Anode body for solid electrolytic capacitor elements and method for producing same
An anode body for a solid electrolytic capacitor element, which is an anode body for a solid electrolytic capacitor element having a dielectric layer on the surface of a sintered body, wherein at least a part of the surface of the valve-acting metal particles constituting the sintered body is covered with a dielectric layer, and a part of the dielectric layer on the particle surface has a larger thickness than the other part; and a method for producing the same, in which a sintered body of a valve-acting metal is immersed in an aqueous solution of an oxidizing agent after being subjected to chemical formation, the resulting sintered body is then immersed in water-soluble alcohol and dried, and the oxidizing agent is removed by water washing.
1. A method for producing an anode body for a solid electrolytic capacitor element, wherein at least a part of a surface of valve-acting metal particles constituting a sintered body is covered with a dielectric layer, and a thickest part of the dielectric layer has a thickness 1.5 to three times larger than a thinnest part of the dielectric layer, comprising a process in which a sintered body of a valve-acting metal is immersed in an aqueous solution of an oxidizing agent after being subjected to chemical formation, then the resulting sintered body is immersed in water-soluble alcohol, the sintered body is dried by heating at 100° C. or higher, thereby oxidizing the valve-acting metal being in contact with the oxidizing agent, and then the oxidizing agent is removed by water washing.
2. The method for producing a solid electrolytic capacitor element as claimed in claim 1 , wherein the oxidizing agent is an oxidizing agent which is water-soluble and insoluble in alcohol.
3. The method for producing a solid electrolytic capacitor element as claimed in claim 1 , wherein the oxidizing agent is a persulfuric acid compound.
4. The method for producing a solid electrolytic capacitor element as claimed in claim 1 , wherein the oxidizing agent is at least one member of a halogen acid compound and an organic peroxide.
5. The method for producing a solid electrolytic capacitor element as claimed in claim 1 , wherein concentration of the oxidizing agent is 0.1 mass % or more and a saturated solubility or less.
6. The method for producing a solid electrolytic capacitor element as claimed in claim 1 , wherein the dielectric layer is formed by chemical oxidation and/or electrolytic oxidation.
7. A method for producing a solid electrolytic capacitor element, comprising sequentially laminating a semiconductor layer and a conductor layer on the anode body obtained by the production method claimed in claim 1 .