IP Library › Granted Patent US 11,046,900
Granted Patent B2
US 11,046,900 · App. 14/901,947 · Granted Jun 29, 2021

Process for upgrading refinery heavy residues to petrochemicals

Inventors: Thomas Hubertus Maria Housmans (Geleen, NL); Arno Johannes Maria Oprins (Maastricht, NL)
Assignees: SAUDI BASIC INDUSTRIES CORPORATION; SABIC GLOBAL TECHNOLOGIES B.V.
C10G69/02C10G65/00C10G65/10C10G65/18C10G67/0445C10G69/06C10G69/14C10G2300/107C10G2300/1044C10G2300/1051C10G2300/1055C10G2300/1059C10G2300/1077C10G2400/20C10G2400/30
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Quick Facts
Patent No.
US 11,046,900
App. No.
14/901,947
Granted
Jun 29, 2021
Kind
B2
Abstract

The present invention relates to a process for upgrading refinery heavy residues to petrochemicals, comprising the following steps of: (a) separating a hydrocarbon feedstock in a distillation unit into a to overhead stream and a bottom stream (b) feeding said bottom stream to a hydrocracking reaction area (c) separating reaction products, which are generated from said reaction area of step (b) into a stream rich in mono-aromatics and in a stream rich in poly-aromatics (d) feeding said stream rich in mono-aromatics to a gasoline hydrocracker (GHC) unit, (e) feeding said stream rich in poly-aromatics to a ring opening reaction area.

Claims (10)

1. A process for upgrading refinery heavy residues to petrochemicals, comprising the steps of:

(a) separating a hydrocarbon feedstock in a distillation unit into a top overhead stream and a bottom stream, wherein the hydrocarbon feedstock consists of a combination of crude oil, kerosene, diesel, atmospheric gas oil (AGO), gas condensates, waxes, crude contaminated naphtha, vacuum gas oil (VGO), vacuum residue, atmospheric residue, naphtha and pretreated naphtha;

(b) feeding said bottom stream to a hydrocracking reaction area, wherein the process conditions prevailing in said hydrocracking area of step consist of a temperature of 300° C., a pressure of 300 kPa gauge and a Weight Hourly Space Velocity of 0.1 h −1 ;

(c) separating reaction products, which are generated from said reaction area of step (b) into a stream rich in mono-aromatics and in a stream rich in poly-aromatics, wherein the stream rich in mono-aromatics consists of mono-aromatics having a boiling range of from 70° C. to 217° C., and wherein said stream rich in poly-aromatics consists of poly-aromatics having a boiling range of from 217° C. and higher;

(d) feeding said stream rich in mono-aromatics to a gasoline hydrocracker unit, wherein the process conditions prevailing in said gasoline hydrocracker unit consist of a reaction temperature of 300° C., a pressure of 0.3 MPa gauge and a Weight Hourly Space Velocity (WHSV) of 0.1 h −1 ;

(e) feeding said stream rich in poly-aromatics to a ring opening reaction area; and; wherein the process conditions prevailing in said ring opening reaction area consist of a temperature of 100° C. and a pressure of 2 MPa together with from 50 to 300 kg of hydrogen per 1,000 kg of said stream rich in poly-aromatics over an aromatic hydrogenation catalyst and passing a resulting stream from said ring opening reaction area to a ring cleavage unit at a temperature 200° C. and a pressure from 1 Mpa together with from 50 to 200 kg of hydrogen per 1,000 kg of said resulting stream over a ring cleavage catalyst;

feeding a stream rich in paraffins separated from the top overhead stream in step a) into an isomerization unit and feeding the thus isomerized stream to a steam cracking unit;

separating reaction products of said gasoline hydrocracker of step (d) into an overhead gas stream comprising C2-C4 paraffins, hydrogen and methane and a bottom stream comprising aromatic hydrocarbon compounds and non-aromatic hydrocarbon compounds; feeding the overhead stream from the gasoline hydrocracker unit into the steam cracker unit;

separating the reaction products from the ring opening step (b) into a heavy fraction and a light fraction and feeding the heavy fraction of reaction products formed in the reaction area for ring opening into the gasoline hydrocracker unit; and

feeding the light fraction of reaction products formed in the reaction area for ring opening into the steam cracker unit.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 29, 2015
From: HOUSMANS, THOMAS HUBERTUS MARIA; OPRINS, ARNO JOHANNES MARIA
To: SAUDI BASIC INDUSTRIES CORPORATION; SABIC GLOBAL TECHNOLOGIES B.V
Reel/Frame 037378/0978 →
Priority Claims (1)
EP 13174770 · Jul 2, 2013 · regional
Continuity (1)
Related Publication 20160369188A1 · Dec 22, 2016
Cited By (2)
US 12,209,222 US 12,371,624