Method for obtaining an iron-comprising solution of high concentration
The current invention concerns a method for increasing an iron content of a solution by converting low iron containing solutions into highly concentrated ferric chloride solutions by adding iron containing substances. The invention concerns also methods for transporting and storage of said highly concentrated ferric chloride solutions.
1. A method for obtaining a solution comprising an increased ferric chloride concentration of between about 67 wt. % and about 75 wt. %, comprising the steps of:
(a) providing a solution comprising ferric chloride and/or ferrous chloride, and having an initial ferric chloride concentration;
(b) increasing an iron content of said solution from the iron content of less than about 10 wt. % to the iron content of more than about 23 wt. % by adding a substance comprising iron, ferric iron and/or ferrous iron,
wherein the step after adding a substance comprising iron, ferric iron and/or ferrous ion further comprises at least one of the following steps:
(1) adding hydrochloric acid to the solution, and/or
(2) oxidizing ferrous ion in the solution; and
(c) obtaining the solution comprising an increased ferric chloride concentration of between about 67 wt. % and about 75 wt. %.
2. The method according to claim 1 , wherein the method is carried out without an evaporation step.
3. The method according to claim 1 , further comprising the step of maintaining a temperature of about 8° C. or higher of the solution comprising an increased ferric chloride concentration of between about 67 wt. % and about 75 wt. %.
4. The method according to claim 1 , wherein said solution obtained in step (b) comprises ferrous ion and said ferrous ion in said solution is oxidized in step (b)(2).
5. The method according to claim 1 , wherein said increased ferric chloride concentration is higher than said initial ferric chloride concentration by at least about 1 wt. %.
6. The method according to claim 1 , wherein the provided solution in step (a) comprises a ferric chloride concentration of at least about 12 wt. %.
7. The method according to claim 1 , wherein said iron-comprising substance comprises iron, hematite, magnetite, iron oxide, ferrite, or any combination thereof.
8. The method according to claim 1 , wherein step (b) comprises oxidation using ozone, oxygen gas, chlorine dioxide, sodium hypochlorite, peroxide, hydrogen peroxide, perchlorate, or sodium perchlorate, chlorination and/or oxychlorination.
9. The method according to claim 1 , wherein the steps of adding the substance comprising iron, ferric iron and/or ferrous iron, increasing the iron content of said solution, adding hydrochloric acid to the solution, and oxidizing the ferrous ion in the solution are performed multiple times subsequently or simultaneously.
10. The method according to claim 1 , wherein step (b)(1) is performed before, during and/or after adding the substance comprising iron, ferric iron and/or ferrous iron, and/or wherein step (b)(1) is performed before and/or during step (b)(2).
11. The method according to claim 1 , wherein in step (b)(1) hydrochloric acid in a gaseous state is added to and absorbed by said solution in step (b).
12. The method according to claim 1 , for increasing an iron content of a solution, wherein step (a) comprises providing a solution having an initial iron content of at least about 4 wt. %; and wherein step (b) comprises adding a substance comprising iron, to obtain a solution having an increased iron content of at least about 12 wt. % compared to the solution provided in step (a).
13. The method according to claim 1 , further comprising diluting the solution obtained by the method of claim 1 to decrease its concentration of ferric chloride.
14. A method for storing, transporting and/or moving a ferric chloride solution with an iron content of at least about 23 wt. % or higher comprising placing the solution obtained by the method of claim 1 in an intermodal container or barge.
15. The method according to claim 1 , whereby said solution is stored, transported and/or moved in an intermodal container or in a barge.
16. A method for storing, transporting and/or moving a ferric chloride solution with an iron content of between about 67 wt. % and about 75 wt. %, comprising placing the solution obtained by the method according to claim 1 in an intermodal container or barge adapted for long-time storage, long-distance transport without tracing, and/or long-distance transport with tracing.
17. The method according to claim 1 , wherein step (b)(2) comprises oxidizing ferrous ion with an agent selected from chlorine gas, ozone, oxygen gas, chlorine dioxide, sodium hypochlorite, oxychlorination gas, peroxides, perchlorate or a combination of one or more thereof.
18. The method according to claim 17 , wherein the oxychlorination gas comprises a combination of oxygen gas and hydrochloric acid gas.
19. The method according to claim 1 , further comprising maintaining the solution comprising an increased ferric chloride content above its freezing point.