POLYAMIDE RESIN COMPOSITION AND MOLDED ARTICLE
A polyamide resin composition including a polyamide resin (A), a copper compound (B), a bromide of an alkali metal and/or a bromide of an alkaline earth metal (C), and an amphoteric compound and/or a basic compound (D).
1 . A polyamide resin composition comprising:
a polyamide resin (A),
a copper compound (B),
a bromide of an alkali metal and/or a bromide of an alkaline earth metal (C), and
an amphoteric compound and/or a basic compound (D).
2 . The polyamide resin composition according to claim 1 ,
wherein the amphoteric compound and/or basic compound (D) is one or more selected from the group consisting of
metal carbonate salts, metal bicarbonate salts, metal hydroxides, metal oxides, and solid solutions thereof.
3 . The polyamide resin composition according to claim 1 ,
wherein the amphoteric compound and/or basic compound (D) is one or more selected from the group consisting of hydroxides of alkali metals and/or alkaline earth metals, oxides of alkali metals and/or alkaline earth metals, and solid solutions of hydroxides containing alkali metals and/or alkaline earth metals and carbonates.
4 . The polyamide resin composition according to claim 1 ,
wherein the copper compound (B) is a copper halide compound.
5 . The polyamide resin composition according to claim 1 ,
wherein a molar ratio of a halogen element to a copper element in the polyamide resin composition is 2/1 to 50/1.
6 . The polyamide resin composition according to claim 1 , further comprising one or more fatty acid compound (E) selected from the group consisting of fatty acid esters, fatty acid amides, and fatty acid metal salts.
7 . The polyamide resin composition according to claim 6 ,
wherein the fatty acid compound (E) has an acid value of 10 mg/g or less.
8 . The polyamide resin composition according to claim 6 ,
wherein the fatty acid compound (E) is a higher fatty acid metal salt with a metal content of 3.5 to 11.5% by mass.
9 . The polyamide resin composition according to claim 1 ,
wherein the polyamide resin composition contains 0.005% by mass or more of a copper element based on 100% by mass of the polyamide resin composition.
10 . The polyamide resin composition according to claim 1 ,
wherein a mass ratio of the bromide of an alkali metal and/or bromide of an alkaline earth metal (C) to the amphoteric compound and/or basic compound (D) in the polyamide resin composition is 100/1 to 1/100.
11 . The polyamide resin composition according to claim 1 , further comprising an inorganic filler (F).
12 . The polyamide resin composition according to claim 1 ,
wherein a copper element is not deposited on a surface of rolled steel (SS400) after the polyamide resin composition is in contact with the rolled steel at a temperature 30° C. higher than the melting point of the polyamide resin (A) for 12 hours.
13 . A molded article comprising the polyamide resin composition according to claim 1 .
14 . The molded article according to claim 13 ,
wherein the molded article is a vehicle part.
15 . The polyamide resin composition according to claim 2 , further comprising one or more fatty acid compound (E) selected from the group consisting of fatty acid esters, fatty acid amides, and fatty acid metal salts.
16 . The polyamide resin composition according to claim 3 , further comprising at least one fatty acid compound (E) selected from the group consisting of fatty acid esters, fatty acid amides, and fatty acid metal salts.
17 . The polyamide resin composition according to claim 16 ,
wherein the fatty acid compound (E) has an acid value of 10 mg/g or less.
18 . The polyamide resin composition according to claim 3 , further comprising an inorganic filler (F).
19 . The polyamide resin composition according to claim 6 , further comprising an inorganic filler (F).
20 . The polyamide resin composition according to claim 16 , further comprising an inorganic filler (F).