Polyglycerol dye whitening agents for cellulosic substrates
The present application relates to novel whitening agents for cellulosic substrates. The whitening agents are comprised of at least two constituents: at least one chromophore constituent and at least one polymeric constituent. Suitable chromophore components generally fluoresce blue, red, violet, or purple color when exposed to light, or they may absorb light to reflect these same shades. The whitening agents are further characterized by the polymeric component comprising at least two repeating glycerol units. This disclosure also relates to laundry care compositions including but not limited to liquid and/or powder laundry detergent formulations and rinse added fabric softening (RAFS) compositions that comprise such whitening agents.
1. A laundry care composition comprising a laundry care ingredient and a whitening agent, wherein the whitening agent is a nonionic amphiphilic nitrogen-linked polyglycerol dye having the structure of Formula I:
wherein each R 5 is independently selected from the group consisting of alkyl, oxyalkyl, oxyaryl, sulfonamidoalkyl, sulfonamidoaryl, amidoalkyl, amidodialkyl, amidoaryl, amidodiaryl, halogen, thioalkyl and thioaryl;
wherein the index a is an integer from about 0 to about 4;
wherein D is an aromatic or heteroaromatic group;
wherein R 1 is selected from the group consisting of H, alkyl, aryl, aryl alkyl and [(CH 2 CH 2 O) x (CH 2 C(OR)HCH 2 O) y (CH 2 CH 2 O) z H], wherein R 2 is [(CH 2 CH 2 O) x (CH 2 C(OR)HCH 2 O) y (CH 2 CH 2 O) z H], wherein each R is independently selected from the group consisting of H, (CH 2 CH 2 O) z′ H, and mixtures thereof; wherein groups indicated by indices x, y and z may be arranged in any order; wherein x=0 to 10, wherein 1≦y≦5 and at least one y≧2; and
wherein independently each z=0 to 5 and each z′=0 to 5.
2. A laundry care composition according to claim 1 , said nonionic amphiphilic nitrogen-linked polyglycerol dye being an azo dye having the structure of Formula II:
wherein the index a is from 0 to 2; wherein each R is independently selected from the group consisting of H, (CH 2 CH 2 O) z′ H, and mixtures thereof; wherein groups indicated by indices x, y and z may be arranged in any order; wherein x=0 to 10, wherein 1≦y≦5 and at least one y≧2; and wherein independently each z=0 to 5 and each z′=0 to 5.
3. A laundry care composition according to claim 1 , wherein each R is independently selected from the group consisting of H, (CH 2 CH 2 O) z′ H, and mixtures thereof; wherein groups indicated by indices x, y and z may be arranged in any order; wherein x=0 to 10, wherein 1≦y≦5 and at least one y≦2; and wherein independently each z=0 and each z′=0.
4. A laundry care composition according to claim 3 , wherein independently each x=0.
5. A laundry care composition according to claim 1 , wherein the composition further comprises a first wash lipase.
6. A laundry care composition according to claim 1 , wherein the composition comprises a fluorescent agent selected from the group consisting of sodium 2 (4-styryl-3-sulfophenyl)-2H-napthol[1,2-ditriazole, disodium 4,4′-bis{[(4-anilino-6-{N methyl-N-2 hydroxyethyl)amino 1,3,5-triazin-2-yl)]amino}stilbeno-2-2′disulfonate, disodium 4,4′-bis[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)amino]stilbene-2-2 ′disulfonate, disodium 4,4′-bis (2-sulfostyryl)biphenyl, and 7-(diethylamino)-4-methyl-2H-1-Benzopyran-2-one and mixtures thereof.
7. A laundry care composition according to claim 1 , wherein the composition further comprises a dye transfer inhibitor selected from the group consisting of:
(a) polyvinylpyrrolidone polymers;
(b) polyamine N-oxide polymers;
(c) copolymers of N-vinylpyrrolidone and N-vinylimidazole;
(d) polyvinyloxazolidones;
(e) polyvinylimidazoles; and
(f) mixtures thereof.
8. A laundry care composition according to claim 1 , wherein the laundry care composition is packaged in a unit dose pouch.
9. A laundry care composition according to claim 1 , wherein the composition comprises a total of no more than about 20 wt % water.
10. A laundry care composition according to claim 1 , wherein the composition further comprises a perfume microcapsule having a D[4,3] average particle of from about 0.01 microns to about 200 micrometers.
11. A method of treating a cellulosic and/or polyester and/or nylon-comprising textile, the method comprising the steps of:
(i) treating the textile with an aqueous solution comprising a laundry care composition according to claim 1 , wherein the concentration of nonionic amphiphilic nitrogen-linked polyglycerol dye is from about 1 ppb to about 500 ppm;
(ii) optionally rinsing, and
(iii) drying the textile.