent B2
US 9,701,852 · App. 14/867,717 · Granted Jul 11, 2017

Active energy ray curable composition, ink, composition stored container, and two-dimensional or three-dimensional image forming apparatus

Inventors: Tomohiro Hirade (Kanagawa, JP); Tomohiro Inoue (Kanagawa, JP)
Assignee: Ricoh Company, Ltd.
C09D11/101C09D11/322C09D11/326
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Quick Facts
Patent No.
US 9,701,852
App. No.
14/867,717
Granted
Jul 11, 2017
Kind
B2
Abstract

An active energy ray curable composition includes an inorganic pigment and a polymerizable monomer, wherein the inorganic pigment is carbon black having a ratio of the amount of hydrophilic functional group to the specific surface area in a range of from 7 μmol/m 2 to 42μmol/m 2 or a metal oxide having a ratio of the amount of sulfonic acid group to the specific surface area in a range of from 7 μmol/m 2 to 85 μmol/m 2 , wherein the active energy ray curable composition has a viscosity change rate (ΔV) represented by the following relation 1 from −10 percent by mass to +10 percent by mass: Δ V (%)=| V−V 0 |/V 0 ×100  relation 1, where V 0 represents an initial viscosity at 25 degrees C. and V represents a storage viscosity after the active energy ray curable composition is stored still at 70 degrees C. for 14 days.

Claims (22)

1. An active energy ray curable composition comprising:

an inorganic pigment; and

a polymerizable monomer,

wherein the inorganic pigment is carbon black having a ratio of an amount of hydrophilic functional group to a specific surface area in a range of from 8.2 μmol/m 2 to 42 μmol/m 2 or a metal oxide having a ratio of an amount of sulfonic acid group to a specific surface area in a range of from 7 μmol/m 2 to 85 μmol/m 2 ,

wherein the active energy ray curable composition has a viscosity change rate (ΔV) represented by the following relation 1 from −10 percent by mass to +10 percent by mass:

Δ V (%)=| V−V 0 |/V 0 ×100  relation 1,

where V 0 represents an initial viscosity at 25 degrees C. and V represents a storage viscosity after the active energy ray curable composition is stored still at 70 degrees C. for 14 days.

2. The active energy ray curable composition according to claim 1 , wherein the viscosity change rate (ΔV) is from −5% by mass to +5% by mass.

3. The active energy ray curing type composition according to claim 1 , wherein the carbon black is surface-treated with a sulfonating agent.

4. The active energy ray curing type composition according to claim 3 , further comprising a polymeric dispersant wherein a dispersant adsorption amount to the carbon black is at least 1.0 mg/m 2 .

5. The active energy ray curable composition according to claim 1 , wherein the metal oxide is titanium oxide.

6. The active energy ray curable composition according to claim 5 , wherein the titanium oxide is surface-treated with an alkylhalogen compound having a sulfonic acid group.

7. The active energy ray curable composition according to claim 1 , further comprising a polymeric dispersant.

8. The active energy ray curable composition according to claim 7 , wherein the polymeric dispersant is a polymer having a basic polar functional group.

9. The active energy ray curable composition according to claim 1 , wherein the polymerizable monomer has a solubility parameter (SP) value of 9.5 or higher.

10. An ink comprising:

the active energy ray curable composition of claim 1 .

11. The ink according to claim 10 , wherein the ink is used for inkjet printing.

12. A composition-stored container comprising:

the active energy ray curable composition of claim 1 .

13. A two-dimensional or three-dimensional image forming apparatus comprising:

the composition-stored container of claim 12 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 28, 2015
From: HIRADE, TOMOHIRO; INOUE, TOMOHIRO
To: RICOH COMPANY, LTD.
Reel/Frame 036702/0071 →
Priority Claims (2)
JP 2014-208563 · Oct 10, 2014 · national
JP 2015-127794 · Jun 25, 2015 · national
Continuity (1)
Related Publication 20160102216A1 · Apr 14, 2016