Rotary tubular furnace, method of producing negative electrode active material for non-aqueous electrolyte secondary battery, negative electrode active material for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery
The invention provides a rotary tubular furnace including a rotatable furnace tube having an inlet end through which silicon compound particles (SiO x where 0.5≤x<1.6) are put therein and an outlet end through which the particles coated with carbon are taken out therefrom; and a heating chamber having a heater to heat the furnace tube, wherein the furnace tube is composed of a heat portion inside the heating chamber and a non-heat portion outside the heating chamber, a length B of the heat portion and an overall length A of the furnace tube satisfy 0.4≤B/A<1, and a distance C between the heat portion and the outlet end and the overall length A satisfy 0.04≤C/A≤0.35. This furnace can inhibit clogging of the furnace tube and mass-produce a negative electrode active material for a non-aqueous electrolyte secondary battery having a high capacity with inhibited variations in the amount of carbon coating and crystallinity.
1. A rotary tubular furnace for producing a negative electrode active material for a non-aqueous electrolyte secondary battery by pyrolyzing an organic gas to coat each of silicon compound particles of SiO x with carbon where 0.5≤x<1.6, comprising:
a rotatable furnace tube having an inlet end through which the particles are put therein and an outlet end through which the particles coated with the carbon are taken out therefrom; and
a heating chamber having a heater configured to heat the furnace tube,
the tubular furnace being configured to agitate the particles put in an interior of the furnace tube by rotating the furnace tube while the furnace tube is heated by the heater, whereby each of the particles is coated with the carbon, and to take out the particles coated with the carbon through the outlet end, wherein
the furnace tube is composed of a heat portion located inside the heating chamber having the heater and a non-heat portion located outside the heating chamber,
a length B of the heat portion and an overall length A of the furnace tube satisfy 0.4≤B/A<1, and
a distance C between the heat portion and the outlet end of the furnace tube and the overall length A satisfy 0.04≤C/A≤0.35.
2. The rotary tubular furnace according to claim 1 , wherein a diameter D of the furnace tube and the length B of the heat portion satisfy 0.08≤D/B≤0.3.
3. The rotary tubular furnace according to claim 1 , wherein the furnace tube is made of any one of heat resist cast steel, nickel-based superalloy, nickel-molybdenum-chrome alloy, carbon material, alumina, SiC, magnesia-carbon material, alumina-magnesia-carbon material, and magnesia-chrome material.
4. The rotary tubular furnace according to claim 2 , wherein the furnace tube is made of any one of heat resist cast steel, nickel-based superalloy, nickel-molybdenum-chrome alloy, carbon material, alumina, SiC, magnesia-carbon material, alumina-magnesia-carbon material, and magnesia-chrome material.
5. The rotary tubular furnace according to claim 3 , wherein the carbon material is any one of cold isostatic pressed graphite, extruded graphite, molded graphite, composite material of carbon fiber and resin, and composite material of carbon fiber and a carbon-based matrix.
6. The rotary tubular furnace according to claim 4 , wherein the carbon material is any one of cold isostatic pressed graphite, extruded graphite, molded graphite, composite material of carbon fiber and resin, and composite material of carbon fiber and a carbon-based matrix.
7. The rotary tubular furnace according to claim 1 , further comprising a mechanism for vibrating the furnace tube.
8. The rotary tubular furnace according to claim 6 , further comprising a mechanism for vibrating the furnace tube.
9. The rotary tubular furnace according to claim 7 , wherein the mechanism for vibrating the furnace tube is any one of a knocker, a mechanism using a falling object to impact, an ultrasonic generator, and a vibrator.
10. The rotary tubular furnace according to claim 8 , wherein the mechanism for vibrating the furnace tube is any one of a knocker, a mechanism using a falling object to impact, an ultrasonic generator, and a vibrator.
11. The rotary tubular furnace according to claim 9 , wherein the knocker is air-driven or electromagnetically driven.
12. The rotary tubular furnace according to claim 10 , wherein the knocker is air-driven or electromagnetically driven.
13. The rotary tubular furnace according to claim 1 , wherein the heating chamber is capable of adjusting a temperature of an interior of the heat portion of the furnace tube to a temperature ranging from 800° C. to 1,200° C. when each of the particles is coated with the carbon.
14. The rotary tubular furnace according to claim 11 , wherein the heating chamber is capable of adjusting a temperature of an interior of the heat portion of the furnace tube to a temperature ranging from 800° C. to 1,200° C. when each of the particles is coated with the carbon.
15. The rotary tubular furnace according to claim 12 , wherein the heating chamber is capable of adjusting a temperature of an interior of the heat portion of the furnace tube to a temperature ranging from 800° C. to 1,200° C. when each of the particles is coated with the carbon.
16. A method of producing a negative electrode active material for a non-aqueous electrolyte secondary battery, comprising using a rotary tubular furnace according to claim 1 to coat each of silicon compound particles of SiO x with carbon where 0.5≤x<1.6.
17. A negative electrode active material for a non-aqueous electrolyte secondary battery, produced by the method according to claim 16 .
18. A non-aqueous electrolyte secondary battery comprising a negative electrode containing the negative electrode active material according to claim 17 .