IP Library › Granted Patent US 10,005,950
Granted Patent B2
US 10,005,950 · App. 14/907,582 · Granted Jun 26, 2018

Methods and systems for removing geothermal scale

Inventors: Alyssa Lynn Smith (Humble, TX); Enrique Antonio Reyes (Tomball, TX); Aaron Michael Beuterbaugh (Spring, TX)
Assignee: Halliburton Energy Services, Inc.
C09K8/528E21B37/06
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Quick Facts
Patent No.
US 10,005,950
App. No.
14/907,582
Granted
Jun 26, 2018
Kind
B2
Abstract

Geothermal wells frequently form deposits of geothermal scale that can detrimentally affect subterranean operations. These deposits can be very difficult to remove from a surface. Conventional procedures for addressing geothermal scale often provide inadequate scale removal, in addition to creating a number of other issues. Methods for removing geothermal scale from a wellbore can comprise: introducing a descaling agent comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof into a wellbore of a geothermal well having geothermal scale present therein; contacting the geothermal scale with the descaling agent; and removing at least a portion of the geothermal scale from the geothermal well using the descaling agent.

Claims (38)

1. A method comprising:

introducing a descaling agent comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof into a wellbore of a geothermal well, the geothermal well having a bottom-hole temperature of about 300° F. or greater and having geothermal scale present therein;

contacting the geothermal scale with the descaling agent; and

removing at least a portion of the geothermal scale from the geothermal well using the descaling agent,

wherein removing at least a portion of the geothermal scale comprises dissolving at least a portion of the geothermal scale with the descaling agent to produce a metal ion, and complexing the metal ion with the N-(phosphonoalkyl)iminodiacetic acid or any salt thereof, and wherein the geothermal scale comprises a siliceous material and a metal-containing compound.

2. The method of claim 1 , wherein the metal ion comprises at least one metal ion selected from the group consisting of an iron ion, a copper ion, a silver ion, a magnesium ion, a calcium ion, an aluminum ion, a manganese ion, a nickel ion, a barium ion, a strontium ion, a zirconium ion, a zinc ion, a titanium ion, a tin ion, a beryllium ion, an antimony ion, an arsenic ion, and any combination thereof.

3. The method of claim 1 , wherein the descaling agent further comprises hydrofluoric acid or a hydrofluoric acid-generating compound.

4. The method of claim 3 , wherein the descaling agent is introduced into the wellbore in a treatment fluid that contains about 1 wt. % or less alkali metal ions.

5. The method of claim 1 , wherein the geothermal scale comprises up to about 50 wt. % of the siliceous material.

6. The method of claim 1 , wherein the siliceous material comprises silica, a silicate, an aluminosilicate, or any combination thereof.

7. The method of claim 1 , wherein the geothermal scale is present in the wellbore, in a fracture of a subterranean formation penetrated by the wellbore, on a tool present in the wellbore, or any combination thereof.

8. The method of claim 1 , wherein the descaling agent further comprises hydrofluoric acid or a hydrofluoric acid-generating compound.

9. The method of claim 1 , wherein the N-(phosphonoalkyl)iminodiacetic acid has a structure of

wherein n is an integer ranging between 1 and about 5.

10. The method of claim 9 , wherein the N-(phosphonoalkyl)iminodiacetic acid comprises N-(phosphonomethyl)iminodiacetic acid or any salt thereof.

11. A method comprising:

introducing a treatment fluid comprising a descaling agent into a wellbore of a geothermal well, the geothermal well having a bottom-hole temperature of about 300° F. or greater and having geothermal scale comprising a metal-containing compound present therein, the descaling agent comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof;

dissolving at least a portion of the geothermal scale with the descaling agent to produce a metal ion; and

complexing the metal ion with the N-(phosphonoalkyl)iminodiacetic acid.

12. The method of claim 11 , wherein the treatment fluid contains about 1 wt. % or less alkali metal ions.

13. The method of claim 11 , wherein the metal ion comprises at least one metal ion selected from the group consisting of an iron ion, a copper ion, a silver ion, a magnesium ion, a calcium ion, an aluminum ion, a manganese ion, a nickel ion, a barium ion, a strontium ion, a zirconium ion, a zinc ion, a titanium ion, a tin ion, a beryllium ion, an antimony ion, an arsenic ion, and any combination thereof.

14. The method of claim 11 , wherein the geothermal scale further comprises a siliceous material.

15. The method of claim 14 , wherein the descaling agent further comprises hydrofluoric acid or a hydrofluoric acid-generating compound.

16. The method of claim 14 , wherein the geothermal scale comprises up to about 50 wt. % of the siliceous material.

17. The method of claim 11 , wherein the descaling agent further comprises hydrofluoric acid or a hydrofluoric acid-generating compound.

18. The method of claim 11 , wherein the N-(phosphonoalkyl)iminodiacetic acid has a structure of

wherein n is an integer ranging between 1 and about 5.

19. The method of claim 18 , wherein the N-(phosphonoalkyl)iminodiacetic acid comprises N-(phosphonomethyl)iminodiacetic acid or any salt thereof.

20. The method of claim 11 , wherein the N-(phosphonoalkyl)iminodiacetic acid or any salt thereof is present as a solid in the treatment fluid and is introduced to the geothermal well in a slurry form.

21. A method comprising:

contacting geothermal scale with a descaling agent comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof;

dissolving at least a portion of the geothermal scale with the descaling agent to produce a metal ion; and

complexing the metal ion with the N-(phosphonoalkyl)iminodiacetic acid or any salt.

22. The method of claim 21 , wherein the descaling agent further comprises hydrofluoric acid or a hydrofluoric acid-generating compound.

23. The method of claim 21 , wherein the geothermal scale is present in a wellbore, in a fracture of a subterranean formation penetrated by the wellbore, on a tool present in the wellbore, on a surface structure in fluid communication with the wellbore, or any combination thereof.

24. A system comprising:

a pump fluidly coupled to a tubular, the tubular containing a treatment fluid comprising a descaling agent comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof,

wherein the tubular extends into a wellbore of a geothermal well, the geothermal well having a bottom-hole temperature of about 300° F. or greater and having geothermal scale present therein, wherein removing at least a portion of the geothermal scale comprises dissolving at least a portion of the geothermal scale with the descaling agent to produce a metal ion, and complexing the metal ion with the N-(phosphonoalkyl)iminodiacetic acid or any salt thereof, and wherein the geothermal scale comprises a siliceous material and a metal-containing compound.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 26, 2016
From: SMITH, ALYSSA LYNN; REYES, ENRIQUE ANTONIO; BEUTERBAUGH, AARON MICHAEL
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 037578/0722 →
Continuity (2)
Continuation In Part PCTUS2013075067 · Dec 13, 2013
Related Publication 20160160111A1 · Jun 9, 2016
Cited By (7)
US 12,305,624 US 12,312,981 US 12,385,474 US 12,454,896 US 12,515,973 US 12,534,990 US 12,571,328