Plasma etching method and plasma etching apparatus
A plasma etching method for plasma-etching an object including an etching target film and a patterned mask. The plasma etching method includes a first step of plasma-etching the etching target film using the mask, and a second step of depositing a silicon-containing film using plasma of a silicon-containing gas on at least a part of a side wall of the etching target film etched by the first step.
1. A plasma etching method for plasma-etching an object including an oxide film, an amorphous carbon layer film formed on the oxide film, an inorganic film formed on the amorphous carbon layer film, and a patterned first mask, the method comprising:
a first step of plasma-etching the inorganic film using the first mask;
a second step of etching the amorphous carbon layer film using the etched inorganic film as a second mask and thereby exposing the oxide film; and
a third step of, after exposing the oxide film by the second step, depositing a silicon-containing film using plasma of a silicon-containing gas on an upper surface of the second mask and at least a part of a side wall of the etched amorphous carbon layer film, wherein
as a result of the second step, a thickness of a top part of the side wall of the etched amorphous carbon layer film that is closer to the second mask becomes less than a thickness of a bottom part of the side wall of the etched amorphous carbon layer film that is closer to the oxide film; and
the third step is performed such that a thickness of the silicon-containing film deposited on the top part of the side wall of the etched amorphous carbon layer film becomes greater than a thickness of the silicon-containing film deposited on the bottom part of the side wall of the etched amorphous carbon layer film.
2. The plasma etching method as claimed in claim 1 , wherein the silicon-containing gas includes one of silicon tetrachloride and silicon tetrafluoride, and a reducing gas.
3. The plasma etching method as claimed in claim 1 , wherein
in the second step, the amorphous carbon layer film is etched with plasma of a process gas including an oxygen gas and a carbonyl sulfide gas by using the etched inorganic film as the second mask.
4. The plasma etching method as claimed in claim 1 , further comprising:
a fourth step of plasma-etching the oxide film using a third mask including the amorphous carbon layer film; and
a fifth step of depositing a silicon-containing film using plasma of a silicon-containing gas on at least a part of a side wall of the oxide film etched by the fourth step.
5. The plasma etching method as claimed in claim 4 , wherein in the fourth step, the oxide film is plasma-etched using plasma of a process gas including a fluorocarbon gas.
6. The plasma etching method as claimed in claim 4 , wherein the fourth step and the fifth step are repeated.
7. The plasma etching method as claimed in claim 1 ,
wherein the object further includes an antireflection film formed on an upper side of the inorganic film, and the first mask is a patterned resist film formed on the antireflection film; and
wherein in the first step, the antireflection film and the inorganic film are etched with plasma of a process gas including a fluorocarbon gas by using the resist film as the first mask.
8. The plasma etching method as claimed in claim 1 , wherein in the third step, a process gas including the silicon-containing gas is converted by high-frequency power into the plasma including ions and radicals so that, due to ion scattering caused by collision with molecules in the plasma, the ions and the radicals are incident on the side wall of the etched amorphous carbon layer film at an incident angle with respect to a vertically-downward direction and a larger amount of the silicon-containing film is deposited on the top part of the side wall than on the bottom part of the side wall.