Highly heat-resistant and highly transparent polycarbonate ester, and preparation method therefor
Disclosed is a bio-based polycarbonate ester comprising: (i) repeat unit 1 obtained from a condensation reaction of 1,4:3,6-dianhydrohexitol and carbonate; and (ii) repeat unit 2 obtained from a condensation reaction of 1,4:3,6-dianhydrohexitol and 1,4-cyclohexanedicarboxylate; and a preparation method for the bio-based polycarbonate ester, comprising the steps of: (1) preparing a compound 1,4-diphenyl-cyclohexanedicarboxylate through a trans-esterification or esterification reaction of a compound represented by formula 2 and phenol; and (2) preparing a compound comprising a repeat unit represented by formula 1 through a polycarbonate melt polycondensation reaction of the 1,4-diphenyl-cyclohexanedicarboxylate prepared in step (1), a compound represented by formula 4 and 1,4:3,6-dianhydrohexitol.
1. A bio-based polycarbonate ester consisting of:
a repeating unit represented by Formula 1:
wherein x satisfies 0<x<1, and
wherein the ratio of cis/trans cyclohexanedicarboxylate unit is 20/80% to 80/20% in the repeating unit of Formula 1.
2. The bio-based polycarbonate ester of claim 1 , wherein the ratio of cis/trans cyclohexanedicarboxylate unit is 30/70% to 70/30% in the repeating unit of Formula 1.
3. The bio-based polycarbonate ester of claim 1 , wherein the ratio of cis/trans cyclohexanedicarboxylate unit is 40/60% in the repeating unit of Formula 1.
4. The bio-based polycarbonate ester of claim 1 , wherein the 1,4:3,6-dianhydrohexitol is isosorbide.