Methods and systems for removing geothermal scale
Geothermal wells frequently form deposits of geothermal scale that can detrimentally affect subterranean operations. These deposits can be very difficult to remove from a surface. Conventional procedures for addressing geothermal scale often provide inadequate scale removal, in addition to creating a number of other issues. Methods for removing geothermal scale from a wellbore can comprise: introducing a descaling agent comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof into a wellbore of a geothermal well having geothermal scale present therein; contacting the geothermal scale with the descaling agent; and removing at least a portion of the geothermal scale from the geothermal well using the descaling agent.
1. A method comprising:
introducing a descaling agent comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof into a wellbore of a geothermal well, the geothermal well having a bottom-hole temperature of about 300° F. or greater and having geothermal scale present therein;
contacting the geothermal scale with the descaling agent; and
removing at least a portion of the geothermal scale from the geothermal well using the descaling agent,
wherein removing at least a portion of the geothermal scale comprises dissolving at least a portion of the geothermal scale with the descaling agent to produce a metal ion, and complexing the metal ion with the N-(phosphonoalkyl)iminodiacetic acid or any salt thereof, and wherein the geothermal scale comprises a siliceous material and a metal-containing compound.
2. The method of claim 1 , wherein the metal ion comprises at least one metal ion selected from the group consisting of an iron ion, a copper ion, a silver ion, a magnesium ion, a calcium ion, an aluminum ion, a manganese ion, a nickel ion, a barium ion, a strontium ion, a zirconium ion, a zinc ion, a titanium ion, a tin ion, a beryllium ion, an antimony ion, an arsenic ion, and any combination thereof.
3. The method of claim 1 , wherein the descaling agent further comprises hydrofluoric acid or a hydrofluoric acid-generating compound.
4. The method of claim 3 , wherein the descaling agent is introduced into the wellbore in a treatment fluid that contains about 1 wt. % or less alkali metal ions.
5. The method of claim 1 , wherein the geothermal scale comprises up to about 50 wt. % of the siliceous material.
6. The method of claim 1 , wherein the siliceous material comprises silica, a silicate, an aluminosilicate, or any combination thereof.
7. The method of claim 1 , wherein the geothermal scale is present in the wellbore, in a fracture of a subterranean formation penetrated by the wellbore, on a tool present in the wellbore, or any combination thereof.
8. The method of claim 1 , wherein the descaling agent further comprises hydrofluoric acid or a hydrofluoric acid-generating compound.
9. The method of claim 1 , wherein the N-(phosphonoalkyl)iminodiacetic acid has a structure of
wherein n is an integer ranging between 1 and about 5.
10. The method of claim 9 , wherein the N-(phosphonoalkyl)iminodiacetic acid comprises N-(phosphonomethyl)iminodiacetic acid or any salt thereof.
11. A method comprising:
introducing a treatment fluid comprising a descaling agent into a wellbore of a geothermal well, the geothermal well having a bottom-hole temperature of about 300° F. or greater and having geothermal scale comprising a metal-containing compound present therein, the descaling agent comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof;
dissolving at least a portion of the geothermal scale with the descaling agent to produce a metal ion; and
complexing the metal ion with the N-(phosphonoalkyl)iminodiacetic acid.
12. The method of claim 11 , wherein the treatment fluid contains about 1 wt. % or less alkali metal ions.
13. The method of claim 11 , wherein the metal ion comprises at least one metal ion selected from the group consisting of an iron ion, a copper ion, a silver ion, a magnesium ion, a calcium ion, an aluminum ion, a manganese ion, a nickel ion, a barium ion, a strontium ion, a zirconium ion, a zinc ion, a titanium ion, a tin ion, a beryllium ion, an antimony ion, an arsenic ion, and any combination thereof.
14. The method of claim 11 , wherein the geothermal scale further comprises a siliceous material.
15. The method of claim 14 , wherein the descaling agent further comprises hydrofluoric acid or a hydrofluoric acid-generating compound.
16. The method of claim 14 , wherein the geothermal scale comprises up to about 50 wt. % of the siliceous material.
17. The method of claim 11 , wherein the descaling agent further comprises hydrofluoric acid or a hydrofluoric acid-generating compound.
18. The method of claim 11 , wherein the N-(phosphonoalkyl)iminodiacetic acid has a structure of
wherein n is an integer ranging between 1 and about 5.
19. The method of claim 18 , wherein the N-(phosphonoalkyl)iminodiacetic acid comprises N-(phosphonomethyl)iminodiacetic acid or any salt thereof.
20. The method of claim 11 , wherein the N-(phosphonoalkyl)iminodiacetic acid or any salt thereof is present as a solid in the treatment fluid and is introduced to the geothermal well in a slurry form.
21. A method comprising:
contacting geothermal scale with a descaling agent comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof;
dissolving at least a portion of the geothermal scale with the descaling agent to produce a metal ion; and
complexing the metal ion with the N-(phosphonoalkyl)iminodiacetic acid or any salt.
22. The method of claim 21 , wherein the descaling agent further comprises hydrofluoric acid or a hydrofluoric acid-generating compound.
23. The method of claim 21 , wherein the geothermal scale is present in a wellbore, in a fracture of a subterranean formation penetrated by the wellbore, on a tool present in the wellbore, on a surface structure in fluid communication with the wellbore, or any combination thereof.
24. A system comprising:
a pump fluidly coupled to a tubular, the tubular containing a treatment fluid comprising a descaling agent comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof,
wherein the tubular extends into a wellbore of a geothermal well, the geothermal well having a bottom-hole temperature of about 300° F. or greater and having geothermal scale present therein, wherein removing at least a portion of the geothermal scale comprises dissolving at least a portion of the geothermal scale with the descaling agent to produce a metal ion, and complexing the metal ion with the N-(phosphonoalkyl)iminodiacetic acid or any salt thereof, and wherein the geothermal scale comprises a siliceous material and a metal-containing compound.