Method of manufacturing electrode catalyst layer for fuel cell, and electrode catalyst layer for fuel cell
There is provided a method of manufacturing an electrode catalyst layer for fuel cell. This manufacturing method comprises: (a) separating an ionomer solution by centrifugation into a supernatant that includes only an ionomer as a low molecular-weight component in the ionomer solution and a sediment including an ionomer as a high molecular-weight component having a higher molecular weight than that of the low molecular-weight component included in the supernatant; (b) using the ionomer included in the sediment as an ionomer for electrode catalyst layer and producing a catalyst ink that includes catalyst-supported particles with a catalyst metal supported thereon, a solvent and the ionomer for electrode catalyst layer; and (c) using the catalyst ink to form an electrode catalyst layer.
1. A method of manufacturing an electrode catalyst layer for fuel cell, comprising:
separating a sample of an ionomer solution comprising an ionomer that is a proton-conductive electrolyte material having a sulfonic acid group, by centrifugation into a supernatant and a sediment;
determining whether or not a solid content ratio of the supernatant is equal to or lower than a predetermined value;
wherein the solid content ratio is a value obtained by dividing a weight of the solid content in the supernatant by a total weight of the supernatant;
when the solid content ratio of the supernatant is equal to or lower than the predetermined value, using the ionomer included in the ionomer solution prior to performing the centrifugation as an ionomer for the electrode catalyst layer, and
when the solid content ratio of the supernatant is higher than the predetermined value, using a component of the ionomer included in the sediment obtained by the centrifugation as the ionomer for the electrode catalyst layer;
producing a catalyst ink that includes catalyst-supported particles with a catalyst metal supported thereon, a solvent, and the ionomer for the electrode catalyst layer; and
using the catalyst ink to manufacture an electrode catalyst layer,
wherein the predetermined value is a value which, in a relation between the solid content ratio of the supernatant after centrifugation and an amount of sulfate ion included in the electrode catalyst layer formed by using the ionomer included in the ionomer solution prior to centrifugation, an increase in the amount of the sulfate ion included in the electrode catalyst layer becomes larger with respect to an increase in the solid content ratio of the supernatant after centrifugation when the solid content ratio of the supernatant is greater than the predetermined value as compared to when the solid content ratio of the supernatant is equal to or lower than the predetermined value.
2. The method of manufacturing the electrode catalyst layer for fuel cell according to claim 1 ,
wherein a centrifugal force is set in a range of 600,000 to 750,000 G, a centrifugation time is set in a range of 50 to 100 minutes, and an environment temperature is set in a range of 15 to 35° C., as conditions of the centrifugation.
3. The method of manufacturing the electrode catalyst layer for fuel cell according to claim 1 , wherein
the predetermined value is 5 wt %.